Direct femtosecond laser writing of waveguides in As2S3 thin films

Single-channel waveguides and Y couplers were fabricated in chalcogenide thin films by use of femtosecond laser pulses from a 25-MHz repetition rate Ti:sapphire laser. Refractive-index differentials (delta n > 10(-2)) were measured through interferometric microscopy and are higher than the typical values reported for oxide glasses. The dependence of the index differential on the peak intensity reveals the nonlinear nature of the photosensitivity in arsenic trisulfide below its bandgap energy, and the refractive-index change is correlated to the photoinduced structural changes inferred by Raman spectroscopy data. A free-electron model to predict the parametric dependence of delta n is proposed.     

Tellurite glasses with peak absolute Raman gain coefficients up to 30 times that of fused silica

An experimental system has been assembled to measure the absolute values of the Raman gain spectrum for millimeter-thick glass samples. Results are reported for two new oxide glasses with Raman gain coefficients as much as 30 times larger than that of fused silica and more than twice its spectral coverage.     

Site-selective patterning using surfactant-based resists

Patterned SAMs of alkanethiols on gold or silver are explored as resists for electrodeposition and exhibit surprisingly rich behavior depending on the overpotential and the length of the alkane chain. At small overpotentials, SAMs are positive resists with deposition only in the surfactant-free regions. At larger overpotentials, SAMs are negative resists with preferential deposition in the SAM-modified regions. Tunable surfactant-based resists are potentially versatile tools to dictate the deposition of materials and are demonstrated as a means of creating complex, three-dimensional structures.     

Some Simple Algorithms for Structural Comparison

Structural comparison (i.e., the simultaneous analysis of multiple structures) is a problem which arises frequently in such diverse arenas as the study of organizational forms, social network analysis, and automated text analysis. Prior work has demonstrated the applicability of a range of standard multivariate analysis procedures to the structural comparison problem. Here, some simple algorithms are provided which elucidate several of these methods in an easily implemented form. Carter T. Butts is Assistant Professor at the University of California-Irvine in the Department of Sociology, and is a member of the Institute for Mathematical Behavioral Sciences and the California Institute for Telecommunications and Information Technology. His current research focuses on communication during disasters, Bayesian inference for network data, network comparison, and the structure of spatially embedded interpersonal networks. Kathleen M. Carley is Professor at Carnegie Mellon University, with appointments in the Institute for Software Research International, the H.J. Heinz III School of Public Policy and Management, and the Department of Engineering and Public Policy. Her research centers around areas of social, organizational, knowledge and information networks, organizational design, change, adaptivity and and performance, computational organization theory, crisis management, social theory, impacts on information diffusion of changes in social policy and changes in communication technology, and mapping experts' and executives' knowledge networks using textual analysis techniques.     

NMR spectroscopy of proteins encapsulated in a positively charged surfactant

Traditionally, large proteins, aggregation-prone proteins, and membrane proteins have been difficult to examine by modern multinuclear and multidimensional solution NMR spectroscopy. A major limitation presented by these protein systems is that their slow molecular reorientation compromises many aspects of the more powerful solution NMR methods. Several approaches have emerged to deal with the various spectroscopic difficulties arising from slow molecular reorientation. One of these takes the approach of actively seeking to increase the effective rate of molecular reorientation by encapsulating the protein of interest within the protective shell of a reverse micelle and dissolving the resulting particle in a low viscosity fluid. Since the encapsulation is largely driven by electrostatic interactions, the preparation of samples of acidic proteins suitable for NMR spectroscopy has been problematic owing to the paucity of suitable cationic surfactants. Here, it is shown that the cationic surfactant CTAB may be used to prepare samples of encapsulated anionic proteins dissolved in low viscosity solvents. In a more subtle application, it is further shown that this surfactant can be employed to encapsulate a highly basic protein, which is completely denatured upon encapsulation using an anionic surfactant.     

Tungsten oxide nanowire growth by chemically induced strain

We have investigated the formation of tungsten oxide nanowires under different chemical vapor deposition (CVD) conditions. We find that exposure of oxidized tungsten films to hydrogen and methane at 900 degrees C leads to the formation of a dense array of typically 10 nm diameter nanowires. Structural and chemical analysis shows that the wires are crystalline WO3. We propose a chemically driven whisker growth mechanism in which interfacial strain associated with the formation of tungsten carbide stimulates nanowire growth. This might be a general concept, applicable also to other nanowire systems.     

On Davies’ argument from relational properties

In Art as Performance, David Davies identifies certain properties relevant to artistic appreciation of artworks that, he suggests, are naturally construed as belonging to the artist’s creative performance rather than to any product of that performance (the “work-product”). He further argues, against an anticipated opponent, that such properties cannot be excluded as irrelevant to artistic appreciation in any principled way. I argue that the cited properties can be intelligibly construed as properties of the associated work-product, whether or not they are relevant to artistic appreciation; but that some are not relevant to artistic appreciation. In doing so, I offer a principle determining when a property of an artwork is relevant to artistic appreciation. I conclude that, on its own, Davies’s argument offers no good grounds to abandon our practice of thinking of the artwork as the product of an artist’s activity, rather than the activity itself.     

Efficient methods for configuration interaction calculations

Advanced techniques are developed to provide efficient economic treatment of the large scale eigenvalue problem posed when configuration interaction is carried out on SCF basis sets of moderate size. When the characteristic properties of the hamiltonian matrix are examined in light of the type of solution required, partitioning of the configuration space is shown to result in an expansion of the problem about a limited core of states, where the small but cumulative interactions of vast regions of the remaining space are reduced to the form of an effective potential. With proper selection of the core, the evaluation of this potential can be readily and accurately truncated to a level involving minimum expenditure in time and effort. In particular only diagonal elements and a strip of the full CI matrix are required to achieve an accuracy of 1 – 5 kcal/mole with complete treatment for configuration spaces of order tens of thousands. In addition, a close look at current theory on the generation of matrix elements between spin symmetry adapted configurations leads to simplified expressions where the matrix elements are derived in the form of a weighted sum of molecular integrals in which the weighting coefficients represent the integrated value of the wavefunctions over spin coordinates. For typical cases of low multiplicity and limited numbers of open shells the list of unique parameters needed to generate all weights are shown to be readily stored as a program library. Actual times for matrix element generation are believed to be an order of magnitude faster than current techniques. Practical demonstration of the accuracy and efficiency of the method is provided by calculations on formaldehyde, water, and ethylene.     

Steady state hot atom kinetic theory model calculations. Time dependent rate coefficients for the nonthermal 18F + H2 reaction

This paper briefly summarizes the methodology and results for a new type of hot atom kinetic theory model calculation. The microscopic time dependence for the nuclear recoil ¹⁸F + H₂ reaction is characterized using the steady state kinetic theory of hot atom reactions. The relaxing hot atom laboratory momentum distribution is represented using a local equilibrium model. The calculated results illustrate the nature and significance of quasi steady state reaction rate coefficients and of the dynamical coupling between reactive heating and nonreactive cooling phenomena. Under nuclear recoil conditions the nonthermal ¹⁸F + H₂ reaction, which exhibits a total hot yield of 100%, fails to establish a high temperature steady state.     

Broadly tunable compact continuous-wave Cr(2+):ZnS laser

We report the development of a continuous-wave, room-temperature Cr(2+) ZnS laser that is compact and tunable over 700 nm. The laser is pumped by a diode-pumped Er-fiber laser and generates 0.7 W of linearly polarized radiation at 2.35microm , at up to 40% slope efficiency. Cr(2+) ZnS directly diode-pumped at 1.6microm yields polarized radiation that is tunable over 400 nm at up to 25 mW of output power. A comparison of Cr(2+) ZnS with Cr ZnSe (70 mW, 350 nm) in a similar setup is given. As opposed to Cr ZnSe, the Cr ZnS laser is intrinsically polarized. Finally, we observe sensitization of the output radiation by a few milliwatts of the visible (470-500-nm) and near-infrared (740-770-nm) radiation.