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991.
Jung-Woo Kim 《Tetrahedron letters》2006,47(27):4745-4748
We synthesized amphiphilic polymer-supported N-heterocyclic carbene (NHC) precursor resins by loading polyethylene glycol (PEG) containing imidazolium groups on Merrifield resin. These PS-PEG-NHC precursor resins were compatible with water and readily formed a stable complex with palladium. These PS-PEG-NHC-Pd catalysts showed excellent catalytic activity for Suzuki cross-coupling reactions of various aryl iodides and bromides with phenylboronic acid in water than the previously described polystyrene based catalysts. In addition, the PS-PEG-NHC-Pd catalysts continued to provide excellent catalytic activity in Suzuki cross-coupling reactions after five consecutive recycles. 相似文献
992.
Simple tandemly organized (GTG)n/(CAC)n sequences are spread throughout the human chromosomes. The most informative DNA fingerprints for the testing of pedigrees and/or paternity were obtained with the simple triplet repeat probe (GTG)5 or its complement (CAC)5. These hypervariable simple-repeat fragments are stably inherited in a Mendelian fashion. Using these highly discriminating probes, all human individuals could, theoretically, be differentiated, except for genetically identical monozygotic twins. Examples from actual case work are reported and pertinent advantages of this methodology are discussed. 相似文献
993.
V. Spěvá?ková J. Jhn M. Pra?ská 《Journal of Radioanalytical and Nuclear Chemistry》1983,80(1-2):115-120
The determination of uranium in natural waters by XRF analysis after its preconcentration with some organic precipitants is described.109Cd source is used for the excitation of L-series X-rays of uranium. Separation yield, kinetics of coprecipitation and the possibility of preparing thin-layer samples for XRF analysis were studied in detail for uranium concentration with α-nitroso-β-naphtol, methylene blue with ammonium thiocyanate, tannin with urotropine and other precipitants. A procedure using coprecipitation of uranium with α-nitroso-β-naphtol from 500 ml samples of surface or waste, waters is proposed. 相似文献
994.
Milan Trsic Kim Wagstaff William G. Laidlaw 《International journal of quantum chemistry》1982,22(5):903-910
An ab initio version of the Hartree–Fock–Slater method is applied to obtain molecular orbitals and eigenvalues for S5N6. The electronic structure, bonding, stability, and electronic spectrum are discussed. 相似文献
995.
A kinetic method for the determination of Te based on its inhibitory effect on the PdII-catalysed reaction between pyronine G and H2PO2- is described. The influence of experimental variables on the rate of the process and the potential interfering effect of a large number of ions has been studied. Under the selected experimental conditions: 6 x 10(-5) M pyronine G; 0.6 M H2PO2-; pH 2.6, adjusted with Britton-Robinson buffer; 0.80 microgram ml-1 of PdII; and a temperature of 22 +/- 0.2 degrees C, Te was determined in the concentration range 0.08-0.85 microgram ml-1. The method was applied to the determination of Te in waters and lead concentrates. 相似文献
996.
Summary An azomethine H derivative, 1-(2,4-dihydroxybenzylidene-amino)-8-hydroxynaphthalene-3,6-disulphonic acid (azomethine HR) was examined and proposed as a spectrophotometric reagent for boron, as compared with azomethine H. Azomethine HR reacts with boron in aqueous solution (pH 7.5) to form a yellow complex having an absorption maximum at 425 nm. The sensitivity is 3.5-fold greater than with azomethine H when the same reagent concentration is applied. Basic conditions for the determination of boron have been worked out. The method is applicable to sea and hot spring waters. The standard deviation is ±2.1%.
Spektralphotometrische Borbestimmung mit einem Azomethin H-Derivat相似文献
997.
S. Unterricker Kim Jung Ho W. Stolz D. Degering 《Journal of Radioanalytical and Nuclear Chemistry》1988,122(2):271-278
The underground radiation conditions in the mining district of Freiberg and in a rock salt environment of the Werra district were investigated. In a salt mine a very low natural activity level can be found. For selection of proper shielding materials a low-level -spectrometer and an optimum sample geometry must be used. The photopeak differences between sample and blank are small in most cases. Considerable differences can be found in the continuous background below 0.7 MeV. 相似文献
998.
Rory?H.?Uibel Emily?C.?Heider Jennifer?L.?Gasser Joel?M.?HarrisEmail author Edward?M.?Eyring Sergio?Petrucci 《Journal of solution chemistry》2005,34(5):499-514
Advances have been made recently in broadening the accessible ultrasonic absorption frequency range and improving the detectability of minor species present in solution using Raman spectroscopy. Development of chemometric techniques in these areas needs to keep pace with the improvement of these experimental methods. Refinements in the analysis of ultrasonic and Raman data based on multivariable least squares and factor analysis, respectively, are examined to investigate the kinetics of zinc thiocyanate complex formation in water. Analysis of ultrasonic absorption relaxation spectra verified that the observed process in aqueous Zn(SCN)2 involves substitution of water from the first coordination shell of Zn2+. Use of a multivariable least-squares error surface is described that enhances the reliability of assigned frequencies of ultrasonic absorption maxima. Factor analysis of Raman scattering data provided direct evidence that at least four complex species, such as Zn(SCN)+ and Zn(SCN)2, are simultaneously present in the aqueous zinc thiocyanate solutions. 相似文献
999.
Fausi?RassoulEmail author Heinz?L?ster Volker?Richter 《Monatshefte für Chemie / Chemical Monthly》2005,136(8):1501-1507
Summary. L-Carnitine, L-(−)-β-hydroxy-γ-trimethylaminobutyrate, plays an important role as a factor necessary for the transport of long-chain fatty acids into the mitochondria. In order to investigate the influence of L-carnitine on hyperlipidaemias, the experimental model of the sucrose-induced hypertriglyceridaemia of the rat was used. In these experiments L-carnitine in the dose of 11 mg per day and 100 g body weight (over the period of 1 week) was able to antagonize the sucrose-induced hypertriglyceridaemia and the increase of serum free fatty acid level in female rats of the Wistar strain. Carnitine administration did not change the activities of lipogenic enzymes and fatty acid synthesis in the liver. However, L-carnitine increases the rate of hepatic fatty acid oxidation. Our results indicate a hypotriglyceridemic and free fatty acid lowering effect of L-carnitine, and suggest the use of this compound in the therapy of hyperlipidaemias. 相似文献
1000.
Kang MS Kim JH Kim YJ Won J Park NG Kang YS 《Chemical communications (Cambridge, England)》2005,(7):889-891
The ionic conductivity of polymer electrolytes and their interfacial contact with dye-attached TiO2 particles were enhanced markedly by the addition of amorphous oligomer into polymer electrolytes, resulting in very high overall energy conversion efficiency. 相似文献