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991.
Determination of As,Sb and Bi in high-purity copper by electrothermal atomic absorption spectrometry
As, Sb and Bi were determined in copper electric cables by atomic absorption spectrometry with electrothermal atomization in a graphite furnace. The interferences in the determination of As, Sb and Bi caused by eleven cationic species and six types of acid were studied. The different volatilization of the copper matrix in comparison to the analyte was studied, as a means of increasing the analyte signal/non-specific absorption signal ratio. 相似文献
992.
993.
Barluenga J Andina F Fernández-Rodríguez MA García-García P Merino I Aguilar E 《The Journal of organic chemistry》2004,69(21):7352-7354
The utility of fluoride anion as promoter of the oxidation of Fischer carbene complexes is presented. Two different and complementary methods that allow the fast and convenient preparation of carbene-derived esters in good yields have been developed using stoichiometric or catalytic quantities of fluoride ion. 相似文献
994.
M. Ftima C. Guedes da Silva Elsa M. P. R. P. Branco Yu Wang Joo J. R. Fraústo da Silva Armando J. L. Pombeiro Roberta Bertani Rino A. Michelin Mirto Mozzon Franco Benetollo Gabriella Bombieri 《Journal of organometallic chemistry》1995,490(1-2)
Complexes trans-[PtX(L)(PPh3)2]A [1: X = CF3; A = BF4; L = NCNH2, NCNMe2, NCNEt2, or NCNC(NH2)2. 2: X = Cl; A = BPh4; L = NCNMe2 or NCNEt2] and cis-[PtCl(L)(PPh3)2][BPh4] [3: L = NCNH2 or NCNC(NH2)2], which appear to be the first cyanamide or cyanoguanidine complexes of platinum to be reported, have been prepared by treatment of trans-[PtBr(CF3)(PPh3)2] (in CH2Cl2/acetone and in the presence of Ag[BF4]) or of cis-[PtCl2(PPh3)2] (in THF and in the presence of Na[BPh4]), respectively, with the appropriate substrate. In KBr pellets or in solution 1 (L = NCNMe2 or NCNEt2) undergoes ready replacement of the organocyanamide (under the trans influence of CF3) by bromide to regenerate trans-(PtBr(CF3)(PPh3)2]. The X-ray structure of 1 (X = CF3, A = BF4, L = NCNEt2) is also reported, and shows the presence of two apical intramolecular contacts of the metal with two ortho-hydrogen atoms of the phosphines, whereas the amine N atom of the diethylcyanamide is trigonal planar in the linear NCN framework with a delocalized π system. 相似文献
995.
Morán-Pineda M. Castillo S. Asomoza M. Gómez R. 《Journal of Thermal Analysis and Calorimetry》2003,73(1):341-346
TG, FTIR-(CO absorption), and catalytic activity in the NO reduction by CO were used to characterize Cu/Al2O3-TiO2 catalysts prepared by co-gelling aluminum tri-sec-butoxide and titanium iso-propoxide at pH 9 and at pH 3 gelling conditions.
Under nitrogen flow, copper oxide decomposition, oxygen storage capacity (OSC) and sample dehydroxylation (total mass loss)
was followed by TG. The CuO decomposition forming Cu0, Cu+1 was observed by means of FTIR (CO absorption) spectra. In pH 9 sample the large amount of Cu0 was observed. At low total mass loss and high Cu0/Cu+1+Cu+2 ratio (pH 9 sample) a lowest light-off in the NO reduction by CO was observed.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
996.
The effects of dielectric constant, viscosity and polarity of the solvents used on the relative fluorescent emission of 2,3-diphenylquinolizinium bromide and 2(p-dimethyl-amino)styryl-3-methylquinolizinium bromide are described. These salts were entirely dissolved in ten different solvents. The 2(p-dimethylamino)styryl derivative produced different ionic species, and was a fluorescent acid-base indicator. The fluorescence of these quinolizinium salts is shown to increase with greater viscosity of the medium. 相似文献
997.
Franco Bonino Mario Lazzari Bruno Scrosati 《Journal of Electroanalytical Chemistry》1978,93(2):117-125
The behaviour of positive electrodes based on silver polymolybdate (Ag2Mo2O7, Ag6Mo10O33) and polytungstates (Ag2W2O7, Ag2W4O13) in lithium-organic solvent batteries has been investigated. The performances of the lithium/silver oxosalt couples are given and the discharge processes are discussed. 相似文献
998.
Benaglia M Benincori T Mussini P Pilati T Rizzo S Sannicolò F 《The Journal of organic chemistry》2005,70(19):7488-7495
[structure: see text] The role played by the electronic properties and the steric features of bis(oxazoline) ligands in the Cu(I)-catalyzed cyclopropanation of styrene effected with ethyl diazoacetate was investigated. Two pairs of new bis(oxazolines) displaying flexible and atropisomeric 3,3'-bithiophene backbones were synthesized and structurally and electronically characterized. For the first time, the electrochemical oxidative potential was used as a reliable index of the electronic density on the nitrogen atom of the chelating groups of new and, for comparative purposes, of already known bis(oxazolines). The Cu(I) complexes of the new ligands were prepared, and their enantioselection ability and catalytic efficiency were tested. This investigation suggests that steric factors and catalyst geometrical features are clearly more important than any consideration of the electronic properties of the chiral ligands. 相似文献
999.
Calculations on linear and bent structures of N3 and P3 show that these species are quite different. N3 is linear, P3 is bent almost to a D3h geometry. The symmetry of P3 in D3h is 2E″ but the Jahn-Teller distortion is very small, ≈4°. The many-body expansion of the energy of Pn clusters appears to be only slowly convergent. 相似文献
1000.
Marisa Belicchi-Ferrari Franco BisceglieChiara Cavalieri Giorgio PelosiPieralberto Tarasconi 《Polyhedron》2007
This paper reports the synthesis and characterization of six compounds of copper(I), stabilized in its reduced state by two triphenylphosphines, in which 4-fluorobenzaldehyde thiosemicarbazone and N-methylthiosemicarbazone act as chelating through their sulfur and imino nitrogen. The three oxoanions that have been chosen, NO3−, SO42− and CH3COO−, play an important role: their oxygens are bad competitors with the imino nitrogen of the thiosemicarbazone moiety and moreover they form strong charge assisted hydrogen bondings that stabilize the neutral form of the ligand. The overall packing is determined by intermolecular phenyl–phenyl van der Waals interactions. 相似文献