Temperature Dependence of the Mössbauer Effect on Prussian Blue Nanowires

Highly ordered Prussian blue nanowires with diameter of about 50 nm and length up to 4 m have been fabricated by an electrodepositing technology with two-step anodizing anodic aluminum oxide films. The Mössbauer spectra taken between 15 and 300 K indicate that the hyperfine parameters decrease as the temperature increases. The temperature dependence of the quadrupole splitting, the isomer shift and the spectra area are discussed. A decrease of Debye temperature for Prussian blue nanowires was found with respect to that of Prussian blue bulk.     

Synthesis of Monoclinic Form of Gd2-xNaxCuO4 by Direct Precipitation from Molten Salt

Gd,-.Na.CuO#, an interesting compound with complex magnetic behavior, has beensynthesized by a PbO-based flux method (l) and a solid state reaction (2) at temperaturesabout 1000"C. Its X-ray diffraction pattern has been indexed with tetragonal latticeparameters (l,3). Here we report a low temperature synthetic route in which the newmonoclinic form of Gd,-.Na.CuO# is obtained directly by precipitation from a moltenKOH/NaOH/KNO, solution. The SEM, EDX, XRD, XPS and magnetic characte…     

Analysis of aesculin and aesculotin in Cortex fraxini by capillary zone electrophoresis

A simple method for quantitative analysis of aesculin and aesculetin in Cortex fraxini was developed using capillary zone electrophoresis (CZE). Berberin was employed as an internal standard, The running buffer was 6 mM Na(2)B(4)O(7) and 10 mM NaH(2)PO(4) (pH 6.70). The linear calibration range was 32-256 mug ml(-1) (r=0.9996) for aesculin and 23-230 mug ml(-1) (r=0.9993) for aesculetin. The contents of aeculin and aesculetin in C. fraxini were easily determined within 12 min the pKa values of aesculin and asculetin determined by CZE were 6.56 and 5.62, respectively. A simple method for estimation of the temperature inside the capillary during running was also proposed.     

NH-S hydrogen bonding in zinc enzyme model complex with S2N2 binding set studied by normal coordinate analysis of vibrational spectra

In order to provide theoretical evidence for the existence and effect of NH-S hydrogen bonding in the zinc enzyme model complex [Zn(S-2-C6H4NHCOC6H5)2(1-MeIm)2] (1-MeIm = 1-methylimidazole) in addition to the spectroscopic and crystallographic investigations, normal coordinate analysis (NCA) was carried out using a modified Urey-Bradley force field. The vibrational frequencies of the complex with and without the NH-S hydrogen bonding as well as the corresponding internal coordinates were obtained. The good agreement found between the calculated and observed frequencies in the presence of the NH-S hydrogen bond, supports the reliability of the analysis. The stretching force constant of the NH-S hydrogen bond obtained from the calculation is 0.18 mdyne per A. The calculation shows that the N-H bond is weakened by formation of the NH-S hydrogen bond. The results are indicative of the existence of the NH-S hydrogen bond in the complex.     

单丁基磷酸酯的合成与表征

本文报道用三氯氧磷酯化、水解方法制备单丁基磷酸酯，用红外、核磁共振，质谱等方法对其结构进行了分析与表征。     

Vector-based plane-wave spectrum method for the propagation of cylindrical electromagnetic fields

We present a vector-based plane-wave spectrum (VPWS) method for efficient propagation of cylindrical electromagnetic fields. In comparison with electromagnetic propagation integrals, the VPWS method significantly reduces time of propagation. Numerical results that illustrate the utility of this method are presented.     

基于面向对象技术的多媒体CAI素材库系统

建立实用、高效的多媒体ＣＡＩ素材库是高效率、高质量开发ＣＡＩ软件的基础和关键．本文从数据模型、面向对象分析和存储模式三方面入手,提出一种支撑ＣＡＩ制作工具的素材库体系结构,并讨论该体系结构的特性和进一步研究的问题．     

Extensions of perfect GO-spaces and -discrete dense sets

In this paper, we prove that if a perfect GO-space has a -discrete dense set, then has a perfect linearly ordered extension. This answers a problem raised by H. R. Bennett, D. J. Lutzer and S. Purisch. And the result is also a partial answer to an old problem posed by H. R. Bennett and D. J. Lutzer.

     

变质量质点的动能定理与软绳问题

给出变量质点的动能定理和一对反推内力作功的表达式,并由此给出软绳问题的正确解。