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71.
Mees FD Martens LR Janssen MJ Verberckmoes AA Vansant EF 《Chemical communications (Cambridge, England)》2003,(1):44-45
Hydrothermal stability of SAPO-34 is greatly improved by the treatment of the acidic form of the SAPO-34 with NH3. 相似文献
72.
X.J.A. Janssen A. van Reenen L.J. van IJzendoorn A.M. de Jong M.W.J. Prins 《Colloids and surfaces. A, Physicochemical and engineering aspects》2011,373(1-3):88-93
We demonstrate a new probing technique to measure physicochemical interactions between particles and a substrate in a fluid. The technique is based on the measurement of field-induced rotation of individual magnetic particles in contact with the substrate. The parallel measurement of many particles with single-particle resolution gives reliable statistics in a short time. Using this technique, the interaction between streptavidin-coated magnetic particles and a glass substrate is measured for various buffer conditions. Increased binding is quantified for increasing ionic strength and decreasing pH. The results are found to be in agreement with calculations of electrostatic interactions. We also apply the technique to study how binding is reduced by blocking the substrate with albumin. 相似文献
73.
A two-dimensional steady-sate analysis of semi-infinite brittlecrack growth at a constant subcritical rate in an unboundedfully-coupled thermoelastic solid under mixed-mode thermomechanicalloading is made. The loading consists of normal and shear tractionsand heat fluxes applied as point sources (line loads in theout-of-plane direction). A related problem is solved exactly in an integral transformspace, and robust asymptotic forms used to reduce the originalproblem to a set of integral equations. The equations are partiallycoupled and exhibit operators of both Cauchy and Abel types,yet can be solved analytically. The temperature change field at a distance from the moving crackedge is then constructed, and its dominant term is found tobe controlled by the imposed heat fluxes. The role of this termis, indeed, enhanced if the heat fluxes serve to render thecrack as a net heat source/sink for the solid, as opposed tobeing a transmitter of heat across its plane. More generally,the influence of the thermoelastic coupling on this field, aswell as other functions, is found to increase with crack speed. 相似文献
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Ample fields play an important role in possibility theory. These fields of subsets of a universe, which are additionally closed under arbitrary unions, act as the natural domains for possibility measures. A set provided with an ample field is then called an ample space. In this paper we generalise Wang's notions of product ample field and product ample space. We make a topological study of ample spaces and their products, and introduce ample subspaces, extensions and one-point extensions of ample spaces. In this way, a first step towards a mathematical theory of possibilistic processes is made. 相似文献
77.
Hot-film anemometry for measuring lateral line stimuli 总被引:2,自引:0,他引:2
A hot-film anemometer system has been calibrated and evaluated for the measurement of sinusoidal water motions used in stimulating the mechanosensory lateral line system of a teleost fish. The response of the anemometer system to water motions created by a vibrating sphere was measured over a wide range of frequencies, intensities, and distances from the sphere. The amplitude response of the system to signals along the axis of sphere vibration was found to be linear over a 50-dB range for frequencies from 10-200 Hz, with the lowest end of the dynamic range (between 10(-8) and 10(-9) m) corresponding to physiological measures of best sensitivity in the lateral line system of the mottled sculpin, Cottus bairdi. The measured attenuation of the signal with distance was also linear over this frequency range out to distances of six times the radius ( = 3 mm) of the sphere and followed the predicted falloff rate for a dipolar source. The linear response of the anemometer system over a wide dynamic range encompassing the detection range of the lateral line system, and the match between predicted and measured motions at varying distances from a dipolar source, indicates that hot-film anemometry is a useful technique for measuring low-level, low-frequency signals likely to stimulate the lateral line system and other hydrodynamic detectors. 相似文献
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Ilona Visser Monique Klinkenberg Peter Hoos Hans-Gerd Janssen John van Duynhoven 《Analytica chimica acta》2009,654(1):40-44
The performance of many contemporary detergent products critically depends on polymers. Water-soluble polycarboxylates represent an important class of detergent polymers, and their quantitative assessment in detergent matrices stands as a considerable challenge. The presence of high levels of surfactants is a major complication, due to the strong tendency of surfactants to form micelles and to interact with the polymers. First, we addressed critical steps in the subsequent combined use of liquid extraction and off-line size exclusion chromatography-nuclear magnetic resonance (SEC-NMR) for identification and quantification of polycarboxylates in detergent products. Next, the different steps in the off-line SEC-NMR procedure were optimized with respect to precision and accuracy. This resulted in recoveries of more than 80% for maleic acid/acrylic acid copolymers; in detergent products a proportional bias of 30% is achieved. The method showed good precision with a relative standard deviation of within-laboratory reproducibility between 5% and 14%. 相似文献