全文获取类型
收费全文 | 536篇 |
免费 | 42篇 |
国内免费 | 2篇 |
专业分类
化学 | 480篇 |
晶体学 | 6篇 |
力学 | 8篇 |
数学 | 20篇 |
物理学 | 66篇 |
出版年
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 11篇 |
2019年 | 13篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 17篇 |
2015年 | 17篇 |
2014年 | 15篇 |
2013年 | 34篇 |
2012年 | 38篇 |
2011年 | 57篇 |
2010年 | 17篇 |
2009年 | 17篇 |
2008年 | 33篇 |
2007年 | 31篇 |
2006年 | 37篇 |
2005年 | 31篇 |
2004年 | 23篇 |
2003年 | 21篇 |
2002年 | 19篇 |
2001年 | 5篇 |
2000年 | 12篇 |
1999年 | 10篇 |
1998年 | 6篇 |
1997年 | 7篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 6篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 8篇 |
1981年 | 3篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1975年 | 4篇 |
1974年 | 6篇 |
1973年 | 3篇 |
1970年 | 3篇 |
1965年 | 1篇 |
1962年 | 2篇 |
1961年 | 2篇 |
排序方式: 共有580条查询结果,搜索用时 15 毫秒
21.
Yang J Okuyama K Morris K Arp Z Laane J 《The journal of physical chemistry. A》2005,109(37):8290-8292
With the aid of a reported inversion splitting value, the far-infrared spectrum resulting from the ring-puckering vibration of coumaran has been reassigned and the one-dimensional potential energy function has been determined. The barrier to planarity is 155 +/- 4 cm(-1) and the dihedral angle is 25 degrees . These results agree well with the millimeter wave spectra values of 152 cm(-1) and 23 degrees , which utilized different data and a different type of potential function for the calculations. The MP2/cc-pvtz ab initio values of 238 cm(-1) and 26.5 degrees agree more poorly. If the benzene ring is assumed to remain rigid, the calculated barrier drops to 204 cm(-1). The puckering potential functions for the ring-flapping and ring-twisting vibrationally excited states were also determined and the barriers were found to be 149 and 156 cm(-1), respectively. 相似文献
22.
Katsuhiko Tomooka Nobuyuki Komine Tomoya Sasaki Hideo Shimizu Takeshi Nakai 《Tetrahedron letters》1998,39(52):2362-9718
Treatment of (E)-6-phenyl-5-hexenyl carbamates with s-BuLi/(−)-sparteine is shown to afford the trans-1,2-disubstituted cyclopentane derivatives in high % ee, along with the bicyclo[3.1.0]hexanes (bicyclization products). 相似文献
23.
24.
Masahito Segi Katsuhiko Tanno Masumi Kojima Mitsunori Honda Tadashi Nakajima 《Tetrahedron letters》2007,48(13):2303-2306
1,3-Dipolar cycloaddition between aromatic selenoaldehydes, generated by thermal retro Diels-Alder reaction of anthracene cycloadducts, and nitrile oxides or nitrile imines proceeded efficiently to give the corresponding [3+2] cycloadducts as a single isomer in good yields, being 1,4,2-oxaselenazoles or 1,3,4-selenadiazoles, respectively. 相似文献
25.
Katsuhiko Ono Kyohei Yoshikawa Hiroyuki Yamaguchi Masaaki Tomura Katsuhiro Saito 《Tetrahedron》2007,63(38):9354-9358
BF2 complexes with 1,3-diketone ligands were synthesized, and their optical and electrochemical properties were studied. The colors of the complexes varied depending on the structures of the 1,3-diketone ligands. The absorption and emission maxima of the complexes with 1,3-diaryl-1,3-diketone ligands were considerably red shifted as compared to those of the complexes with 1-aryl-3-trifluoromethyl-1,3-diketone ligands, suggesting an extended π-conjugation of the 1,3-diaryl-1,3-diketone moieties. The molar absorption coefficients and quantum yields of the complexes with 1,3-diaryl-1,3-diketone ligands were larger than those of the complexes with 1-aryl-3-trifluoromethyl-1,3-diketone ligands. Cyclic voltammetry measurements revealed that the reduction potentials of the BF2 complexes were higher than those of the free ligands. These complexes exhibited various emission colors in the solid states due to the intermolecular interactions. 相似文献
26.
27.
28.
29.
Kazuyuki Kubo Hiroshi Nakazawa Hiroyasu Inagaki Tomoyuki Miyake Tsutomu Mizuta Katsuhiko Miyoshi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8-9):2159-2160
Treatment of [Cp*(CO) 2 M{P(NHPh)(OMe) 2 }]PF 6 (M = Fe and Ru) with NaNH 2 gives metallaiminophosphoranes, Cp*(CO) 2 M{P(NPh)(OMe) 2 }. The x-ray structures and reactivity of the complexes are reported. 相似文献
30.