一类含临界增长的多重调和方程组非平凡解的存在性

本文研究了带临界指标的多重调和半线性椭圆方程组.利用变分法,得到了此类方程组非平凡解的存在性和非存在性的条件.     

新型硼氮磷一体化阻燃剂的合成

分别以硼酸、二乙醇胺、三氯氧磷和季戊四醇为原料,经酯化反应制得中间体二乙醇胺硼酸酯（DEAB, 1）和双季戊四醇二氯磷酸酯（SPDPC, 2）; 1与2经缩聚反应合成新型集磷、氮、硼于一体的阻燃剂聚季戊四醇双磷酸酯二磷酰氯螺环二乙醇胺硼酸酯（PPSPSDB, 3）,其结构经¹H NMR, ¹³C NMR和FT-IR表征。考察了溶剂、物料比γ［n(2)：n(1)］、反应温度和反应时间对3产率的影响,结果表明：在最佳反应条件（DMF为溶剂,γ=1 ：1.2, 于120 ℃反应2 h后,于190 ℃反应2 h）下,产率93.26%。热重分析表明：3的初始分解温度为240.5 ℃, 800 ℃时残炭率为44.45%。     

含联芴烯单元共轭聚合物的合成及表征

以六羰基钨[W(CO)₆]为催化剂, 合成了聚吲哚芴(P1)、 聚梯型四苯(P2)、 聚梯型五苯(P3)和小分子9-联吲哚芴烯(S1).该类聚合物的重复单元含有联芴烯结构, 通过芴9位的双键连接. 光学和电化学等实验结果表明, 聚合物无荧光发射, 是一类窄带隙的共轭聚合物, 其中聚合物P1薄膜的紫外吸收值最大波长为710 nm.     

新疆圆柏挥发油化学成分分析

气相色谱-质谱联用技术分析研究了植物新疆圆柏枝叶挥发油化学成分,分离鉴定了20个成分,占挥发油色谱总峰面积99.12%。     

基于近红外光谱和ELM算法的菱镁矿石品级分类研究

由工业发展需求,针对菱镁矿石矿物含量不同以及分布不均匀而难以判定其品级的情况,提出一种由近红外光谱技术结合ELM的菱镁矿石品级分类模型。该模型可以实现菱镁矿石品级的快速分类。近红外光谱利用菱镁矿中不同种类含H基团对近红外光谱有不同吸收的特性,用来测定菱镁矿石的成分及其含量,其操作简便、不破坏样品、速度快、准确高效。以辽宁省营口市大石桥的菱镁矿石30组为研究对象,采集菱镁矿石的近红外光谱数据样本30×973。采用主成分分析(PCA)对其进行降维处理,以主元贡献率大于99.99%而得到10维的特征变量值。建立了ELM算法定量分析数学模型,取20组样本为训练样本(包括6组特级,14组非特),其余10组作为测试样本(其中4组特级,6组非特),ELM算法模型的隐含层节点数选取20。为了进一步提高分类效果,提出两种ELM算法模型的改进：采用循环模式对传统ELM的输入权值和阈值进行寻优的精选ELM和在精选ELM基础上进行集成的集成-精选ELM。并与用人工方法、化学方法和BP神经网络模型方法对菱镁矿石样品品级分类作对比。结果表明：近红外光谱和ELM菱镁矿石品级分类模型不论在时间上还是成本上,都具有明显的优势,且其准确率能够达到90%以上,为菱镁矿石品级分类提供了一条新的途径。     

Effect of environmental weathering on flexural creep behavior of long fiber-reinforced thermoplastic composites

Flexural creep behavior of nylon 6/6 (NY66)- and polypropylene (PP)- based long fiber (l/d = 2000−10 000) thermoplastic (LFT) composites was investigated as a function of ultraviolet irradiation and moisture absorption. Extrusion/compression-molded panels were prepared according to ASTM D-2990 and conditioned according to ASTM D-618. NY66 and PP LFTs were characterized using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and Fourier-transform infrared (FTIR) spectroscopy in the unexposed condition, and as-exposed to 253.7 nm UV radiation. The creep compliance of PP LFT increased with increasing UV exposure, whereas the creep compliance of NY66 LFT showed a moderate decrease with increasing UV exposure. Moisture absorption experiments were performed in boiling water until saturation on NY66 and its LFT composites. Characterization of desorbed moisture absorption specimens suggested slight variation in the structure, and an analysis of creep compliances showed minimal changes as compared to the dry/unexposed specimens.     

An auditory periphery model for improving narrow-band noise recognition rate of underwater targets

The recognition rate of the auditory periphery features decreases when the model is used to identify underwater targets in practice. To solve this problem, an improved method based on Gammatone filter bank is proposed. Firstly, after the reason of the decreasing of the recognition results is analyzed,the mechanism of multichannel data acquisition in acoustic engineering may narrow down signal frequency range, which leads to time-frequency features distortion. Secondly, the Gammatone filter bank is implemented to simulate frequency decomposition characteristics of human ear basilar membrane. Since the class information of the underwater noise signal is mostly contained in low frequency range, the auditory features of the conventional model are interpolated and the channel number of the filter bank and the central frequency of each frequency band are adjusted accordingly to obtain a 27-dimensional feature vector of the narrow-band target signal. The adjusted model may reflect the target's timefrequency feature more precisely. Finally, the performance of the auditory features is tested by a Neural Network classifier. The experiment results show that the modified auditory model is more effective than the conventional ones. The major information contained in broadband signals is reserved and the classification ability for real targets is further enhanced. The recognition results are increased from 82.59% to 88.80%. The modified auditory features effectively improve the recognition rate for underwater target radiated noise signals.     

质子交换膜燃料电池动态特性数值分析

本文基于CFD手段计算分析了质子交换膜燃料电池在启动过程、负载突变两种工况下的动态响应特性,与实验结果进行了对比,分析了其影响因素.分析了燃料电池动态工况下膜内含水量、极板电流和阴极扩散层水饱和度三个参数在负载变化时的响应速度,认为膜内含水量、极板电流在2s左右即可达到平衡,而阴极扩散层水饱和度需较长时间才能达到平衡.     

Above-Threshold Dissociation of HD+ in Femtosecond Laser Field

The above-threshold dissociation （ATD） of the HD＋ molecular ion in femtosecond laser field is investigated theoretically. The energy-dependent distribution of the dissociated fragments is calculated using an asymptoticflow expression in the momentum space. The calculations show that the ATD of HD＋ is sensitive to the initial vibrational level of ground electronic state. Multiphoton ATDs can be observed in the dissociation processes. The dynamics phenomena are interpreted by using the concept of light-dressed potential.     

Structural evolution of manganosite: Comparison of properties of nonstoichiometric manganese and iron monoxides

Accurate measurements of the lattice parameters of polycrystalline manganosite Mn_1?zO lead to the conclusion that the magnetic lattices of the stoichiometric MnO and Mn₃O₄, which appear during the cooling process, do not interact. The X-ray energetic shifts and the morphology of the manganosite are described for multilayer samples obtained by oxidation of the metal. The reactivity of the two isomorphic monoxides, Mn_1?zO or manganosite and Fe_1?zO or wüstite, is interpreted in terms of the elastic constant C₄₄. The clustering of the point defects, the deformation energy, and the comparative plasticity or brittleness are discussed in terms of this constant for both monoxides at high temperature and after quenching.