Über Pseudocinchonin und das Verhalten von Hydrochlorcinchonin

Ohne ZusammenfassungEs sei mir gestattet, auch an dieser Stelle meinem hochverehrten Lehrer, Herrn Prof. Dr. Zd. H. Skraup, für das während meiner ganzen Studienzeit mir entgegengebrachte Interesse und Wohlwollen, sowie ganz besonders für die Unterstützung und Förderung bei Ausarbeitung der vorliegenden Dissertation herzlich und aufrichtig zu danken.     

The π N → e +e−N reaction close to the vector-meson production threshold

The π^? p→e ⁺ e ^? n and π⁺ n→e ⁺ e ^? p reaction cross sections are calculated below and in the vicinity of the vector-meson (?⁰,ω) production threshold. These processes are largely responsible for the emission of e ⁺e^? pairs in pion-nucleus reactions and contribute to the dilepton spectra observed in relativistic heavy ion collisions. They are dominated by the decay of low-lying baryon resonances into vector-meson-nucleon channels. The vector mesons materialize subsequently into e ⁺ e^? pairs. Using πN→?⁰ N and πN→ωN, amplitudes calculated in the center of mass energy interval 1.4 < √s<1.8 GeV, we compute the π^? p→e ⁺ e ^? n and π⁺ n→e ⁺ e ^? p reaction cross sections in these kinematics. Below the vector-meson production threshold, the π⁰?ω interference in the e ⁺ e^? channel appears largely destructive for the π^? p→e ⁺ e ^? n cross section and constructive for the π⁺ n→e ⁺ e ^? p cross section. The pion beam and the HADES detector at GSI offer a unique possibility to measure these effects. Such data would provide strong constraints on the coupling of vector-meson-nucleon channels to low-lying baryon resonances.     

A novel strategy to verification of adulteration in alcoholic beverages based on Schlieren effect measurements and chemometric techniques

A novel strategy to evaluation of adulteration in alcoholic beverages based on the measurement of the Schlieren effect using an automated FIA system with photometric detection is proposed. The assay is based on the Schlieren effect produced when beverage samples are injected in a single-line FIA system that uses water as carrier stream and a light-emitting diode-phototransistor photometer controlled by microcomputer as detector. The flow system presents limited mixing conditions which make possible to create gradients of refractive index (Schlieren effect) in the injected sample zone. These gradients are reproducible, characteristic of each alcoholic beverage and undergo specific modifications when adulterations with water or ethanol are imposed. Schlieren effect data of brandies, cachaças, rums, whiskies and vodkas were treated by SIMCA to elaborate class models applied in the evaluation of alcoholic beverages adulteration. Samples of the original matrix of each sort of beverages were adulterated in laboratory by adding water, methanol and ethanol in levels of 5% and 10% (v/v). These samples were used as test set to validate SIMCA class models. The verification of authenticity using Schlieren effect measurements presented good results making possible to identify 100% of the beverages samples adulterated in laboratory and 93% of the actual adulterated alcoholic beverages with confidence levels of 95%. As principal advantage, the automated system does not use reagents to carry out the analysis.     

Immobilized polysiloxanes as stationary phases for high-performance liquid chromatography and solid phase extraction

Polysiloxanes immobilized onto the surfaces of porous silica particles have proven to be good stationary phases for the separation of multiresidues of pesticides and their metabolic/degradation products by reversed-phase high-performance liquid chromatography (RP-HPLC). Similar materials have proven effective for pre-concentration and clean-up procedures using solid phase extraction. The present paper describes the preparation and some applications of several of these packing materials.     

Kinetics and equilibrium of small metallic clusters: Ab initio confinement molecular dynamics study of 4

The ab initio molecular dynamics (AIMD) [1] is combined with the heuristic, successive confinement method of surveying a potential energy surface (PES) [2], thereby offering a framework for the simulation study of kinetics and equilibrium properties of metallic clusters. This approach is applied to the study of Au₄, a cluster possessing a simple but specific PES, which consists of very shallow and deep basins and due to this presents a challenge to the conventional AIMD methods. Among other things, the probabilities of the transitions between isomers have been found, and on this basis, both the time-dependent and equilibrium populations of the isomers have been calculated for the conditions typical of the NeNePo experiments [3] in the femtosecond pump-probe spectroscopy.     

A remark on the moduli field of a curve

We give a purely algebro-geometric proof of the fact that every nonsingular projective curve can be defined over a finite extension of its moduli field. This extends a result byWolfart [7] to curves over fields of arbitrary characteristic. Received: 30 November 2001