Characterization of poly(methyl methacrylate) nanoparticles prepared by nanoprecipitation using analytical ultracentrifugation,dynamic light scattering,and scanning electron microscopy

Nanoprecipitation represents an effective method for the production of polymeric nanoparticles. This technique was used to prepare nanoparticles from solutions of poly(methyl methacrylate) and its copolymers. Since the regulation of main parameters like particle size, particle size distribution, and molar particle mass is very important for future applications, the stable nanoparticle dispersions were examined by scanning electron microscopy, velocity sedimentation, and dynamic light scattering, whereby advantages and disadvantages of each characterization techniques are discussed. Polydispersities of particle size distributions are determined by the ratio of d_w/d_n, where d_w and d_n are weight‐ and number‐average diameters, respectively. The particle characteristics strongly depend on the chemical structure of the polymers and the way of preparation and, therefore, vary in the studied cases in the range of 6 < d_w < 680 nm, whereas the polydispersity index d_w/d_n changes in the range of 1.02 to 1.40. It is shown that nanoparticles in a desirable size range can be prepared by solvent–nonsolvent methods (dialysis technique or dropping technique). © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3924–3931, 2010     

Double-Doppler wavelength conversion of infrared optical pulses by moving grating of refractive index in semiconductors

Optical and Quantum Electronics - A time-domain model of an excited semiconductor medium as a moving Bragg grating was used to investigate a double-Doppler wavelength conversion of an infrared...     

Selective Ruthenium Labeling of the Tryptophan Residue in the Bee Venom Peptide Melittin

Melittin is a membrane‐active peptide from bee venom with promising antimicrobial and anticancer activity. Herein we report on a simple and selective method for labeling of the tryptophan residue in melittin by the organometallic fragment [(C₅H₅)Ru]⁺ in aqueous solution and in air. Ruthenium coordination does not disturb the secondary structure of the peptide (as verified by 2D NMR spectroscopy), but changes the pattern of its intermolecular interactions resulting in an 11‐fold decrease of hemolytic activity. The high stability of the organometallic conjugate allowed the establishment of the biodistribution of the labeled melittin in mice by inductively coupled plasma MS analysis of ruthenium.     

Mechanisms of Methylenecyclobutane Hydrogenation over Supported Metal Catalysts Studied by Parahydrogen-Induced Polarization Technique

In this work the mechanism of methylenecyclobutane hydrogenation over titania-supported Rh, Pt and Pd catalysts was investigated using parahydrogen-induced polarization (PHIP) technique. It was found that methylenecyclobutane hydrogenation leads to formation of a mixture of reaction products including cyclic (1-methylcyclobutene, methylcyclobutane), linear (1-pentene, cis-2-pentene, trans-2-pentene, pentane) and branched (isoprene, 2-methyl-1-butene, 2-methyl-2-butene, isopentane) compounds. Generally, at lower temperatures (150–350 °C) the major reaction product was methylcyclobutane while higher temperature of 450 °C favors the formation of branched products isoprene, 2-methyl-1-butene and 2-methyl-2-butene. PHIP effects were detected for all reaction products except methylenecyclobutane isomers 1-methylcyclobutene and isoprene implying that the corresponding compounds can incorporate two atoms from the same parahydrogen molecule in a pairwise manner in the course of the reaction in particular positions. The mechanisms were proposed for the formation of these products based on PHIP results.     

Roughness-induced effects on the thermomicropolar fluid flow through a thin domain

In this paper, we study the asymptotic behavior of the thermomicropolar fluid flow through a thin channel with rough boundary. The flow is governed by the prescribed pressure drop between the channel's ends and the heat exchange through the rough wall is allowed. Depending on the limit of the ratio between channel's thickness and the wavelength of the roughness, we rigorously derive different asymptotic models clearly showing the roughness-induced effects on the average velocity and microrotation. To accomplish that, we employ the adaptation of the unfolding method to a thin-domain setting.     

AF-algebras and topology of mapping tori

The paper studies applications of C*-algebras in geometric topology. Namely, a covariant functor from the category of mapping tori to a category of AF-algebras is constructed; the functor takes continuous maps between such manifolds to stable homomorphisms between the corresponding AF-algebras. We use this functor to develop an obstruction theory for the torus bundles of dimension 2, 3 and 4. In conclusion, we consider two numerical examples illustrating our main results.     

Transition absorption as a mechanism of surface photoelectron emission from metals

Transition absorption of a photon by an electron passing through a boundary between two media with different permittivities is described both classically and quantum mechanically. Transition absorption is shown to make a substantial contribution to photoelectron emission at a metal/semicon‐ductor interface in nanoplasmonic systems, and is put forth as a possible microscopic mechanism of the surface photoelectric effect in photodetectors and solar cells containing plasmonic nanoparticles.