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51.
A simple, low pressure, low temperature vapour phase decomposition (VPD) of quartz powder has been developed for the determination of phosphorus. A platinum dish containing the quartz or silicon powder was placed inside a polypropylene vessel containing 40 ml of 1:1 mixture of HF and HNO(3). After capping the vessel, the entire assembly was heated on a water bath at approximately 90 degrees C for 8 h. The platinum dish was removed from the vessel, the sample solution was treated with 0.5 ml of H(2)SO(4) and 0.5 ml of HClO(4) and was heated on a hot plate till HClO(4) fumed out. The resultant solution was diluted to 40 ml ( approximately 0.4N), analysed for phosphorus by spectrophotometry as an ion-pair of molybdophosphate with crystal violet. Phosphorus contamination by reagents has been drastically reduced (around 250 times) compared to the conventional dissolution procedure. The optimum reaction conditions were [H(+)]=0.42N, [H(+)]/Mo=62 for the formation of molybdophosphate and its extraction into n-butyl acetate. No interferences due to fluoride, silicate (active silica) and arsenic (V) upto 6.7x10(3),2.7x10(3) and 2.0x10(3) times the content of phosphorus, respectively were observed. The LOD was found to be 0.066 mug g(-1) (+/-3 s). RSD is 0.4-2.3% and the molar absorptivity is 2.7x10(5) l mole(-1) cm(-1). 相似文献
52.
Ong?Chong?Cheen Subash?C.?B.?GopinathEmail author Veeradasan?Perumal M.?K.?Md?Arshad Thangavel?Lakshmipriya Yeng?Chen R.?Haarindraprasad Balakrishnan?S.?Rao Uda?Hashim Kannaiyan?Pandian 《Mikrochimica acta》2017,184(1):117-125
This article describes a sensitive impedimetric method for the determination of human blood coagulation factor IX protein (FIX) which is present in extremely low concentration in serum. An interdigitated electrode (IDE) whose surface was layered with zinc oxide was modified with two kinds of probes. One is an antibody, the other an aptamer against FIX. A comparative study between anti-FIX aptamer and anti-FIX antibody showed the aptamer to possess higher affinity for FIX. A sandwich aptamer assay was worked out by using the FIX-binding aptamer on the surface of the IDE. It has a detection limit as low as 10 pM which makes it 4 to 30-fold more sensitive than any other method reported for FIX. Moreover, to practice detection in clinical samples, FIX was detected from the human blood serum by spiking. In our perception, the sensitivity of the ZnO-modified IDE presented here makes it a promising tool for sensing clinically relevant analytes that are present in very low (sub-pM) concentrations. 相似文献
53.
The use of boric acid as a modifier for the determination of trace amount of rubidium in high purity cesium chloride matrix by electrothermal atomic absorption is described. It was found that the negative influence of the chloride matrix could not be eliminated using stabilized temperature platform (STPF) alone. Due to the high dissociation energy (D0 = 427 kJ mol−1) of rubidium chloride, it was difficult to dissociate in the gas phase and hence is lost. Elimination of interferences was achieved by the addition of boric acid as a chemical modifier. Diluted cesium chloride samples (5%, m/v) were analyzed applying the standard addition method. The characteristic mass of 24 pg was obtained. The detection limit of the proposed method is around 26 ng g−1. The developed method was applied to the determination of traces of rubidium in high purity cesium chloride samples. The data obtained by this method were in good agreement with those obtained by other independent method like FAAS. 相似文献
54.
Enhancing Capacity Performance by Utilizing the Redox Chemistry of the Electrolyte in a Dual‐Electrolyte Sodium‐Ion Battery 下载免费PDF全文
Dr. Sirugaloor Thangavel Senthilkumar Hyuntae Bae Jinhyup Han Prof. Youngsik Kim 《Angewandte Chemie (International ed. in English)》2018,57(19):5335-5339
A strategy is described to increase charge storage in a dual electrolyte Na‐ion battery (DESIB) by combining the redox chemistry of the electrolyte with a Na+ ion de‐insertion/insertion cathode. Conventional electrolytes do not contribute to charge storage in battery systems, but redox‐active electrolytes augment this property via charge transfer reactions at the electrode–electrolyte interface. The capacity of the cathode combined with that provided by the electrolyte redox reaction thus increases overall charge storage. An aqueous sodium hexacyanoferrate (Na4Fe(CN)6) solution is employed as the redox‐active electrolyte (Na‐FC) and sodium nickel Prussian blue (Nax‐NiBP) as the Na+ ion insertion/de‐insertion cathode. The capacity of DESIB with Na‐FC electrolyte is twice that of a battery using a conventional (Na2SO4) electrolyte. The use of redox‐active electrolytes in batteries of any kind is an efficient and scalable approach to develop advanced high‐energy‐density storage systems. 相似文献
55.
Hydrothermal growth of Cr doped ZnO nanorods (NRs) thin films was grown on glass substrates. The strong ferromagnetic (FM) and antiferromagnetic (AFM) ordering was observed in 3% and 7% of Cr doped samples. The optical excitation of the Cr doped ZnO NRs is responsible for injection of the spin-polarized carriers in the 3% Cr doped ZnO NRs through longitudinal magneto-optical Kerr effect (MOKE). We determined a negative anisotropic magnetoresistance () originated from spin orbit coupling due to sp-d exchange interaction. we calculated the process of photon induced inverse spin Hall angle () close to the MOKE saturated rotation angle () for 3% Cr: ZnO. These results can open a new path of optical spin detectors for next-generation spintronic device technology. 相似文献
56.
Chinnaswamy Thangavel Vijayakumar Nagarajan David Mathan Vijayakumar Sarasvathy Thangamani Rajkumar Arunachalam Thamaraichelvan Durairaj Ponraju 《Journal of Thermal Analysis and Calorimetry》2010,101(1):281-287
Intumescent materials, 3,9-dichloro-2,4,8,10-tetraoxa-3,9-diphosphaspiro-[5,5]-undecane-3,9-dioxide and 3,9-dichloro-2,4,8,10-tetraoxa-3,9-diphosphaspiro-[5,5]-undecane
having the capacity to produce dehydrating agent, blowing agent, and undergo carbonization during burning have been synthesized.
The thermal behavior of the synthesized materials was investigated using differential thermal analysis, thermal volatilization
analysis, programmed vacuum pyrolysis–mass spectrometry, flash pyrolysis–mass spectrometry and off-line pyrolysis–gas chromatography–mass
spectrometry. The materials show exothermic degradation after 250 °C. Monitoring the release of hydrogen chloride and water,
the blowing agents for the production of carbon foam, clearly indicated the superior performance of the pentavalent phosphorus
compound over the trivalent phosphorus compound. The major gaseous degradation products released during pyrolysis showed the
presence of sufficient quantities of several alkyl-substituted benzenes and fused aromatics. Suitable degradation mechanism
has been proposed and discussed to explain the formation of various organics during thermal degradation. 相似文献
57.
S. Munawar Basha S. Ramasubramanian R. Thangavel M. Rajagopalan J. Kumar 《Journal of magnetism and magnetic materials》2010,322(2):238-241
Investigations have been carried out to study the ferromagnetic properties of transition metal (TM) doped wurtzite GaN from first principle calculations using tight binding linear muffin-tin orbital (TBLMTO) method within the density functional theory. The present calculation reveals ferromagnetism in nickel doped GaN with a magnetic moment of 1.13 μB for 6.25% of Ni doping and 1.32 μB for 12.5% of nickel doping, there is a decrease of magnetic moment when two Ni atoms are bonded via nitrogen atom. The Ga vacancy (VGa) induced defect shows ferromagnetic state. Here the magnetic moment arises due to the tetrahedral bonding of three N atoms with the vacancy which is at a distance of 3.689 Å and the other N atom which is at a distance of 3.678 Å .On the other hand the defect induced by N vacancy (VN) has no effect on magnetic moment and the system shows metallic character. When Ni is introduced into a Ga vacancy (VGa) site, charge transfer occur from the Ni ‘d’ like band to acceptor level of VGa and formed a strong Ni–N bond. In this Ni–VGa complex with an Ni ion and a Ga defect, the magnetic moment due to N atom is 0.299 μB .In case of Ni substitution in Ga site with N vacancy, the system is ferromagnetic with a magnetic moment of 1 μB. 相似文献
58.
ONO pincer‐type palladium(II) complexes of heterocyclic hydrazone: Synthesis,characterization and biological evaluation 下载免费PDF全文
Thangavel Thirunavukkarasu Hazel A. Sparkes Karuppannan Natarajan V.G. Gnanasoundari 《应用有机金属化学》2018,32(8)
Two new Pd(II) complexes of N′‐(4‐(diethylamino)‐2‐hydroxybenzylidene)furan‐2‐carbohydrazide were synthesized and characterized using various spectral methods. The structure of one of the complexes was determined using single‐crystal X‐ray diffraction. DNA and protein binding affinities of the synthesized compounds were examined using UV–visible and fluorescence titration method. In addition, the in vitro cytotoxicity of the compounds was evaluated against A549 (lung cancer) and MCF7 (breast cancer) cell lines using the MTT assay method. 相似文献
59.
Thangavel Vijayakanth Farsa Ram Balu Praveenkumar Kadhiravan Shanmuganathan Ramamoorthy Boomishankar 《Angewandte Chemie (International ed. in English)》2020,59(26):10368-10373
Organic–inorganic hybrid ferroelectrics are an exciting class of molecular materials with promising applications in the area of energy and electronics. The synthesis, ferroelectric and piezoelectric energy harvesting behavior of a 3d metal ion‐containing A4BX6 type organic–inorganic hybrid salt [Ph3MeP]4[Ni(NCS)6] ( 1 ) is now presented. P‐E hysteresis loop studies on 1 show a remnant ferroelectric polarization value of 18.71 μC cm?2, at room temperature. Composite thermoplastic polyurethane (TPU) devices with 5, 10, 15 and 20 wt % compositions of 1 were prepared and employed for piezoelectric energy harvesting studies. A maximum output voltage of 19.29 V and a calculated power density value of 2.51 mW cm?3 were observed for the 15 wt % 1 ‐TPU device. The capacitor charging experiments on the 15 wt % 1 ‐TPU composite device shows an excellent energy storage performance with the highest stored energies and measured charges of 198.8 μJ and 600 μC, respectively. 相似文献
60.