A One-Pot Synthesis of Tetrahydro-2,5-dioxofuran-3-yl Alkylcarbamodithioates

An efficient one-pot synthesis of tetrahydro-2,5-dioxofuran-3-yl alkylcarbamodithioates via three-component reaction of maleic anhydride, CS₂, and primary amines in good yields is described.     

On the Stress Field of a Nonlinear Elastic Solid Torus with a Toroidal Inclusion

Standard measures of local deformation such as deformation gradient, strain, elastic deformation, and plastic deformation are dimensionless. However, many macroscopic and submacroscopic geometrical changes observed in continuous bodies result in the formation of zones across whose boundaries significant changes in geometry can occur. In order to predict the sizes of such zones and their influence on material response, theories of elasticity and plasticity have been employed in which second gradients of deformation, gradients of strain, as well as gradients of elastic or of plastic deformation are taken into account. The theory of structured deformations provides additive decompositions of first deformation gradient and of second deformation gradient, valid for large deformations of any material, in which each term has a multiscale geometrical interpretation corresponding to the presence or absence of submacroscopic disarrangements (non-smooth geometrical changes such as slips and void formation). This article provides a field theory that broadens the earlier field theory, elasticity with disarrangements, by including energetic contributions from submacroscopic “gradient-disarrangements” (limits of averages of jumps in gradients of approximating deformations) and by treating particular kinematical conditions as internal constraints. An explicit formula is obtained showing the manner in which submacroscopic gradient-disarrangements determine a defectiveness density analogous to the dislocation density in theories of plasticity. A version of the new field theory incorporates this defectiveness density to obtain a counterpart of strain-gradient plasticity, while another instance of elasticity with gradient-disarrangements recovers an instance of strain-gradient elasticity with symmetric Cauchy stress. All versions of the new theory included here are compatible with the Second Law of Thermodynamics.     

Quasi injectivity and θ-internal order sum in partially ordered acts

Injectivity (weakly injectivity) of objects is an important concept which category theory inherited from homological and commutative algebra. One of the useful kinds of weakly injectivity is quasi injectivity. In this paper, we study the relation between different kinds of quasi injectivity and the concept of θ-internal order sum in the category of actions of an ordered monoid on ordered sets and some of its important subcategories. From the results obtained, we investigated the relations between these types of quasi injectivity.     

Triphenylphosphine Catalyzed Stereoselective Synthesis of O-Vinyloximes

The conjugate addition of oximes to ethyl propiolate proceeds under neutral conditions in presence of a catalytic amount of triphenylphosphine to give the corresponding O-vinyloximes in good yields.     

Nonlinear mechanics of accretion

We formulate a geometric nonlinear theory of the mechanics of accretion. In this theory, the material manifold of an accreting body is represented by a time-dependent Riemannian manifold with a time-independent metric that at each point depends on the state of deformation at that point at its time of attachment to the body, and on the way the new material is added to the body. We study the incompatibilities induced by accretion through the analysis of the material metric and its curvature in relation to the foliated structure of the accreted body. Balance laws are discussed and the initial boundary value problem of accretion is formulated. The particular cases where the growth surface is either fixed or traction-free are studied and some analytical results are provided. We numerically solve several accretion problems and calculate the residual stresses in nonlinear elastic bodies induced from accretion.

     

Phosphahelicenes: From Chiroptical and Photophysical Properties to OLED Applications

Herein, the experimental physicochemical and chiroptical properties of a series of phosphahelicenes are reported, focusing on their UV/Vis absorption, luminescence, electronic circular dichroism, optical rotations, and circularly polarized luminescence. Furthermore, detailed analysis of absorption and ECD spectra performed with the help of quantum-chemical calculations allowed us to highlight general features of these helicenic phosphines. Finally, due to well-suited electrochemical properties and thermal stability, the systems were successfully used as emitters in organic light-emitting diodes.