Electrochemical Determination of Dextromethorphan on Reduced Graphene Oxide Modified Screen‐Printed Electrode after Electromembrane Extraction

In this paper, electromembrane extraction coupled with differential pulse voltammetry (DPV) on a reduced graphene oxide modified screen‐printed carbon electrode (RGO‐SPCE) for the determination of dextromethorphan (DXM) in urine and plasma has been described. DXM migrated from 4 mL of a donor phase across a thin layer of 2‐nitrophenyl octyl ether (NPOE) immobilized in the pores of a porous hollow fiber, into a 20 µL acceptor phase (HCl) present inside the lumen of the fiber. Then, 15 µL of a 0.1 M NaOH solution was added to the acceptor phase and the mixture was analyzed using DPV.     

Thermodynamic Consistency Test of Vapor–liquid Equilibrium Data of Binary Systems Including Carbon Dioxide (CO 2 ) and Ionic Liquids Using the Generic Redlich–Kwong Equation of State

The thermodynamic consistency test of solubility P–T–x data for binary mixtures including carbon dioxide (CO2) + a room temperature ionic liquid has been investigated. Experimental solubility data taken from the open literature for 32 binary mixtures of CO2/RTILs contains 80 isotherms. The applied consistency test is based on the fundamental Gibbs–Duhem equation with use of the generic Redlich–Kwong (GRK) equation of state (EoS) coupled with the van der Waals–Berthelot (GRK/vdWB) mixing rule. The optimum parameters were obtained by minimizing the summation of per cent relative deviations between modeled and experimental data, based on the bubble pressure algorithm. Modeling was found acceptable for all isotherms, which demonstrated the usability of the GRK equation of state. Results of the thermodynamic consistency test showed that 36 of the isothermal data sets were thermodynamically consistent, 37 were not fully consistent, 6 were thermodynamically inconsistent and only one data set was found to need another model.     

Contracted Hamiltonian on Symmetric Space <Emphasis Type="Italic">SU</Emphasis>(3)/<Emphasis Type="Italic">SU</Emphasis>(2) and Conserved Quantities

We study the quantum model on symmetric space SU(3)/SU(2). By using the Inonu-Wigner contraction to Lie algebra su(3), we arrive at a special case of three-body Sutherland model. It has shown that by calculating conservative quantities of this model, it has Poincare Lie algebra, too.     

One-pot synthesis of 1,2,3-triazole linked dihydropyrimidinones via Huisgen 1,3-dipolar/Biginelli cycloaddition

The combination of the Biginelli reaction with click chemistry has been used for the one-pot synthesis of 1,2,3-triazole linked dihydropyrimidinones from azides, aromatic aldehydes containing a propargyl ether group, urea, and 1,3-dicarbonyl compounds using Cu(OAc)₂/sodium ascorbate as catalyst in acetic acid under mild reaction conditions.     

Electrodeposition of nanocrystalline Zn-Ni alloy from alkaline glycinate bath containing saccharin as additive

Nanocrystalline Zn-Ni (crystallite sizes 13-68 nm) alloy coatings were produced from an alkaline glycinate bath containing saccharin as additive. X-ray diffraction (XRD) was used to determine the phase composition and average crystallite size of nanocrystalline Zn-Ni alloy coatings. The average grain size of a deposit was also studied by transmission electron microscopy (TEM). The effects of saccharin concentration and current density on the crystallite size and surface roughness of the coatings were studied. Crystallite size and average surface roughness were diminished as a result of increasing saccharin concentration. Scanning electron microscopy (SEM) examination showed that coatings had a colony-like morphology and the colony size was increased with increasing current density. Microhardness testing was carried out in order to determine the degree of dependence of this mechanical property on the crystallite size. It was found that microhardness did not depend on crystallite size (Hall-Petch).     

Optimal estimation of reactivity ratios for acrylamide/acrylic acid copolymerization

Reactivity ratios for the important acrylamide (AAm)/acrylic acid (AAc) copolymerization system exhibit considerable scatter in previously published literature, and therefore, there is a need for more definitive values for these reactivity ratios. An appropriate methodology, based on the error‐in‐variables‐model (EVM) framework along with a direct numerical integration procedure, is applied in order to determine reliable reactivity ratios. The reliability of the results is confirmed with extensive and independent replication. Furthermore, via an EVM‐based criterion for the design of experiments using mechanistic models, optimal feed compositions are calculated, and from these optimal reactivity ratios are estimated for the first time (r_AAm = 1.33 and r_AAc = 0.23) based on information from the full conversion range. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4819–4827     

Synthesis of a novel molecularly imprinted polymer based on functionalized multi-walled carbon nanotubes for selective extraction of sulfadiazine prior to spectrophotometric determination

A novel and efficient sulfadiazine imprinted polymer was synthesized via co-precipitation method and successfully grafted on magnetic multi-walled carbon nanotubes. The synthesized magnetic imprinted polymer was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray powder diffraction analysis, thermal analysis and applied as a sorbent for selective magnetic solid-phase extraction of sulfadiazine. The retained sulfadiazine was eluted by 150.0 µL methanol/acetic acid (6:4) solution and quantified by fiber optic linear array spectrophotometry via formation of a detectable azo dye. All parameters affecting the extraction of sulfadiazine were investigated and optimized. Under the optimized conditions, the method exhibited a linear dynamic range of 2.0–50.0 µg L^?1 with a detection limit of 0.56 µg L^?1 and enrichment factor of 300.0. The relative standard deviation at 30.0 µg L^?1 of sulfadiazine (N = 6) was 2.8 and 4.6% for intra-day and inter-day, respectively. The method was successfully applied to determine sulfadiazine in human urine, honey, milk and environmental water samples.     

A two-phase approach for setting targets in DEA with negative data

Conventional DEA models have been introduced to deal with non-negative data. In the real world, in some occasions, we have outputs and/or inputs, which can take negative data. In DEA literature some approaches have been presented for evaluating performance of units, which operate with negative data. In this paper, firstly, we give a brief review of these works, then we present a new additive based approach in this framework. The proposed model is designed to provide a target with non-negative value associated with negative components for each observed unit, failed by other methods. An empirical application in banking is then used to show the applicability of the proposed method and make a comparison with the other approaches in the literature.     

Two phase mixed convection Al2O3–water nanofluid flow in an annulus

Heat transfer enhancement of a mixed convection laminar Al₂O₃–water nanofluid flow in an annulus with constant heat flux boundary condition has been studied employing two phase mixture model and effective expressions of nanofluid properties. The fluid flow properties are assumed constant except for the density in the body force, which varies linearly with the temperature (Boussinesq’s hypothesis), thus the fluid flow characteristics are affected by the buoyancy force. The Brownian motions of nanoparticles have been considered to determine the effective thermal conductivity and the effective dynamic viscosity of Al₂O₃–water nanofluid, which depend on temperature. Three-dimensional Navier–Stokes, energy and volume fraction equations have been discretized using the finite volume method while the SIMPELC algorithm has been introduced to couple the velocity–pressure. Numerical simulations have been presented for the nanoparticles volume fraction (?) between 0 and 0.05 and different values of the Grashof and Reynolds numbers. The calculated results show that at a given Re and Gr, increasing nanoparticles volume fraction increases the Nusselt number at the inner and outer walls while it does not have any significant effect on the friction factor. Both the Nusselt number and the friction coefficient at the inner wall are more than their corresponding values at the outer wall.     

Slant Submanifolds of Almost Contact Metric 3-Structure Manifolds

In this paper we introduce the notion of slant submanifold of an almost contact metric 3-structure manifold. We give some examples and characterize these submanifolds. Moreover, Sasakian slant submanifolds of an almost contact 3-structure manifold are defined and studied. We also establish a sharp inequality including the squared mean curvature and Ricci curvature of a Sasakian slant submanifold.