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421.
Jelena Mijatovic Wolfgang H. Binder Frank Kubel Wolfgang Kantner 《Macromolecular Symposia》2002,181(1):373-382
The phenomenon of thixotropy of melamine-formaldehyde (MF) resins has been investigated. A series of MF-resins with varying F/M ratios, different condensation times and pH during the condensation has been prepared. The storage stability at room temperature was measured using viscosimetry, polarization microscopy, NMR-spectroscopy and XRD. The visible changes observed in polarization microscopy (i. e. the formation of micron sized structures) correlate with the increase of viscosity related to the formation of thixotropy. The formation of a transient network can be concluded on basis of nmr-relaxation measurements and viscosimetry. 相似文献
422.
423.
Snežana Radisavljević Ana Kesić Dušan Ćoćić Vladimir Marković Jelena Milovanović Biljana Petrović Ana Rilak Simović 《应用有机金属化学》2023,37(1):e6922
In this work we synthesized new monofunctional gold(III) complex [Au(Cl-Ph-tpy)Cl]Cl2 (Cl-Ph-tpy = 4′-[4-chlorophenyl]-2,2′:6′, 2″-terpyridine). This complex was characterized by UV–Vis, NMR, IR, and ESI-MS spectrometry. The kinetic study of the substitution reactions of the Au-Cl-Ph-tpy complex with biomolecules showed that the rate constants depend on the nature of the entering nucleophile. Based on the calculated values of entropy (∆H≠ > 0) and enthalpy (∆S≠ < 0) the proposed substitution mechanism is associative. Additionally, the relative stability and thermodynamic properties of Au-Cl-Ph-tpy complex were compared with the analogue Au-tpy complex by the B3LYP/def2-svp method. DNA/BSA binding studies showed that Au-Cl-Ph-tpy complex interacts with CT DNA through the intercalation and moderately quenches the fluorescence of tryptophan residues in serum albumin (BSA). Molecular docking confirmed results obtained by spectroscopic experiments and suggested site I (subdomain IIA) for binding of Au complex to BSA. We demonstrated that the Au chlorophenyl terpyridine complex possessed significant in vitro cytotoxic activity against human oral squamous carcinoma cells (CAL-27), induced apoptosis, inhibited proliferation of CAL-27 cells, and induced cell cycle disturbance. Treatment of CAL-27 cells with the Au complex enhanced expression of cyclin-dependent kinase inhibitors p21 and p27, resulting in cell cycle arrest in the G1 phase, reduced the percentage of CAL-27 cells in S phase and decreased expression of Ki-67. Additionally, Au complex reduced expression of phosphorylated STAT3 and downstream regulated molecules associated with cancer stemness, NANOG, and Sox2 protein. 相似文献
424.
Nikolić Nebojša D. Lović Jelena D. Maksimović Vesna M. 《Journal of Solid State Electrochemistry》2023,27(7):1889-1900
Journal of Solid State Electrochemistry - The influence of chronopotentiometry response on the morphology and structure of galvanostatically synthesized tin dendritic particles has been... 相似文献
425.
Simović Andjela Stevanović Sanja Milovanović Branislav Etinski Mihajlo Bajat Jelena B. 《Journal of Solid State Electrochemistry》2023,27(7):1821-1834
Journal of Solid State Electrochemistry - In this work, six groups of non-toxic compounds were tested as inhibitors for mild steel in 1 M HCl solution: glycine (Gly), glutamic acid (Glu),... 相似文献
426.
Ciglenečki Irena Orlović-Leko Palma Vidović Kristijan Simonović Niki Marguš Marija Dautović Jelena Mateša Sarah Galić Ivo 《Journal of Solid State Electrochemistry》2023,27(7):1781-1793
Journal of Solid State Electrochemistry - This paper describes the application of a methodology, which primarily involves low-cost voltammetry, to rapidly track the reactivity (i.e. surfactant... 相似文献
427.
Dr. Matko Mužević Assoc. Prof. Dr. Igor Lukačević Ivan Kovač Dr. Davor Gracin Andreja Žužić Prof. Dr. Jelena Macan Asst. Prof. Dr. Maja Varga Pajtler 《Chemphyschem》2023,24(9):e202200837
Inorganic perovskite CaMnO was proposed as a substitution for the TiO anatase in electron transport layers of solar cells containing the hybrid perovskite CH NH PbI based on increased mobility of electrons and better optical matching. Due to a suitable band gap concerning the absorption of sunlight, we investigate the potential of CaMnO and similar manganite perovskites, where Ca is replaced by either Sr, Ba or La, as an absorber layer in inorganic perovskite solar cells. In this study, we have used optical measurements on the synthesized AMnO (A=Ca, Sr, Ba, La) samples to aid density functional theory calculations (DFT) in order to accurately simulate the electronic and optical properties of AMnO compounds and gauge their potential for the role of absorber layer. Both experimental measurements and theoretical calculations show suitable band gap of 1.1-1.5 eV, depending on the compound, and absorption coefficients of the order of cm in the visible part of the spectrum. 相似文献