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101.
Carbon nanotube–supported palladium nanoparticles prepared by a supercritical fluid deposition method show high activities for catalyzing Suzuki coupling reactions, and the catalysts can be recycled and reused at least six times without losing activity. 相似文献
102.
Shinn‐Horng Chen Shiao‐Wen Hwang Yun Chen 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):883-893
Two, novel copoly(aryl ether)s ( P1 and P2 ) consisting of alternate, isolated electron‐ and hole‐transporting fluorophores were synthesized and characterized. Furthermore, we investigated the optical, photoluminescent (PL), and electrochemical properties of copoly(aryl ether)s P1 – P5 . The PL spectra of these polymers in film states showed maximum peaks around 420–498 nm. However, compared with the PL spectra of corresponding model compounds M1 – M5 , the emissions of P1 and P2 were compositions of the two isolated fluorophores, and that of P3 was dominated by the fluorophores with a longer emissive wavelength via the energy transfer. The formation of an interchain interaction in P4 and P5 was also observed. The highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels of these copolymers were measured by cyclic voltammetry. Both the electron and hole affinities could be enhanced simultaneously because of the introduction of isolated hole‐transporting naphthalene (or fluorene) and electron‐transporting bis‐1,3,4‐oxadiazole segments. The single‐layer devices (Al/polymer/indium tin oxide) of P1 , P2 , and P4 revealed blue or blue‐green electroluminescence, but that of P3 emitted yellow light because of the excimer emission. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 883–893, 2004 相似文献
103.
Ping‐Chieh Wang Wen‐Yen Chiu Chia‐Fen Lee Tai‐Horng Young 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5695-5705
A magnetic poly(methyl methacrylate) (PMMA) composite latex was prepared by soapless emulsion polymerization in the presence of ferrofluid, and the ferrofluid was prepared by means of a coprecipitation method. The effects of various polymerization parameters, such as the monomer concentration, ferrofluid content, and initiator concentration, on the conversion curve and particle size of the magnetic composite latex particles were examined in detail. The results showed that two nucleation mechanisms were involved according to the polymerization conditions. In the monomer‐rich and less ferrofluid system, self‐nucleation of PMMA was dominant over the entire course of emulsion polymerization. In the ferrofluid‐rich system, seeded emulsion polymerization was the main course to form the magnetic composite latex particles. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5695–5705, 2004 相似文献
104.
利用卢瑟夫背散射/沟道技术和金属有机化学气相沉积方法, 对蓝宝石衬底上 在不同温度、压强下生长的Ga2+xO3-x薄膜进行结构和结晶品质的测量与分析; 并结合高分辨X射线衍射分析技术, 通过对其对称(402)面的θ–2θ及ω扫描, 确定了其结构类型及结晶品质. 实验表明: 在相同的生长温度(500 ℃)下, 结晶品质随压强的下降而变好, 生长压强为15 Torr (1 Torr=133.322 Pa)的样品其结晶品质最好, 沿轴入射之比χmin值为14.5%; 在相同的生长压强(15 Torr)下, 结晶品质受生长温度的影响不大, 所以, 生长温度不是改变结晶品质的主要因素; 此外, 在相同的生长条件下制备的样品, 分别经过700, 800和900 ℃退火后, 其结晶品质随退火温度的变化而变化. 退火温度为800 ℃的样品的结晶品质最好, χmin值为11.1%; 当退火温度达到900 ℃时, 样品部分分解; 经热处理的样品其X射线衍射谱中有一个强的Ga2O3 (402)面衍射峰, 其半峰全宽为0.5°, 表明该Ga2O3外延膜是(402)择优取向.
关键词:
氧化镓
卢瑟夫背散射
X射线衍射
结晶品质 相似文献
105.
Effect of side chain conjugation lengths on photovoltaic performance of two‐dimensional conjugated copolymers that contain diketopyrrolopyrrole and thiophene with side chains 下载免费PDF全文
You‐Ren Liu Li‐Hsin Chan Horng‐Yi Tang 《Journal of polymer science. Part A, Polymer chemistry》2015,53(24):2878-2889
Two new two‐dimensional conjugated copolymers that contain diketopyrrolopyrrole and thiophene with different π conjugation lengths as side chains, called PDPPMTD and PDPPBTD , were designed and synthesized for use in polymer solar cells (PSCs). The resulting copolymers in the thin film state displayed broad absorption in the visible range with an absorption edge at over 1000 nm, and both had relatively low‐lying HOMO levels, at ?5.20 and ?5.18 eV for PDPPMTD and PDPPBTD , respectively. The power conversion efficiency (PCE) of the PSC that was based on PDPPBTD /PC61BM (w/w = 1:2) reached 4.10 % with a Jsc of 14.5 mA/cm2, a Voc of 0.59 V and an FF of 48%, while PDPPMTD /PC61BM (w/w = 1:2) had a PCE of 2.96% with a Jsc of 12.6 mA/cm2, a Voc of 0.60 V, and an FF of 39%. These results indicate that subtle tuning of the chemical structure can significantly influence Jsc and FF. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2878–2889 相似文献
106.
In this paper, we propose an ordinal optimization theory based algorithm to solve the optimization problem of G/G/1/K polling
system with k-limited service discipline for a good enough solution using limited computation time. We assume that the arrival rates do
not deteriorate visibly within a very short period. Our approach consists of two stages. In the first stage, we employ a typical
genetic algorithm to select N=1024 roughly good solutions from the huge discrete solution space Ω using an offline trained artificial neural network as
a surrogate model for fitness evaluation. The second stage consists of several substages to select estimated good enough solutions
from the previous N, and the solution obtained in the last substage is the good enough solution that we seek. Using numerous tests, we demonstrate:
(i) the computational efficiency of our algorithm in the aspect that we can apply our algorithm in real-time based on the
arrival rate assumption; (ii) the superiority of the good enough solution, which achieves drastic objective value reduction
in comparison with other existing service disciplines. We provide a performance analysis for our algorithm based on the derived
models. The results show that the good enough solution that we obtained is among the best 3.31×10−6% in the solution space with probability 0.99.
This research work was supported in part by the National Science Council of Taiwan, ROC, Grant NSC95-2221-E-009-099-MY2. 相似文献
107.
Hao‐Kai Peng XiaoXiao Wang Ting‐Ting Li Ching‐Wen Lou YanTing Wang Jia‐Horng Lin 《先进技术聚合物》2019,30(8):2045-2055
Isocyanate, polyether polyol, a flame retardant (10 wt%), and aluminum hydroxide/magnesium hydroxide (0, 5, 10, 15, and 20 wt%) are used to form the rigid polyurethane (PU) foam, while nylon nonwoven fabrics and a polyester aluminum foil are combined to serve as the panel. The rigid PU foam and panel are combined to form the rigid foam composites. The cell structure, compressive stress, combustion resistance, thermal stability, sound absorption, and electromagnetic interference shielding effectiveness (EMI SE) of the rigid foam composites are evaluated, examining the effects of using aluminum hydroxide and magnesium hydroxide. Compared with magnesium hydroxide, aluminum hydroxide exhibits superior performance to the rigid foam composites. When aluminum hydroxide is 20 wt%, the rigid foam composite has an optimal density of 0.153 g/cm3, an average cell size of 0.2466 mm, a maximum compressive stress of 546.44 Kpa, an optimal limiting oxygen index (LOI) of 29.5%, an optimal EMI SE of 40 dB, and excellent thermal stability and sound absorption. 相似文献
108.
B.-L. Yu J.C.F. Wang A.D. Beyer M.L. Teague G.P. Lockhart J.S.A. Horng S.-P. Lee N.-C. Yeh 《Solid State Communications》2009,149(7-8):261-265
We investigate the scenario of competing order (CO) induced Fermi arcs and pseudogap in cuprate superconductors. For hole-type cuprates, both phenomena as functions of temperature and doping level can be accounted for if the CO vanishes at above the superconducting transition and the CO wave-vector Q is parallel to the antinodal direction. In contrast, the absence of these phenomena and the non-monotonic -wave gap in electron-type cuprates may be attributed to and a CO wave-vector Q parallel to the nodal direction. 相似文献
109.
An extension of Prager-Ziegler's work-hardening rule for infinitesimal elastic-plastic deformation to a work-hardening rule for finite elastic-plastic deformation of polycrystalline metals at elevated temperatures is developed. Attention is given to the development to satisfy certain invariant, continuity and thermodynamic requirements. 相似文献
110.
The determination of toxic metals in urine is an important clinical screening procedure. In this study, the aim of our investigation was to determine the concentrations of Pb, Cd, and Ni in urine samples under routine clinical laboratory conditions. To assess the reliability of these methods, critical factors such as detection limit(s), calibration range(s), cost, accuracy and precision were studied. The method was employed for the quantitative determination of lead, cadmium and nickel in urine samples from steel production and quality control (QC) workers and healthy unexposed controls. After pre-treatment with acids, the samples were digested via a microwave oven and the samples were determined by a graphite furnace atomic absorption spectrometry (GFAAS). Quality control for these procedures was established with the concurrent analysis of Standard Trace Metals 7879 Level II and NIST SRM 2670 (Toxic Elements in Freeze Dried Urine). The results indicate that urinary lead, cadmium and nickel levels of the exposed workers are significantly higher those of the controls. The possible connection of these elements with the etiology of disease is discussed. The results also show the need for immediate improvements in workplace ventilation and industrial hygiene practices. 相似文献