FORMATION OF THE CRYSTALLINE INCLUSION COMPLEX BETWEEN β-CYCLODEXTRIN AND POLYPROPYLENE

PP can be included in the cavities of cyclodextrin (CD). The crystalline inclusion complex between β-CD and lowmolecular weight polypropylene (PP) was obtained and investigated. α-CD and γ-CD did not form crystalline inclusioncomplexes with PP. The FTIR spectra, TGA, X-ray diffraction spectra were studied, ~1H-NMR spectra and ~(13)C CP/MAS NMR spectra were used to characterize the crystalline inclusion complexes.     

Asymmetric aziridination of chalcones catalyzed by a novel backbone 1,8-bisoxazolinylanthracene (AnBOX)-copper complex

Highly enantioselective aziridination of chalcones catalyzed by a novel backbone 1,8-bisoxazolidinylanthracene (AnBOX) and CuOTf with up to >99% ee and the opposite enantioselectivity compared with the ligands of Evans are described.     

Cavity-enhanced spectroscopy in optical fibers

Cavity-enhanced methods have been extended to fiber optics by use of fiber Bragg gratings (FBGs) as reflectors. High-finesse fiber cavities were fabricated from FBGs made in both germanium/boron-co-doped photosensitive fiber and hydrogen-loaded Corning SMF-28 fiber. Optical losses in these cavities were determined from the measured Fabry-Perot transmission spectra and cavity ring-down spectroscopy. For a 10-m-long single-mode fiber cavity, ring-down times in excess of 2 ms were observed at 1563.6 nm, and individual laser pulses were resolved. An evanescent-wave access block was produced within a fiber cavity, and an enhanced sensitivity to optical loss was observed as the external medium's refractive index was altered.     

Adaptive time-domain filtering for real-time spectral discrimination in a Michelson interferometer

We present a method of spectral discrimination that employs time-domain processing instead of the typical frequency-domain analysis and implement the method in a Michelson interferometer with a nonlinear mirror scan. The technique yields one analog output value per scan instead of a complete interferogram by directly filtering a measured scan with a reference function in the time domain. Such a procedure drastically reduces data-processing requirements downstream. Additionally, using prerecorded interferograms as references eliminates the need to compensate for scan nonlinearities, which broadens the field of usable components for implementation in miniaturized sensing systems. With our efficient use of known spectral signatures, we demonstrate real-time discrimination of 633- and 663-nm laser sources with a mirror scan length of 1 microm , compared with the Rayleigh criterion of 7 microm.     

大孔吸附树脂对肿瘤坏死因子吸附性能的研究

选用NK-110、碳化树脂和MET-10043种大孔吸附树脂,通过对树脂吸附量的测定,吸附动力学曲线和吸附等温线的描述等方法,研究了3种大孔吸附树脂对血浆中TNFα的吸附性能,结果表明NK-110和MET-1004对TNFα的吸附量较高,其中又以MET-1004的吸附速率最快     

Ionization of NF3 by electron impact

The ionization and dissociative ionization of NF₃ by electron impact has been measured by Fourier transform mass spectrometry (FTMS). The total ionization cross-section rises to a maximum value of 2.4±0.4×10⁻¹⁶ cm² at 140 eV. Estimates of the total single ionization cross-section using ab initio energies with the binary encounter Bethe (BEB) [Y.K. Kim, M.E. Rudd, Phys. Rev. A 50 (1994) 3594] or Deutsch–Märk [Int. J. Mass Spec. 197 (2000) 37] models are roughly twice the measured values. The partial cross-sections creating NF_x⁺ (x=0, 1, 2, 3), F⁺, and NF_x²⁺ (x=1, 2, 3) are reported. Differences between the FTMS results and quadrupole data and fast atom beam results of Tarnovsky et al. [Int. J. Mass Spectrom. Ion Processes 133 (1994) 175] are discussed.     

导管螺旋桨气动性能的风洞试验研究

对自行研制的一船用空气推进导管螺旋桨系统的导管和桨后整流支架的空气动力学性能在试验雷诺数范围进行了风洞模型试验研究.研究结果表明,导管和桨后整流支架明显改善了系统的空气动力学性能,螺旋桨系统的推力系数和效率都有较明显提高,螺旋桨系统的原地静推力和倒车性能也得到很大改善.     

Al-X谱线电子碰撞展宽的理论研究

 使用R-矩阵方法和半经验方法,计算了高价离子Al-X 2s^{2 1}S-2s2p¹P⁰共振谱线在电子密度为10¹⁷cm^-3时的线宽和线移随温度的变化关系,两种计算得到的线宽结果符合得比较好。使用半经验方法可以获得大量谱线的电子碰撞展宽,以满足需要大量数据的等离子体不透明度的计算的需要。使用半经验方法同时得到了其它一些谱线的电子碰撞宽度。