全文获取类型
收费全文 | 1616篇 |
免费 | 76篇 |
国内免费 | 6篇 |
专业分类
化学 | 1137篇 |
晶体学 | 11篇 |
力学 | 18篇 |
数学 | 188篇 |
物理学 | 344篇 |
出版年
2023年 | 8篇 |
2022年 | 15篇 |
2021年 | 42篇 |
2020年 | 32篇 |
2019年 | 36篇 |
2018年 | 26篇 |
2017年 | 29篇 |
2016年 | 50篇 |
2015年 | 50篇 |
2014年 | 65篇 |
2013年 | 83篇 |
2012年 | 108篇 |
2011年 | 129篇 |
2010年 | 66篇 |
2009年 | 85篇 |
2008年 | 126篇 |
2007年 | 104篇 |
2006年 | 82篇 |
2005年 | 67篇 |
2004年 | 66篇 |
2003年 | 52篇 |
2002年 | 68篇 |
2001年 | 31篇 |
2000年 | 33篇 |
1999年 | 28篇 |
1998年 | 16篇 |
1997年 | 11篇 |
1996年 | 19篇 |
1995年 | 16篇 |
1994年 | 12篇 |
1993年 | 11篇 |
1992年 | 15篇 |
1991年 | 9篇 |
1990年 | 13篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 10篇 |
1986年 | 8篇 |
1985年 | 13篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 5篇 |
1978年 | 2篇 |
1976年 | 3篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1941年 | 2篇 |
1931年 | 2篇 |
排序方式: 共有1698条查询结果,搜索用时 31 毫秒
31.
32.
A. González Arias A. del Cueto J. M. Muñoz C. de Francisco L. Torres A. G. Flores M. Zazo J. Iñiguez 《Applied Physics A: Materials Science & Processing》1996,63(5):453-459
Silica may dissolve up to about 0.05 wt% in an iron excess NiZnCo spinel matrix, affecting noticeably the magnetic properties at low and high values of the applied field. The initial permeability is reduced by about 50% with the addition of only 0.1 % SiO2, while the coercivity almost triples, without noticeable changes in porosity or grain distribution. The vacancy and Fe2+ content of the sintered material also show a considerable change. The energy associated to the transformation Fe3+ Fe2+ for the samples without SiO2 was found to be 0.41–0.42 eV, while for the samples with SiO2 additions it decreased to 0.26 eV. The changes in magnetic properties are thought to be caused, more than because of the mentioned changes in ion distribution, by the stresses and defects created in the lattice due to the very small size of the Si4+ ion, which substitutes Fe3+ ions in tetrahedral sites. The transition Fe3+ Fe2+ seems to take place exclusively in the octahedral sites. 相似文献
33.
34.
The fluorimetric determination of adrenaline is carried out in a continuous-flow assembly and by means of the molecular dissolved oxygen. The sample solution merges with an NaOH stream, then the resulting mixture is heated at 73 °C and led to the flow-cell of the fluorimeter. The flow-assembly is very simple and the procedure is quick (107 samples h–1) reproducible (R.S.D. 0.6%), selective and suitable to be applied to determination of adrenaline in formulations. Calibrations graph are linear over the ranges 0.05–15 and 20–40 mgl–1. 相似文献
35.
Moreno M. M. Torres Santos R. H. A. Gambardella M. T. P. Camargo A. J. da Silva A. B. F. Trsic M. 《Structural chemistry》1998,9(5):365-373
The crystal and molecular structures of the following molecules have been determined: 1-acetyl-indoline, 1-acetyl-5-nitro-indoline, l-acetyl-5-nitro-7-bromo-indoline, 1-acetyl-5-bromo-7-nitroindoline, and l-acetyl-5-bromo-7-nitro-indol. Molecular orbital calculations are performed for these compounds and two related species. 相似文献
36.
The synthesis, physicochemical properties and interactions of two new thiocarbohydrazones, namely 1,5-bis[1-(2-pyridyl) ethylidene] thiocarbonohydrazide (APTH) and 1,5-bis[phenyl-(2-pyridyl) methylene] thiocarbonohydrazide (BPTH) have been studied as well as the use of both compounds as extracting reagents. These thiocarbohydrazones form yellow complexes with bivalent metal ions, and these are extractable into methyl isobutyl ketone. Conditions for quantitative extraction of Cd(II), Co(II), Cu(II), Ni(II) and Zn(II) are established from a critical study of the effect of pH, shaking time, reagent concentration in the organic phase, ionic strength and volume ratio of aqueous to organic phase. 相似文献
37.
Nicole Brasseur Karina Lewis Jacques Rousseau Johan E. van Ller 《Photochemistry and photobiology》1996,64(4):702-706
Abstract— The clinical perfusion agent 99m Tc-MIBI was used to monitor changes in tumor vascular perfusion (TVP) induced by Photofrin® (Pll)-mediated photodynamic therapy (PDT). BALB/c mice bearing an EMT-6 tumor on each hind thigh were given an intravenous injection of 1, 2 or 5 mg kg−1 PII. Twenty-four hours later, one tumor was illuminated (600–650 run, 200 mW cm−2 400 J cm−2 ) while the other served as a control. At various time intervals after PDT (0, 2 and 24 h) mice received an intravenous injection of 99m Tc-hexakismethoxy(sobutyusonitri-le (MIBI) (0.18 MBq g−1 ) and were sacrificed 2 min later. The light-treated and the untreated tumors were then dissected, the radioactivity was counted and the percentage of the injected dose per gram of tumor (%ID g−1 ) was calculated as a measure of TVP. We observed that TVP is drug dose dependent, develops progressively with time post-PDT and is inversely related to PDT efficacy. Our data show that early tumor retention of 99m MIBI is a simple method to assess TVP and vascular damage induced by PDT. 相似文献
38.
S. R. de Miguel G. Torres A. A. Castro O. A. Scelza 《Reaction Kinetics and Catalysis Letters》1993,51(2):443-447
The hydrogenation activity of Pt supported on activated carbon would depend on both the Pt dispersity (which can be modified by a partial carbon burn-off in air) and the impurities concentration. 相似文献
39.
40.
The flash photolysis of purine in acetonitrile and in water at different pH was studied. The transients produced on flash excitation of degassed aqueous solutions have been identified as the triplet excited state, the hydrated electron, a purine radical cation and radical anion on the basis of quenching experiments and comparison to transients observed in low temperature photolysis. 相似文献