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991.
The low-temperature single-crystal spectrum of TMCBD has revealed a low-lying triplet state at 25 718 cm-1 (72·5 kcal/mol). The observed band is ascribed to a 3 Au (3 A 2) ← 1 Ag nπ* transition on the basis of its small singlet-triplet splitting, its polarization behaviour, and its vibrational structure. The 3 Au state is first-order spin-orbit coupled to either or both of the 1 B 2u or 1 B 3u states. No evidence for two or more nπ* transitions was found. Several multi-membered progressions in the carbonyl wagging mode indicate the presence of a distorted excited state, in which the carbonyl carbons attain a pyramidal conformation. Analysis of the site symmetry shows that TMCBD is distorted to a boat-shaped C 2v structure in its triplet nπ* state. 相似文献
992.
We prove that an integrated version of the Gurau colored tensor model supplemented with the usual Bosonic propagator on U(1)4 is renormalizable to all orders in perturbation theory. The model is of the type expected for quantization of space-time in 4D Euclidean gravity and is the first example of a renormalizable model of this kind. Its vertex and propagator are four-stranded like in 4D group field theories, but without gauge averaging on the strands. Surprisingly perhaps, the model is of the ${\phi^6}$ rather than of the ${\phi^4}$ type, since two different ${\phi^6}$ -type interactions are log-divergent, i.e. marginal in the renormalization group sense. The renormalization proof relies on a multiscale analysis. It identifies all divergent graphs through a power counting theorem. These divergent graphs have internal and external structure of a particular kind called melonic. Melonic graphs dominate the 1/N expansion of colored tensor models and generalize the planar ribbon graphs of matrix models. A new locality principle is established for this category of graphs which allows to renormalize their divergences through counterterms of the form of the bare Lagrangian interactions. The model also has an unexpected anomalous log-divergent ${(\int \phi^2)^2}$ term, which can be interpreted as the generation of a scalar matter field out of pure gravity. 相似文献
993.
994.
Joseph K. Rugutt Nikolaus H. Fischer Marcus A. Nauman Thomas J. Schmidt Dana K. Berner 《光谱学快报》2013,46(5):799-818
The two known cadinanes 2-hydroxy-8α-hydroxycalamenene and 2-hydroxy-8α-angeloyloxycalamenene were isolated from a Louisiana population of Heterotheca subaxillaris. Their 13C NMR spectra were fully assigned by the application of HETCOR, COLOC, COSY, NOESY and DEPT experiments. It was shown on the basis of NOESY experiments that both cadinanes require revision at the stereogenic centre C-7. 相似文献
995.
Nathan A. Stump George K. Schweitzer Lester L. Pesterfield Joseph R. Peterson George M. Murray 《光谱学快报》2013,46(8):1421-1432
Abstract Salts of the [Eu(2,6-pyridinedicarboxylate)3]3- complex anion and various monovalent inorganic and organic counterions (Li+, Na+, K+, Rb+, Cs+, NH4 +, and pyridinium+) have been synthesized and studied by emission spectroscopy. The Eu3+ ion emission spectra exhibited by these salts have been observed with high resolution (less than 1.0 cm?1) and at low temperature (77 K). The emission spectra of these compounds indicate that changing the attached counterion does not affect the site symmetry observed by the europium ion beyond slight distortions indicated by small shifts in the energies of the Eu3+ electronic levels. 相似文献
996.
Joseph M. Maubach 《Applications of Mathematics》2005,50(3):309-321
Numerical experiments in J. Maubach: Local bisection refinement and optimal order algebraic multilevel preconditioners, PRISM-97 conference Proceedings, 1977, 121–136 indicated that the refinement with the use of local bisections presented in J. Maubach: Local bisection refinement for n-simplicial grids generated by reflections, SIAM J. Sci. Comput. 16 (1995), 210–227 leads to highly locally refined computational 2-meshes which can be very efficiently load-balanced with the use of a space-filling curve. This paper introduces the construction of this curve which can be produced at almost no costs, proofs that all its properties are invariant under local bisection, and comments on the 3-dimensional case.With the use of a space-filling curve (which passes through all triangular elements), load balancing over several processors is trivial: The load can be distributed over N processors by cutting the curve into N almost equilength parts. Each processor then operates on the triangles which are passed by its part of the curve. 相似文献
997.
The J/Ψ decay into a baryon pair and a pseudoscalar meson is computed, for some channels, in lowest order in perturbative QCD, modeling the baryon with a quark-diquark system. We use a set of parameters that has been proposed by some authors in order to fit the proton magnetic form factor G M P, the angular distribution of protons in the processes γγ → pp?, γp → γp and the width of η_c → γγ. 相似文献
998.
Joseph F. Grotowski 《Journal of Geometric Analysis》1993,3(3):279-292
We examine the existence problem for harmonic maps between the three-dimensional ball and the two-sphere. We utilize results on the classification of harmonic maps into hemispheres and a result on the regularity of the weak limit of energy minimizers over the class of axially symmetric maps to establish the existence of asmooth harmonic extension for boundary data suitably “concentrated” away from the axis of symmetry. In addition, we establish convergence results for the harmonic map heat flow problem for suitably “concentrated” axially symmetric initial and boundary data. 相似文献
999.
Working in a quantum logic framework and using the idea of Galois connections, we give a natural sufficient condition for superposition and inaccessibility to give the same closure map on sets of states. 相似文献
1000.
Joseph D. Masters 《Geometriae Dedicata》2006,119(1):17-33
We show that every closed, virtually fibered hyperbolic 3-manifold contains immersed, quasi-Fuchsian. 相似文献