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91.
Isabel Brandariz José L. Barriada Teresa Vilari?o Manuel E. Sastre de Vicente 《Monatshefte für Chemie / Chemical Monthly》2004,343(6):1475-1488
Several reported procedures for calibrating glass electrodes in proton concentration are compared. Some recommendations for non-experts are also given. The examined procedures can be classified into two broad categories, namely: those based on direct potential difference measurements of solutions of known proton concentration and those that use one or several pH standards to calibrate the electrode and subsequently measure the pH of solutions containing known proton concentrations. With a single buffer, the two types of procedures lead to equivalent results. However, if two pH buffers are used, the slope of the calibration graph in proton concentration will differ from the real electrode slope to an extent proportional to the difference between the liquid junction potentials of the two buffers. Therefore, any other method is preferable under these circumstances. 相似文献
92.
José Trashorras 《Comptes Rendus Mathematique》2003,336(1):69-74
We improve the Large Deviations Principle satisfied by a Coarse Grained process already analyzed by Boucher, Ellis and Turkington [Ann. Probab. 27 (1999) 297–324]. To cite this article: J. Trashorras, C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献
93.
94.
95.
土壤盐渍化的研究进展 总被引:8,自引:0,他引:8
根据近年来国内外土壤学者在土壤盐渍化的研究成果,从土壤盐渍化的基本理论,改良方法以及预测预报方面的研究,综述了土壤盐渍化的研究现状,通过分析土壤盐渍化研究多方面存在的问题,对其发展趋势和今后研究重点进行了展望,望能为进一步的深入研究工作提供帮助. 相似文献
96.
We focus on continuous Markov chains as a model to describe the evolution of credit ratings. In this work it is checked whether a simple, tridiagonal type of generator provides a good approximation to a general one. Three different tridiagonal approximations are proposed and their performance is checked against two generators, corresponding to a volatile and a stable period, respectively. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
97.
First order necessary conditions and duality results for general inexact nonlinear programming problems formulated in nonreflexive
spaces are obtained. The Dubovitskii–Milyutin approach is the main tool used. Particular cases of linear and convex programs
are also analyzed and some comments about a comparison of the obtained results with those existing in the literature are given. 相似文献
98.
Berry Frank J. Ren Xiaolin Gancedo J. Ramón Marco José F. 《Hyperfine Interactions》2004,156(1-4):335-340
Hyperfine Interactions - Perovskite-related phases of the type LaFe1?x Co x O3 (x=0 and 0.5) have been synthesised by milling techniques. The materials are of smaller particle size and more... 相似文献
99.
Guan Wu WANG* Li Juan JIAO Er Hong HAO Yong Ming LU You Jun YANG Department of Chemistry University of Science Technology of China Hefei 《中国化学快报》2004,15(5)
Water-soluble fullerenes not only have a number of important applications in biological chemistry1, but also form ordered aggregate structures that can be utilized in materials science2. There are reports that some water-soluble fullerene derivatives can form ordered structures in water, such as vesicle, nanorod and nanoparticle2-5. However, relatively few reports on the aggregation process have been reported. Knowledge of factors that affect the cluster formation in solution is of consider… 相似文献
100.
Three novel zinc complexes [Zn(dbsf)(H2O)2] ( 1 ), [Zn(dbsf)(2,2′‐bpy)(H2O)]·(i‐C3H7OH) ( 2 ) and [Zn(dbsf)(DMF)] ( 3 ) (H2dbsf = 4,4′‐dicarboxybiphenyl sulfone, 2,2′‐bpy = 2,2′‐bipyridine, i‐C3H7OH = iso‐propanol, DMF = N,N‐dimethylformamide) were first obtained and characterized by single crystal X‐ray crystallography. Although the results show that all the complexes 1–3 have one‐dimensional chains formed via coordination bonds, unique three‐dimensional supramolecular structures are formed due to different coordination modes and configuration of the dbsf2? ligand, hydrogen bonds and π–π interactions. Iso‐propanol molecules are in open channels of 2 while larger empty channels are formed in 3 . As compared with emission band of the free H2dbsf ligand, emission peaks of the complexes 1–3 are red‐shifted, and they show blue emission, which originates from enlarging conjugation upon coordination. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献