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排序方式: 共有113条查询结果,搜索用时 234 毫秒
111.
New soluble and intrinsic amorphous red emitters 1 and 2 were obtained by Suzuki coupling. Due to the close molecular polarities, separation of target products from monocoupling impurities presents a challenge. The results showed highly pure 2 would be a potentially valuable fluorophore for solution-processed pure red electroluminescence in terms of visual sensitivity with respect to 1. 相似文献
112.
Jun Huang Yongxiang Zhu Junwu Chen Lianjie Zhang Junbiao Peng Yong Cao 《Macromolecular rapid communications》2014,35(22):1960-1967
DTfBT‐Th3, a new conjugated polymer based on dithienobenzothiadiazole and terthiophene, possesses a bandgap of ≈1.86 eV and a HOMO level of −5.27 eV. Due to strong interchain aggregation, DTfBT‐Th3 can not be well dissolved in chlorobenzene (CB) and o‐dichlorobenzene (DCB) at room temperature (RT), but the polymer can be processed from hot CB and DCB solutions of ≈100 °C. In CB, with a lower solvation ability, a certain polymer chain aggregation can be preserved, even in hot solution. DTfBT‐Th3 displays a field‐effect hole mobility of 0.55 cm2 V−1 s−1 when fabricated from hot CB solution, which is higher than that of the device processed from hot DCB (0.16 cm2 V−1 s−1). In DTfBT‐Th3‐based polymer solar cells, a good power conversion efficiency from 5.37% to 6.67% can be achieved with 150−300 nm thick active layers casted from hot CB solution, while the highest efficiency for hot DCB‐processed solar cells is only 5.07%. The results demonstrate that using a solvent with a lower solvation ability, as a “wet control” process, is beneficial to preserve strong interchain aggregation of a conjugated polymer during solution processing, showing great potential to improve its performances in optoelectronic devices.
113.
Liu N Zhou Y Ai N Luo C Peng J Wang J Pei J Cao Y 《Langmuir : the ACS journal of surfaces and colloids》2011,27(24):14710-14715
Organic nanowire (NW) transistor arrays with a mobility of as high as 1.26 cm(2)·V(-1)·S(-1) are fabricated by combining the dip-coating process to align the NW into arrays with the inkjet printing process to pattern the source/drain electrodes. A narrow gap of ~20 μm has been obtained by modifying the inkjet process. The all-solution process is proven to be a low-cost, high-yield, simple approach to fabricating high-performance organic NW transistor arrays over a large area. 相似文献