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151.
Shirai A Miyata O Tohnai N Miyata M Procter DJ Sucunza D Naito T 《The Journal of organic chemistry》2008,73(12):4464-4475
The asymmetric total synthesis of martinellic acid, the first pyrrolo[3,2-c]quinoline alkaloid found in nature, is described. Three key steps in our synthesis of (-)-martinellic acid are the Bu(3)SnH-promoted radical addition-cyclization-elimination (RACE) reaction of an oxime ether with an alpha,beta-unsaturated ester to generate the pyrrolo[3,2-c]quinoline core, a chemoselective lactam carbonyl reduction, and guanidinylation under Mitsunobu reaction conditions. The key radical cyclization has also been investigated by using SmI(2). (-)-Martinellic acid was synthesized from commercially available methyl 4-bromo-3-methylbenzoate in fewer steps than previous syntheses and in an improved overall yield. 相似文献
152.
Yanagi K Iakoubovskii K Matsui H Matsuzaki H Okamoto H Miyata Y Maniwa Y Kazaoui S Minami N Kataura H 《Journal of the American Chemical Society》2007,129(16):4992-4997
Single-wall carbon nanotubes (SWCNTs) exhibit resonant absorption localized in specific spectral regions. To expand the light spectrum that can be utilized by SWCNTs, we have encapsulated squarylium dye into SWCNTs and clarified its microscopic structure and photosensitizing function. X-ray diffraction and polarization-resolved optical absorption measurements revealed that the encapsulated dye molecules are located at an off center position inside the tubes and aligned to the nanotube axis. Efficient energy transfer from the encapsulated dye to SWCNTs was clearly observed in the photoluminescence spectra. Enhancement of transient absorption saturation in the S1 state of the semiconducting SWCNTs was detected after the photoexcitation of the encapsulated dye, which indicates that ultrafast (<190 fs) energy transfer occurred from the dye to the SWCNTs. 相似文献
153.
Fujihara A Miyata C Maekawa A Fuke K Daigoku K Murata N Hashimoto K 《The journal of physical chemistry. A》2007,111(31):7364-7373
Photoelectron spectroscopy (PES) of Na2- (H2O)n (n < or = 6) was investigated to examine the solvation of sodium aggregates in small water clusters. The PES bands for the transitions from the anion to the neutral ground and first excited states derived from Na2 (1(1)Sigmag+) and Na2 (1(3)Sigmau+) shifted gradually to the blue, and those to the higher-excited states correlated to the 3(2)S + 3(2)P asymptote dropped down rapidly to the red and almost degenerated on the 1(3)Sigmau+-type band at n = 4. Quantum chemical calculations for n up to 3 showed that the spectra can be ascribed to structures where one of the Na atoms is selectively hydrated. From the electron distributions, it is found that the Na- -Na+(H2O)n- -type electronic state grows with increasing cluster size, which can be regarded as a sign of the solvation of Na2- with ionization of the hydrated Na. 相似文献
154.
A C3‐Symmetric Macrocycle‐Based,Hydrogen‐Bonded,Multiporous Hexagonal Network as a Motif of Porous Molecular Crystals 下载免费PDF全文
Dr. Ichiro Hisaki Shoichi Nakagawa Dr. Norimitsu Tohnai Prof. Mikiji Miyata 《Angewandte Chemie (International ed. in English)》2015,54(10):3008-3012
A C3‐symmetric π‐conjugated macrocycle combined with an appropriate hydrogen bonding module (phenylene triangle) allowed the construction of crystalline supramolecular frameworks with a cavity volume of up to 58 %. The frameworks were obtained through non‐interpenetrated stacking of a hexagonal sheet possessing three kinds of pores with different sizes and shapes. The activated porous material absorbed CO2 up to 96 cm3 g?1 at 195 K under 1 atm. 相似文献
155.
Ueda M Kondoh E Ito Y Shono H Kakiuchi M Ichii Y Kimura T Miyoshi T Naito T Miyata O 《Organic & biomolecular chemistry》2011,9(7):2062-2064
Direct generation of a benzyl radical by C-H bond activation of toluenes and the addition reaction of the resulting radical to an electron deficient olefin were developed. The reaction of dimethyl fumarate with toluene in the presence of Et(3)B as a radical initiator at reflux afforded 2-benzylsuccinic acid dimethyl ester in good yield. 相似文献
156.
Matsumura A Tsuchiya K Torigoe K Sakai K Sakai H Abe M 《Langmuir : the ACS journal of surfaces and colloids》2011,27(5):1610-1617
Photochemical control of vesicle disintegration and reformation in aqueous solution was examined using a mixture of 4-butylazobenzene-4'-(oxyethyl)trimethylammonium bromide (AZTMA) as the photoresponsive cationic surfactant and sodium dodecylbenzenesulfonate (SDBS) as the anionic surfactant. Spontaneous vesicle formation was found in a wide-ranging composition of the trans-AZTMA/SDBS system. AZTMA molecules constituting vesicles underwent reversible trans-cis photoisomerization when irradiated with ultraviolet and visible light. Transmission electron microscopy observations using the freeze-fracture technique (FF-TEM) showed that UV light irradiation caused the vesicles to disintegrate into coarse aggregates and visible light irradiation stimulated the reformation of vesicles (normal control). A detailed investigation of the phase state and the effects of UV and visible light irradiation on the AZTMA/SDBS system with the use of electroconductivity, dynamic/static light scattering, and surface tension measurements and FF-TEM observations revealed that in the AZTMA-rich composition (AZTMA/SDBS 9:1) a micellar solution before light irradiation became a vesicular solution after UV light irradiation and visible light irradiation allowed the return to a micellar solution (reverse control). Thus, we could photochemically control the disintegration (normal control) and reformation (reverse control) of vesicles in the same system. 相似文献
157.
Sasaki T Shizuki N Hiraishi E Hisaki I Tohnai N Miyata M 《Organic & biomolecular chemistry》2012,10(30):5985-5992
Molecular assemblies based on helical motifs are of substantial interest from the view point of fundamental science as well as application. In this study, we propose a new class of organic crystal, that is, heteroH-MOC (multi-component organic crystal containing different kinds of helical motifs consisted of different components), and describe successful construction of heteroH-MOCs with P2(1) and P2(1)2(1)2(1) space groups by using steroidal bile acids and cinchona alkaloids. In the P2(1) crystals, two kinds of helices composed of the steroid and alkaloid are arranged in a parallel fashion, while, in the P2(1)2(1)2(1) crystals, those are in a perpendicular fashion. It is remarkable that, in such systems, particularly in the latter crystals, components ingeniously achieved highly-ordered synchronization of periodicity (helical pitches r and periodic distances in the array of helices p), which is first demonstrated in this study through hierarchical interpretation of the crystal structures. 相似文献
158.
A polytopal digraph is an orientation of the skeleton of a convex polytope P. The possible non-degenerate pivot operations of the simplex method in solving a linear program over P can be represented as a special polytopal digraph known as an LP digraph. Presently there is no general characterization of which polytopal digraphs are LP digraphs, although four necessary properties are known: acyclicity, unique sink orientation (USO), the Holt–Klee property and the shelling property. The shelling property was introduced by Avis and Moriyama (2009), where two examples are given in dimensions of polytopal digraphs satisfying the first three properties but not the shelling property. The smaller of these examples has vertices. Avis, Miyata and Moriyama (2009) constructed for each and , a d-polytope P with n vertices which has a polytopal digraph which is an acyclic USO that satisfies the Holt–Klee property, but does not satisfy the shelling property. The construction was based on a minimal such example, which has and . In this paper we explore the shelling condition further. First we give an apparently stronger definition of the shelling property, which we then prove is equivalent to the original definition. Using this stronger condition we are able to give a more general construction of such families. In particular, we show that given any 4-dimensional polytope P with vertices whose unique sink is simple, we can extend P for any and to a d-polytope with these properties that has n vertices. Finally we investigate the strength of the shelling condition for d-crosspolytopes, for which Develin (2004) has given a complete characterization of LP orientations. 相似文献
159.
160.
Cho T Kohagura J Numakura T Hirata M Higaki H Hojo H Ichimura M Ishii K Islam KM Itakura A Katanuma I Minami R Nakashima Y Saito T Tatematsu Y Watanabe O Yoshikawa M Kojima A Miyake Y Miyata Y Shimizu K Tomii Y Yoshida M Sakamoto K Imai T Pastukhov VP Miyoshi S;GAMMA Group 《Physical review letters》2006,97(5):055001
Off-axis electron-cyclotron heating in an axisymmetric barrier mirror produces a cylindrical layer with energetic electrons, which flow through the central cell and into the end region. The layer, producing a localized bumped ambipolar potential Phi(C), forms a strong shear of radial electric fields E(r) and peaked vorticity with the direction reversal of E(r)xB sheared flow near the Phi(C) peak. Intermittent vortexlike turbulent structures near the layer are suppressed in the central cell by this actively produced transverse energy-transport barrier; this results in T(e) and T(i) rises surrounded by the layer. 相似文献