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91.
MR Eskildsen AB Abrahamsen PL Gammel DJ Bishop NH Andersen K Mortensen PC Canfield 《Pramana》2002,58(5-6):903-905
We compare the results of small angle neutron scattering on the flux line lattice (FLL) obtained in the borocarbide superconductor
LuNi2B2C with the applied field along the c- and a-axes. For H‖c the temperature dependence of the FLL structural phase transition from square to hexagonal symmetry was investigated. Above
10 K the transition onset field. H
2(T), rises sharply, bending away from H
c2(T) in contradiction to theoretical predictions of the two merging. For H‖a a first order FLL reorientation transition is observed at H
tr=3–3.5 kOe. Below H
tr the FLL nearest neighbor direction is parallel to the b-axis, and above H
tr to the c-axis. This transition cannot be explained using nonlocal corrections to the London model. 相似文献
92.
Computable lower and upper bounds for the symmetric elliptic integrals and for Legendre's incomplete integral of the first kind are obtained. New bounds are sharper than those known earlier. Several inequalities involving integrals under discussion are derived. 相似文献
93.
A simple method was developed to separate Pu and Am using single column extraction chromatography employing N,N,N′,N′-tetra-n-octyldiglycolamide (DGA) resin. Isotope dilution measurements of Am and Pu were performed using accelerator mass spectrometry (AMS) and alpha spectrometry. For maximum adsorption Pu was stabilized in the tetra valent oxidation state in 8 M HNO3 with 0.05 M NaNO2 before loading the sample onto the resin. Am(III) was adsorbed also onto the resin from concentrated HNO3, and desorbed with 0.1 M HCl while keeping the Pu adsorbed. The on-column reduction of Pu(IV) to Pu(III) with 0.02 M TiCl3 facilitated the complete desorption of Pu. Interferences (e.g. Ca2+, Fe3+) were washed off from the resin bed with excess HNO3. Using NdF3, micro-precipitates of the separated isotopes were prepared for analysis by both AMS and alpha spectrometry. The recovery was 97.7 ± 5.3% and 95.5 ± 4.6% for 241Am and 242Pu respectively in reagents without a matrix. The recoveries of the same isotopes were 99.1 ± 6.0 and 96.8 ± 5.3% respectively in garden soil. The robustness of the method was validated using certified reference materials (IAEA 384 and IAEA 385). The measurements agree with the certified values over a range of about 1–100 Bq kg−1. The single column separation of Pu and Am saves reagents, separation time, and cost. 相似文献
94.
Naeemullah Tasneem Gul Kazi Mustafa Tuzen Faheem Shah Hassan Imran Afridi Demirhan Citak 《Analytica chimica acta》2014
Easy and innovative non-dispersive ionic liquid based microextraction (NDILME) has been developed for preconcentration of trace level of cadmium (Cd) in aqueous real surface water samples prior to couple with graphite furnace atomic absorption spectrometry (GFAAS). A 200 cm long narrow glass column containing aqueous solution of standard/sample was used to increase phase transfer ratio by providing more contact area between two medium (aqueous and extractive), which drastically improve the recoveries of labile hydrophobic chelate of Cd ammonium pyrrolidinedithiocarbamate (APDC), into ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate [C4mim][PF6]. Different aspect of the desire method have been investigated and optimized. Under the optimized key experimental variables, limit of detection (LOD) and enhancement factor (EF) were achieved to be 0.5 ng L−1 and 150, respectively. Reliability of the model method was checked by relative standard deviation (%RSD), which was found to be < 5%. Validity and accuracy of the developed method was checked by analysis of certified reference water samples (SLRS-4 Riverine water) using standard addition method. 相似文献
95.
S. M. Islam Paramita Mondal Kazi Tuhina Anupam Singha Roy Dilder Hossain Sanchita Mondal 《Transition Metal Chemistry》2010,35(7):891-901
The polymer-anchored Schiff base complexes of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) were prepared by reacting polystyrene
amine with 2-pyridinecarbaldehyde followed by loading of metal atom in methanol. These complexes were characterized by using
different physico-chemical and spectroscopic methods. The catalytic activity of these polymer-supported metal catalysts was
tested for the oxidation of various olefins and alcohols. Influence of various reaction parameters, such as reaction temperature,
reaction time, oxidant, substrate-to-oxidant mole ratio and nature of solvent, was studied for the oxidation of cyclohexene
with these catalysts. Among the catalysts studied, Cu-Cat showed higher catalytic activity toward oxidation reactions than
the other catalysts. Moreover, hot filtration experiments proved that these catalysts are truly heterogeneous and can be reused
a number of times without significant loss of activity. 相似文献
96.
Fluorescence Properties of Donor Acceptor Chromophores on Newly Synthesized Pyridine-3-Carbonitriles 总被引:1,自引:1,他引:0
Raghunath B. Toche Muddassar A. Kazi Bhausaheb K. Ghotekar Sandeep M. Bagul Chanda D. Tantak Madhukar N. Jachak 《Journal of fluorescence》2009,19(6):1119-1124
A convenient route was successfully developed for the synthesis of novel heterocycles such as pyridine-3-carbonitriles 4 from
chalcone 3 in good yields. The pyridine-3-carbonitrile derivatives synthesized were further studied for their photophysical
properties and observed that absorption and emission was changed, due to the chromospheres at C4-position in phenyl ring and C2-position in pyridine-3-carbonitrile derivatives. 相似文献
97.
A systematic study of Fe atom encapsulation and adsorption in armchair SiC nanotubes (SiCNT) with diameters in the range of 5.313 to 10.582 Å has been performed using hybrid density functional theory and a finite cluster approximation. A detailed comparison of the binding energies, equilibrium positions, Mulliken charges, and spin magnetic moments of Fe atoms has been performed for three types of nanotubes. The electronic states, HOMO–LUMO gaps, and changes in gaps with respect to the bare nanotube gaps have been investigated as well. Our results show that the properties of SiCNT can be modified by Fe atom encapsulation and adsorption. Binding energies of the encapsulated and adsorbed systems indicate that these structures are stable and show site dependence. For both cases a significant band gap decrease is observed for type 1 nanotubes enabling band gap tailoring. This decrease is not observed for the other two types with a larger diameter. All structures are found to have magnetic ground states with high magnetic moments indicating the possibility of them being used in spintronics applications. 相似文献
98.
Extraction followed by spectrophotometry was employed to determine nitrate and nitrite in sewage sludge. Recovery of added nitrate and nitrite was complete. The procedure was suitable for the determination of nitrate nitrogen and nitrite nitrogen in this matrix. 相似文献
99.
Kazi Sabnam Banu Tanmay Chattopadhyay Arpita Banerjee Santanu Bhattacharya Ennio Zangrando Debasis Das 《Journal of molecular catalysis. A, Chemical》2009,310(1-2):34-41
Five dinuclear copper(II) complexes, [Cu2L1(N3)2·2H2O] (1), [Cu2L2(N3)2·2H2O] (2), [Cu2L3(N3)2·2H2O] (3), [Cu2L4(N3)2·2H2O] (4) and [Cu2L5(N3)2·2H2O] (5) of Robson type macrocyclic Schiff-base ligands derived from [2 + 2] condensation of 4-methyl-2,6-diformylphenol with 1,3-diaminopropane (H2L1), 1,2-diaminoethane (H2L2), 1,2-diaminopropane (H2L3), 1,2-diamino-2-methylpropane (H2L4) and 1,2-diaminocyclohexane (H2L5), respectively have been synthesized and characterized. Catecholase activity of those complexes using 3,5-di-tert-butylcatechol as substrate has been investigated in two solvents, methanol and acetonitrile. The role of the solvent and of the steric properties of the macrocyclic ligand of these complexes on their catecholase activity has been examined thoroughly. Acetonitrile is observed to be a better solvent than methanol as far as their catalytic activity is concerned. However, methanol reveals to be a better choice to identify the enzyme–substrate adduct. The investigation also prompted that chelate ring size does affect on the catalytic efficiency: 6-membered ring (as in H2L1) exhibits better activity than its 5-membered counterpart (as in H2L2). The activity of the 5-membered counter parts also depend upon the steric factor. Moreover, the catalytic activity of the complexes is enhanced to a significant extent by increasing the bulkiness of the substituents on the backbone of macrocyclic H2L2 ligands. 相似文献
100.
Modal analysis of IncGaAsP-InP, GaAs/AlGaAs-GaAs, and InGaAsP/AlGaAs-GaAs MIS heterostructure lasers
The transverse modal behavior of Metal-Insulator (Oxide)-Semiconductor (MIS) heterostructure injection lasers is analyzed. MIS structures have been proposed by Jain and Marciniec as an alternate approach to p-n heterojunctions to obtain minority carrier injection and subsequent lasing action. In the modal analysis the MIS structure is treated as an asymmetrical three-layer slab waveguide with appropriate boundary conditions. Numerical computations of electric field strength, intensity and confinement factor P are presented for various GaAs and InP based MIS structures. A comparison of the output characteristics of a GaAs MIS laser with a conventional GaAs p-n double heterostructure laser is also reported. 相似文献