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51.
Reaction of 2 with bis(tributyltin) in the presence of 3 mol % Pd2(dba)3, 6 mol % XPhos, and 30 equiv of LiBr in wet and air bubbled THF at reflux for 8 h afforded the desired products 3 in 73–74% yields. The cross-coupling reaction of 3a with aryl iodides in the presence of 10 mol % Pd(PPh3)4 and 10 mol % CuI afforded the coupled products 4a–p in 47–90% yields. The coupling reaction of 3b with various alkynyl bromides having aryl-, alkyl, or trialkylsilyl group also afforded the corresponding 1,3-enynes 5a–g in 61–77% yields. 相似文献
52.
Efficient Diketopyrrolopyrrole‐Based Small‐Molecule Bulk‐Heterojunction Solar Cells with Different Electron‐Donating End‐Groups 下载免费PDF全文
Yu Jin Kim Jang Yeol Back Seul‐Ong Kim Chan‐Woo Jeon Prof. Chan Eon Park Prof. Yun‐Hi Kim 《化学:亚洲杂志》2014,9(9):2505-2513
A series of small molecules that contained identical π‐spacers (ethyne), a central diketopyrrolopyrrole (DPP) unit, and different aromatic electron‐donating end‐groups were synthesized and used in organic solar cells (OSCs) to study the effect of electron‐donating groups on the device performance. The three compounds, DPP‐A‐Ph , DPP‐A‐Na , and DPP‐A‐An , possessed intense absorption bands that covered a wide range, from 350 to 750 nm, and relatively low HOMO energy levels, from ?5.50 to ?5.55 eV. DPP‐A‐An , which contained anthracene end‐groups, demonstrated a stronger absorbance and a higher hole mobility than DPP‐A‐Ph , which contained phenyl groups, and DPP‐A‐Na , which contained naphthalene units. The power‐conversion efficiencies (PCEs) of OSCs based on organic:PC71BM blends (1:1, w/w) with a processed DIO additive were 3.93 % for DPP‐A‐An , 3.02 % for DPP‐Na , and 2.26 % for DPP‐A‐Ph . These findings suggest that a DPP core that is functionalized with electron‐donating capping groups constitutes a promising new class of solution‐processable small molecules for OSC applications. 相似文献
53.
Eun Hee-Chul Yang Hee-Chul Kim Hyung-Ju Kim Sung-Jun Jeon Min-Ku Lee Keun-Young Seo Bum-Kyoung 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(9):3735-3744
Journal of Radioanalytical and Nuclear Chemistry - CaCO3 powder containing C-14, which has a long half-life, is generated from the treatment process of spent activated carbons from the air cleaning... 相似文献
54.
Ji-Woo Hong Da-Hye Gam Jun-Hee Kim Sung-Jin Jeon Ho-Seob Kim Jin-Woo Kim 《Molecules (Basel, Switzerland)》2021,26(9)
The aim of this study was to remove 5-hydroxymethyl furfural (5-HMF) and furfural, known as fermentation inhibitors, in acid pretreated hydrolysates (APH) obtained from Scenedesmus obliquus using activated carbon. Microwave-assisted pretreatment was used to produce APH containing glucose, xylose, and fermentation inhibitors (5-HMF, furfural). The response surface methodology was applied to optimize key detoxification variables such as temperature (16.5–58.5 °C), time (0.5–5.5 h), and solid–liquid (S-L) ratio of activated carbon (0.6–7.4 w/v%). Three variables showed significant effects on the removal of fermentation inhibitors. The optimum detoxification conditions with the maximum removal of fermentation inhibitors and the minimum loss of sugars (glucose and xylose) were as follows: temperature of 36.6 °C, extraction time of 3.86 h, and S-L ratio of 3.3 w/v%. Under these conditions, removal of 5-HMF, furfural, and sugars were 71.6, 83.1, and 2.44%, respectively, which agreed closely with the predicted values. When the APH and detoxified APH were used for ethanol fermentation by S. cerevisiae, the ethanol produced was 38.5% and 84.5% of the theoretical yields, respectively, which confirmed that detoxification using activated carbon was effective in removing fermentation inhibitors and increasing fermentation yield without significant removal of fermentable sugars. 相似文献
55.
Hyun-Shik Yun Hongkyun Lee Young-Tae Park Min-Kyu Ji Akhil N. Kabra Chung Jeon Byong-Hun Jeon Jaeyoung Choi 《Applied biochemistry and biotechnology》2014,173(8):2054-2064
Microalgae were selected and isolated from acid mine drainage in order to find microalgae species which could be cultivated in low pH condition. In the present investigation, 30 microalgae were isolated from ten locations of acid mine drainage in South Korea. Four microalgae were selected based on their growth rate, morphology, and identified as strains of KGE1, KGE3, KGE4, and KGE7. The dry biomass of microalgae species ranged between 1 and 2 g L?1 after 21 days of cultivation. The growth kinetics of microalgae was well described by logistic growth model. Among these, KGE7 has the highest biomass production (2.05?±?0.35 g L?1), lipid productivity (0.82?±?0.14 g L?1), and C16–C18 fatty acid contents (97.6 %). These results suggest that Scenedesmus sp. KGE 7 can be utilized for biodiesel production based on its high biomass and lipid productivity. 相似文献
56.
Jinwon Jeon Dr. Yu-Tao He Sanghoon Shin Prof. Dr. Sungwoo Hong 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(1):287-291
The photocatalyzed ortho-selective migration on a pyridyl ring has been achieved for the site-selective trifluoromethylative pyridylation of unactivated alkenes. The overall process is initiated by the selective addition of a CF3 radical to the alkene to provide a nucleophilic alkyl radical intermediate, which enables an intramolecular endo addition exclusively to the ortho-position of the pyridinium salt. Both secondary and tertiary alkyl radicals are well-suited for addition to the C2-position of pyridinium salts to ultimately provide synthetically valuable C2-fluoroalkyl functionalized pyridines. Moreover, the method was successfully applied to the reaction with P-centered radicals. The utility of this transformation was further demonstrated by the late-stage functionalization of complex bioactive molecules. 相似文献
57.
Jinny Claire Lee Hye Yun Kim Sejin Lee Jisu Shin Hyunjin Vincent Kim Kyeonghwan Kim Seungyeop Baek Donghee Lee Hanna Jeon DaWon Kim Seung‐Hoon Yang Gyoonhee Han Keunwan Park Jaeho Choi Jinwoo Park Jason A. Moss Kim D. Janda YoungSoo Kim 《Angewandte Chemie (International ed. in English)》2020,59(28):11491-11500
Amyloid‐β (Aβ) oligomers are implicated in Alzheimer disease (AD). However, their unstable nature and heterogeneous state disrupts elucidation of their explicit role in AD progression, impeding the development of tools targeting soluble Aβ oligomers. Herein parallel and anti‐parallel variants of Aβ(1–40) dimers were designed and synthesized, and their pathogenic properties in AD models characterized. Anti‐parallel dimers induced cognitive impairments with increased amyloidogenesis and cytotoxicity, and this dimer was then used in a screening platform. Through screening, two FDA‐approved drugs, Oxytetracycline and Sunitinib, were identified to dissociate Aβ oligomers and plaques to monomers in 5XFAD transgenic mice. In addition, fluorescent Astrophloxine was shown to detect aggregated Aβ in brain tissue and cerebrospinal fluid samples of AD mice. This screening platform provides a stable and homogeneous environment for observing Aβ interactions with dimer‐specific molecules. 相似文献
58.
Min Ku Jeon Kweon Ho Kang Geun Il Park Young Soon Lee 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(2):513-517
Chlorination reaction behavior of Zircaloy-4 (Zry-4) cladding hulls was demonstrated by using a quartz reactor system. By
reacting at 380 °C for 3 h, mass of the Zry-4 hulls decreased by 65.8 wt% with Cl2 utilization of 87.1 mol%. Composition of collected product was analyzed and it was revealed that concentration of Zr was
higher than 99.97 wt%. The purity of Zr in the experimental result was higher than expectation when considering Sn (1.31 wt%)
and Fe (0.25 wt%) contents which can produce gaseous SnCl4 and FeCl3 at the experimental condition. Theoretical calculations were performed to clarify the high purity of Zr by using the HSC
code. The simulation results revealed that formation of ZrCl4 is more preferred than SnCl4, FeCl3, and CrCl3. The preference of chloride formation was confirmed by the theoretical calculation, and it was suggested that the major constituents
of Zry-4 might react with Cl2 to produce chlorides in an order of ZrCl4 > CrCl3 > SnCl4 > FeCl3. It was also suggested that continuous removal of ZrCl4 and sufficient supply of Zr source during the chlorination reaction might have contributed to the high purity of Zr. 相似文献
59.
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