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181.
Lattice dynamical calculations of the lattice modes for both trans and cis polyacetylene were performed. Using rigid body approximation for the chain we obtained all 8 lattice frequencies and modes of motion for both trans and cis polyacetylene. The frequencies concerned with Raman active lattice modes are presented for the first time. We also performed far infrared transmission measurements of undoped trans and cis polyacetylene and confirmed the results obtained by Bechtold et al. Comparison of the lattice frequencies obtained by lattice dynamical calculations with the results obtained by far infrared measurement and inelastic neutron scattering is discussed.  相似文献   
182.
Two-component interpenetrating polymer networks (IPN) were made by stepwise synthesis by UV-irradiated polymerization and heat curing. The mechanical properties of normal IPN, inverse IPN and SIN (simultaneous interpenetrating networks) prepared with acrylate and epoxy were studied. Unique mechanical properties were found in each case. All of these iPN systems were composed of the individual preswollen networks. A homogeneous system is produced in the inverse IPN and SIN, while a heterogeneous system is brought about in the normal IPN. Glass transition temperatures for the inverse IPN and the SIN are lower than the normal IPN, and are attributed to molecular packing effects.  相似文献   
183.
The crystallinity and porosity of all-inorganic dodecatungstophosphate M3PW12O40 (M=Cs, NH4, Ag, denoted as MPW) particles are controlled by the changes in the synthetic temperatures and countercations. The MPW particles can be classified into three groups by the crystallinity and porosity: (i) mesoporous "disordered" aggregates, (ii) microporous "self-organized" aggregates, and (iii) nonporous single crystals. The formation and growth mechanism of MPW particles is expressed by three steps: formation of nanocrystallites, assembly of the nanocrystallites to form aggregates, and the growth of aggregates by the attachment of nanocrystallites. The time courses of the turbidity of the synthetic solution, the concentration of the nanocrystallites, and the average particle sizes of MPW particles are well reproduced by the calculation based on the mechanism.  相似文献   
184.
Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide--acryloylmorpholine co-oligomers were prepared by the co-oligomerizations of fluoroalkanoyl peroxides with the corresponding monomers. These fluorinated co-oligomers exhibited a lower critical solution temperature (LCST) characteristic in aqueous solutions. Of particular interest, a steep time dependence of contact angle values for dodecane was observed from 40 to 60 degrees C to decrease their values, effectively, on the modified PMMA [poly(methyl methacrylate)] film surface treated with fluorinated co-oligomer possessing the LCST: 36 degrees C (in water), although such a steep time dependence was not observed from 20 to 30 degrees C.  相似文献   
185.
A large variety of synthetic vesicles has been created for potential engineering applications and as model systems which mimic living organisms. In most cases, the structure is designed to be thermodynamically stable. However, mimicking dynamic behaviors of living vesicles still remains undeveloped. Herein, we present a synthetic vesicle which shows autonomous disintegration–reconstruction cycles without any external stimuli and which is similar to those in living organisms, such as in the nuclear envelope and synaptic vesicles. The vesicle is composed of a diblock copolymer which has a hydrophilic and a thermosensitive segment. The thermosensitive segment includes a redox moiety that acts as a catalyst for an oscillatory chemical reaction and also controls the aggregation temperature of vesicles. Furthermore, autonomous fusion of vesicles is also observed during the cycles.  相似文献   
186.
A terahertz stop band filter and a resonator consisting of metal gratings are analyzed using the finite-difference time-domain (FDTD) method, with special attention to the treatment of metal. Numerical results based on a perfect electric conductor (PEC) approximation are compared to those with a metal dispersion being taken into account by the Drude model. It is shown that the results of the resonator for the PEC model are favorably compared with those for the Drude model at frequencies of less than 1 THz. However, care must be taken at higher frequencies, since not only the transmittance at the resonance remarkably reduces for the Drude model, but also its resonance frequency deviates, in comparison with those for the PEC model. Metal mesh structures are also investigated using the periodic FDTD. The differences are found to be relatively small, due to the weak confinement of THz waves in metal mesh structures. The results can serve as a guideline for the FDTD analysis of THz devices consisting of metal.  相似文献   
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188.
A series of triple ionic compounds consisting of double armed anions and one cation were prepared as lithium cation conductive matrices. As anions, lithium borates derived from lithium-9-borabicyclo[3,3,1]nonane hydride were introduced. The sterically hindered borate anion structures prevented the crystallization of triple ionic compounds. Introduction of ethylene oxide chains attached to the borate anions led to lower glass transition temperature, and also improved ionic conductivity. A lithium transference number of 0.73 was observed in spite of the presence of ethylene oxide chains.  相似文献   
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