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Yonglin Xu Ted Belytschko Dept. of Civil Engineering Northwestern University Evanston IL U. S. A 《Acta Mechanica Solida Sinica》1996,9(2):104-123
The Self-Similar Crack Expansion (SSCE) method is proposed to evaluate stress intensi-ty factors at crack tips, whereby stress intensity factors of a crack can be determined by the crackopening displacement over the crack, not just by the local displacement around the crack tip. The crackexpansion rate is estimated by taking advantage of the crack self-similarity. Therefore, the accuracy ofthe calculation is improved. The singular integrals on crack tip elements are also analyzed and are pre-cisely evaluated in terms of a special integral analysis. Combination of these two techniques greatly in-creases the accuracy in estimating the stress distribution around the crack tip. A variety of two-dimen-sional cracks, such as subsurface cracks, edge cracks, and their interactions are calculated in terms ofthe self-similar expansion rate. Solutions are satisfied with errors less than 0.5% as compared with theanalytical solutions. Based on the calculations of the crack interactions, a theory for crack interactionsis proposed such that for a group of aligned cracks the summation of the square of SIFs at the right tipsof cracks is always equal to that at the left tips of cracks. This theory was proved by the mehtod ofSelf-Similar Crack Expansion in this paper. 相似文献
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Thermal radical initiator derivatives based on O‐imino‐isourea: Synthesis,polymerization, and characterization 下载免费PDF全文
Dong Yeon Kim Hyeok Jin Kim Nam Sik Kong Jin Chul Kim Seung Man Noh Hyun Wook Jung Young IL Park 《Journal of polymer science. Part A, Polymer chemistry》2016,54(22):3593-3600
The new thermal radical initiators (TRIs) with linear and cyclic type groups based on derivatives of O‐imino‐isourea have been designed and synthesized. The radical polymerization property of the synthesized TRI derivatives as a radical initiator in n‐butyl acrylate was monitored by differential scanning calorimetry analysis. TRI derivatives with linear type groups, such as 3‐PenDCC, 3‐HexDCC, and 4‐HepDCC, showed peak temperatures (Tpeak) of 80–84 °C, whereas those with cyclic type groups, such as C‐PenDCC, C‐HexDCC, and C‐HepDCC, exhibited a wide Tpeak distribution in the 74–87 °C range. The polymerization efficiency using new TRIs in n‐butyl acrylate was elaborately identified from the molecular weights and conversion obtained using gel permeation chromatography analysis and NMR spectroscopy. To consider their possible application to automotive clearcoats, the real‐time evolution of the rheological properties of clearcoat resins during the crosslinking process with newly synthesized TRI derivatives was measured, confirming the different crosslinking kinetics of TRI derivatives in real thermal curing process. The results were found to be well correlated with data from the radical polymerization experiments of TRIs. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 3593–3600. 相似文献
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Yong Seok Jang Yu Kyoung Kim IL Song Park Sook Jeong Lee Min Ho Lee Jeong Mo Yoon Tae Sung Bae 《Surface and interface analysis : SIA》2009,41(6):524-530
This study examined the film characteristics of an anodized AZ91D magnesium alloy by varying the direct current and pulse frequency conditions. In order to evaluate the effect of the pulse frequency on film formation, anodic oxidation was carried out by applying direct current and pulse current at a current density of 300 mA/cm2. Compared with the sample groups treated with the direct current, a large number of small arcs were generated continuously on the film treated with the pulse current and the film formation rate was found to increase. Homogeneous and compact pores were formed with increasing frequency, and the rate of formation was increased rapidly to the arrival voltage. The film thickness increased and the surface roughness decreased with increasing anodic oxidation time at a fixed frequency of 125 Hz. However, treatment for more than 3 min led to decomposition of the oxidized film onto the previously formed film, which caused an increase in the number of cracks and pores within the film. The most uniform and smallest pores were acquired when the surface was anodized for 3 min at a current density and frequency of 300 mA/cm2 and 125 Hz, respectively. X‐ray diffraction revealed the formation of MgO and Mg2SiO4 peaks, with a relative decrease in peak intensity for the MgO and Mg substrate. The Vickers hardness value was higher on the treated groups than on the untreated group, and the potentiodynamic polarization test revealed satisfactory corrosion resistance through a decrease in corrosion density and a large improvement in the corrosion potential. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
15.
ZHAO Mei-Shan The James Franck Institute The University of Chicago Chicago IL U.S.A. 《中国化学》1995,13(2):141-149
This paper reports calculations of the rate of isomerization of HCN - HCN based on the theory of Gary and Rice as extended by Zhao and Rice. The major task is to determine the effect of intramolecular energy transfer on the prediction of the rate of isomerization. Both the full three-dimensional (3D) system and the reduced two-dimensional (2D) system obtained from freezing CN bond at 1.159 A are analyzed to check the validity of the freezing bond approximation. Meanwhile, RRKM rates are calculated to test RRKM choice of the transition state by comparing to Gary-Rice three-state model. The comparison shows that the rates from 2D model and 3D model are differing up to 20% with 2D rates consistently larger. The intramolecular energy transfer modifies the isomerization rate for HCN system up to 30% that is modestly small by the expectation. The isomerization rate predicted from RRKM theory is greater than those of Gary-Rice three-state model theory up to 65%, and it overstimates the rates under all consider 相似文献