Experimental characterization of quantum-correlated twin beams and a quantum channel with twin beams

We report the generation and characterization of quantum-correlated twin beams and their application to a quantum channel. Compared with our previous results, the characterization of twin beams and the quantum channel have been studied with 7.0-dB intensity difference squeezing. The measured inference variance of twin beams is decreased to 0.40 ± 0.02. For the quantum channel, the bit error rate will be 0.035 by using 7.0-dB intensity difference squeezing compared with our previous result of 0.067 by using 4.9-dB intensity difference squeezing.     

Characterization of an oriented metastable atom source based on a magnetic hexapole

The M_J-state selection of the metastable rare-gas (Rg*) was achieved by a magnetic hexapole that is composed of permanent magnets. The performance of the magnetic hexapole was examined by characterizing the velocity distribution and the spatial profile of the state selected Rg* beam. The characterization was carried out using position resolved time-of-flight analysis and its trajectory simulation. The magnetic hexapole enhanced the beam intensity at least one order of magnitude owing to the focusing effect. In addition, the magnetic hexapole was found to act as a good velocity selector.     

Penultimate effect in radical copolymerization of 2‐trifluoromethylacrylates

Electron‐deficient 2‐trifluoromethylacrylates (TFMA) undergo radical copolymerization with electron‐rich norbornene derivatives, vinyl ethers, and styrene derivatives, which can be described by the penultimate model much better than by the commonly employed terminal model. In an attempt to directly observe the effect of the CF₃ group in the penultimate unit on the radical reactivity, we employed the Giese's mercury method. 4,4,4‐Trifluorobutyl and n‐butyl radicals produced from respective alkylmercuric chlorides were competitively reacted with t‐butyl 2‐trifluoromethylacrylate (TBTFMA) and t‐butyl methacrylate (TBMA) and the products analyzed with gas chromatography. While TBTFMA has been found to be about 24times more reactive than TBMA toward the n‐butyl radical, the former is about 12 times more reactive than the latter toward the 4,4,4‐trifluorobutyl radical. Thus, the reactivity of the propagating radical toward TBTFMA in comparison with TBMA is suppressed by a factor of two when the penultimate unit has the CF₃ group. We observed a sextet electron spin resonance of the TFMA propagating radical with a coupling constant of ca. 25 gauss between the β‐proton and β‐fluorine. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1559–1565, 2008     

Linear Separability of Positive Self-Dual Logical Filters

The threshold logic filter is an important nonlinear filter class, which is defined by a threshold logic function of binary input values. It is proved in this paper that not all positive self-dual logical functions are threshold functions if the number of input variables is 5 or more. The positive self-dual logical filter is a limited class but includes almost all filters for noise removal. Our result means that not all positive self-dual filters can be expressed by one operation of the threshold logic filters. In the sense of the filter expression by neural networks, the two-layer network cannot always optimize even this limited class.     

Hydrogenase-based nanomaterials as anode electrode catalyst in polymer electrolyte fuel cells

We consider hydrogenase-based nanomaterials for possible use as anode electrode catalysts in polymer electrolyte fuel cells (PEFCs). We choose Fe-only hydrogenase component of Desulfovibrio desulfuricans (DdHase) as a hydrogenase complex, and investigate its catalytic activity for H₂ dissociation using ab initio calculations based on density functional theory (DFT). We found two possible H-H bond cleavage pathways, which are heterolytic and possess low activation barriers. Moreover, the H₂ dissociation can be promoted by inducing spin polarization of the H₂ adduct. We report that hydrogenase or hydrogenase-based nanomaterials can manipulate to exhibit the catalytic activity equivalent to the well-known platinum catalyst.     

Major metabolites of ginseng sapogenins formed by rat liver microsomes

Incubation of ginseng sapogenins with microsomes from rat liver resulted in formation of their 20,24-epoxides as major metabolites. Identification of the metabolites was performed by HPLC, FAB-MS and EI-MS.     

Acetylated triterpene saponins from the Thai medicinal plant, Sapindus emarginatus

From the pericarps of Sapindus emarginatus (Sapindaceae), three new acetylated triterpene saponins were isolated together with hederagenin and five known triterpene saponins, as well as one known sweet acyclic sesquiterpene glycoside, mukurozioside IIb. The structures of new compounds were elucidated as hederagenin 3-O-(2-O-acetyl-beta-D-xylopyranosyl)-(1-->3)-alpha-L-rhamnopyranosyl-(1-->2)-alpha-L-arabinopyranoside, 23-O-acetyl-hederagenin 3-O-(4-O-acetyl-beta-D-xylopyranosyl)-(1-->3)-alpha-L-rhamnopyranosyl-(1-->2)-alpha-L-arabinopyranoside and oleanolic acid 3-O-(4-O-acetyl-beta-D-xylopyranosyl)-(1-->3)-alpha-L-rhamnopyranosyl-(1-->2)-alpha-L-arabinopyranoside by chemical and spectroscopic data.