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101.
Liolios C Laouer H Boulaacheb N Gortzi O Chinou I 《Molecules (Basel, Switzerland)》2007,12(4):772-781
The chemical composition of essential oil obtained by steam distillation of dried aerial parts of Phlomis bovei De Noé subsp. bovei collected from Algeria, was analyzed by GC and GC/MS. Seventy five constituents (corresponding to 86.37% of the total weight) were identified. The main components were: germacrene D, beta-caryophyllene, beta-bournonene, thymol and hexahydrofarnesyl acetone. Furthermore, the antimicrobial activity of the oil was evaluated against six gram (+/-) bacteria and three pathogenic fungi, using the agar dilution technique. It was found that the oil exhibited strong antimicrobial activity against most of the tested microorganisms. 相似文献
102.
Evans BS Ntai I Chen Y Robinson SJ Kelleher NL 《Journal of the American Chemical Society》2011,133(19):7316-7319
Nonribosomal peptide synthetases (NRPSs) and polyketide synthases (PKSs) are large enzymes responsible for the biosynthesis of medically and ecologically important secondary metabolites. In a previous report, we described a proteomics approach to screen for expressed NRPSs or PKSs from bacteria with or without sequenced genomes. Here we used this proteome mining approach to discover a novel natural product arising from rare adenylation (A) and reductase (Red) domains in its biosynthetic machinery. We also cloned the entire gene cluster and elucidated the biosynthesis of the new compound, which is produced by an unsequenced Bacillus sp. isolated from soil collected in Koran, Louisiana. 相似文献
103.
104.
Karagiannis EE Kefalidis CE Petrakopoulou I Tsipis CA 《Journal of computational chemistry》2011,32(7):1241-1261
The structural, electronic, bonding, magnetic, and optical properties of bimetallic [Cu(n)Ru(m)](+/0/-) (n + m ≤ 3; n, m = 0-3) clusters were computed in the framework of the density functional theory (DFT) and time-dependent DFT (TD-DFT) using the full-range PBE0 nonlocal hybrid GGA functional combined with the Def2-QZVPP basis sets. Several low-lying states have been investigated and the stability of the ground state spinomers was estimated with respect to all possible fragmentation schemes. Molecular orbital and population analysis schemes along with computed electronic parameters illustrated the details of the bonding mechanisms in the [Cu(n Ru(m)](+/0/-) clusters. The TD-DFT computed UV-visible absorption spectra of the bimetallic clusters have been fully analyzed and assignments of all principal electronic transitions were made and interpreted in terms of contribution from specific molecular orbital excitations. 相似文献
105.
All uncountable cardinals in the Gitik model are almost Ramsey and carry Rowbottom filters 下载免费PDF全文
Using the analysis developed in our earlier paper 5 , we show that every uncountable cardinal in Gitik's model of 8 in which all uncountable cardinals are singular is almost Ramsey and is also a Rowbottom cardinal carrying a Rowbottom filter. We assume that the model of 8 is constructed from a proper class of strongly compact cardinals, each of which is a limit of measurable cardinals. Our work consequently reduces the best previously known upper bound in consistency strength for the theory + “All uncountable cardinals are singular” + “Every uncountable cardinal is both almost Ramsey and a Rowbottom cardinal carrying a Rowbottom filter”. 相似文献
106.
Ioanna Anna Papachristou Martí Rosas-Casals 《The Journal of mathematical sociology》2016,40(4):219-238
We present a methodology based on weighted networks and dependence coefficients aimed at revealing connectivity patterns between categories. As a case study, it is applied to an urban place and at two spatial levels—neighborhood and square—where categories correspond to human needs. Our results show that diverse spatial levels present different and nontrivial patterns of need emergence. A numerical model indicates that these patterns depend on the probability distribution of weights. We suggest that this way of analyzing the connectivity of categories (human needs in our case study) in social and ecological systems can be used to define new strategies to cope with complex processes, such as those related to transition management and governance, urban-making, and integrated planning. 相似文献
107.
Molinou IE Tsierkezos NG 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,71(3):954-958
Raman spectra of water+N,N-dimethylformamide (DMF) mixtures and their solutions with NaNCS, KNCS and NH(4)NCS were obtained. The bands of nu(CO) stretching, delta(OCN) bending, r(CH(3)) rocking and nu(N-CH)(3)) stretching of the DMF molecule with and without salts were studied. The dependence of the vibration frequencies and Raman intensities of the bands on the composition of the mixed solvent was discussed. The change of the band frequencies as a result of the presence of the salts and the solvation of the cations by the solvent molecules was examined. The stronger cation solvation by the aprotic solvent molecules instead of the water molecules in DMF concentrated solutions was discussed. The nu(CN) and nu(CS) vibrations of the SCN(-) ions were observed as a function of the cation present and the solvent composition. The presence of the SCN(-) ions as "free", contact ion pairs, or solvent separated pairs, was discussed. 相似文献
108.
D Kalaitzakis T Montagnon I Alexopoulou G Vassilikogiannakis 《Angewandte Chemie (International ed. in English)》2012,51(35):8868-8871
All in one: Meyers' bicyclic lactams were synthesized in high yield from furans using a new and powerful method that involves a one-pot singlet-oxygen-initiated reaction cascade (see scheme; TFA=trifluoroacetic acid). This method has broad synthetic potential because of the ease of access to a wide range of furans with a variety of substituents. 相似文献
109.
The general complexation scheme as well as the dynamic features of the supramolecular structures resulting from the interaction of the laser dye 2,5-diphenyl-1,3,4-oxadiazole (PPD) with the naturally occurring alpha-, beta-, and gamma-cyclodextrins in water are studied by means of fluorescence spectroscopy, both steady-state (SS) and time-resolved (TR). PPD interacts weakly, from a thermodynamic point of view, with alpha-cyclodextrin (alpha-CD), forming 1:1 complexes with an association constant of K(11) = 85 +/- 4 M(-1). However, the local motion of the substrate (PPD) with respect to the ligand (CD) in the complexed form is hindered; namely, dynamically, they are strongly coupled and only a global tumbling motion, = 370 +/- 30 ps, of the whole adduct is observed. The next homologue beta-CD also forms 1:1 entities with PPD, but although the binding strength of reactants (K(11) = 682 +/- 60 M(-1)) is almost an order of magnitude greater than the former case with the alpha-CD, these are dynamically weakly coupled. In fact, two independent motions are detected: one is that of the whole nanostructure motion (1:1, PPD/beta-CD) with a global rotational relaxation time of = 480 +/- 30 ps, and the other is an internal librational motion of the dye inside the host cavity with an average angular displacement of theta approximately 27 degrees . Finally, the interaction of PPD with the wider and more flexible cavity of the gamma-CD "triggers" a self-associative scheme of the initially formed supramolecular building blocks, namely, singly occupied complexes, leading to the formation of nanotubular superstructures. It is found that these linear arrays are constituted from more than 17 gamma-CD units which are held together with the aid of dimers of PPD. Interestingly, our results supported that two distinct dimeric forms of PPD play the role of the "shaft" between adjacent cyclodextrin units. The topology of the dimers in the interlinking space of gamma-CD units is such that PPD molecules are held in suitable proximity, resulting, upon excitation, in the observation of dual excimer emission. 相似文献
110.
Ioanna Chalari Stergios Pispas Nikos Hadjichristidis 《Journal of polymer science. Part A, Polymer chemistry》2001,39(17):2889-2895
Bulk free‐radical polymerization of 2‐vinylpyridine (2VP) in the presence of 2,2,6,6‐tetramethylpiperidine‐N‐oxyl (TEMPO) was studied under different conditions (temperature and presence of additives). Linear poly‐(2‐vinylpyridine) with a narrow molecular weight distribution and controllable molecular weight was prepared in the presence of acetic anhydride at 95 °C up to a conversion of 66%. At higher conversions side reactions became very important (pseudoliving polymerization). By applying this procedure, well‐defined random copolymers of 2VP with styrene or tert‐butylmethacrylate as well as block copolymers of 2VP with styrene were synthesized. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2889–2895, 2001 相似文献