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111.
Balawant S. Joshi Taikyun Rho Peter L. Rinaldi Weixia Liu Todd A. Wagler M. Gary Newton Doowon Lee S. William Pelletier 《Journal of chemical crystallography》1991,27(9):553-559
The structure of the π-molecular complex (10) was assigned on the basis of the solid state13C-nmr spectrum. The solid state13C-nmr spectrum of quinhydrone (12) has also been determined. Accurate1H and13C chemical shift assignments have been made for the compounds3,5,6,7,8, and10 on the basis of HMQC and HMBC spectral data. The π-molecular complex10 crystallizes in the space groupP21
In with cell parameters:a=4.052 (1) ?,b=6.477 (1) ?,c=19.093 (2) ?, β=90.17 (1)o,z=1,D
c
=1.400 g mc−32. Crystal and molecular structure of the title compound, C28H22O4, has been determined by an X-ray analysis of10 by direct methods from diffractometer data and refined by full-matrix least-squares 相似文献
112.
Golmaenone, a new diketopiperazine alkaloid from the marine-derived fungus Aspergillus sp 总被引:2,自引:0,他引:2
Li Y Li X Kim SK Kang JS Choi HD Rho JR Son BW 《Chemical & pharmaceutical bulletin》2004,52(3):375-376
A new diketopiperazine alkaloid, golmaenone (1). and related alkaloids, neoechinulin A (2). and L-alanyl-L-tryptophan anhydride (3). have been isolated from the culture broth of the marine-derived fungus Aspergillus sp. The structure and absolute stereochemistry of the new compound (1). was assigned by spectroscopic methods and the advanced Marfey's method. Compounds 1 and 2 exhibited a significant radical scavenging activity against 1,1-diphenyl-2-picrylhydrazyl (DPPH) with IC(50) values of 20 and 24 microM, respectively, which are similar to the positive control, ascorbic acid (IC(50), 20 microM). Compounds 1 and 2 also showed an ultraviolet-A (UV-A) (320--390 nm) protecting activity with ED(50) values of 90 and 170 microM, respectively, which are more active than oxybenzone (ED(50), 350 microM) currently being used as sunscreen. 相似文献
113.
Euplexides F (3) and G (4), novel farnesylhydroquinone glycosides, have been isolated as minor constituents of the gorgonian Euplexaura anastomosans. The structures of these compounds have been determined by combined spectroscopic methods. These compounds exhibited moderate cytotoxicity and inhibitory activity against PLA2. 相似文献
114.
The energy levels of the charm and bottom as well as the mixed flavour hyperons are calculated with the model in which the hyperons are described as bound states of a topologicalSU (2) soliton andK-, D- andB-mesons. The spectra are obtained in a modified version of the Skyrme model where the chiral symmetry breaking term in the Lagrangian density is modified so as to incorporate the different values of the decay constants of the mesons of different flavour. The predicted strange and charmed hyperon spectra are in very good agreement with the empirical values, while the bottom hyperon energies that are more sensitive to the short range dynamics are somewhat below the empirical values. The predicted hyperfine spectra are remarkably close to those obtained with the constituent quark model, more or less independently of the short-distance properties of the effective Lagrangian. We suggest that this feature reflects the presence of an induced nonabelian gauge potential generated by the interplay between “fast” and “slow” degrees of freedom in the meson-soliton system. 相似文献
115.
A digraph D is oriented if it does not contain 2-cycles.If an oriented digraph D has a directed eulerian path,it is an oriented eulerian digraph.In this paper,when an oriented eulerian digraph D has minimum out-degree 2 and a diameter d,we find the minimum order of D.In addition,when D is 2-regular with diameter 4m(m ≥ 2),we classify the extremal cases. 相似文献
116.
JaeHoon Rho 《Journal of luminescence》2011,131(1):69-71
We have measured photoluminescence (PL) spectrum of (1) thermal-annealed SrTiO3/Si thin film and undoped SrTiO3 single crystal; (2) SrTiO3 single crystal irradiated by high energy (3 MeV) proton, deuterium, and He ion beams and (3) SrTiO3 single crystal irradiated by low energy (60 keV) H+ and C− ions. Two PL emissions are induced in (1) and (2) at visible frequencies 3 and 2.45 eV, while another PL peak is induced at 2 eV in (3). When compared with our previous PL experiments on high-temperature annealed SrTiO3/SiO2/Si thin film and 3 MeV proton (H+) irradiated STO single crystal, these results confirm that the three PL emissions with blue (3 eV), green (2.45 eV), and red-orange (2 eV) frequencies originate indeed from SrTiO3. These primary-color PL effect induced at room-temperature makes STO a strong candidate material for future oxide-based optoelectronic application. 相似文献
117.
RuH2(PPh3)4-catalyzed reductive cleavage reactions of chiral allylic cyclic carbonates with ammonium formate afforded optically active (E)-allylic alcohols with excellent regioselectivity. Alternatively, hydrogenolysis of propargylic cyclic carbonates in the presence of RuH2(PPh3)4 catalyst afforded allenic alcohols as a sole products. 相似文献
118.
Yong-Jae Kim Chang-Kyu Kim Cheol-Su Kim Ju-Yong Yun Byung-Hwan Rho 《Journal of Radioanalytical and Nuclear Chemistry》1999,240(2):613-618
A time-saving and accurate technique for determining226Ra in groundwater and soil was examined, using high-resolution inductively coupled plasma-mass spectrometry (HR-ICP-MS). The
technique was applied to the determination of226Ra in groundwater and soil samples and compared with the conventional liquid scintillation counting method. This technique
was capable of completing226Ra counting within 3 minutes, without the in-growth period to allow radon and its progeny to achieve secular equilibrium with
the parent226Ra. The detection limits of HR-ICP-MS for226Ra in groundwater and soil were 0.19 mBq·1−1 and 0.75 Bq·kg−1, respectively, which were about 10 times lower than that of the liquid scintillation counter. The results obtained from HR-ICP-MS
in groundwater and soil were in accordance with those of LSC within a relative error of about 13%. 相似文献
119.
120.