Phase characterization of the reflection on an extreme UV multilayer: comparison between attosecond metrology and standing wave measurements

We characterize the phase shift induced by reflection on a multilayer mirror in the extreme UV range (80-93?eV) using two techniques: one based on high order harmonic generation and attosecond metrology (reconstruction of attosecond beating by interference of two-photon transitions), and a second based on synchrotron radiation and measurements of standing waves (total electron yield). We find an excellent agreement between the results from the two measurements and a flat group delay shift (±40?as) over the main reflectivity peak of the mirror.     

Towards factoring in {SL(2,\,\mathbb{F}_{2^n})}

The security of many cryptographic protocols relies on the hardness of some computational problems. Besides discrete logarithm or integer factorization, other problems are regularly proposed as potential hard problems. The factorization problem in finite groups is one of them. Given a finite group G, a set of generators generators for this group and an element ${g\in G}$ , the factorization problem asks for a “short” representation of g as a product of the generators. The problem is related to a famous conjecture of Babai on the diameter of Cayley graphs. It is also motivated by the preimage security of Cayley hash functions, a particular kind of cryptographic hash functions. The problem has been solved for a few particular generator sets, but essentially nothing is known for generic generator sets. In this paper, we make significant steps towards a solution of the factorization problem in the group ${G:=\,SL(2,\,\mathbb{F}_{2^n})}$ , a particularly interesting group for cryptographic applications. To avoid considering all generator sets separately, we first give a new reduction tool that allows focusing on some generator sets with a “nice” special structure. We then identify classes of trapdoor matrices for these special generator sets, such that the factorization of a single one of these matrices would allow efficiently factoring any element in the group. Finally, we provide a heuristic subexponential time algorithm that can compute subexponential length factorizations of any element for any pair of generators of ${SL(2,\,\mathbb{F}_{2^n})}$ . Our results do not yet completely remove the factorization problem in ${SL(2,\,\mathbb{F}_{2^n})}$ from the list of potential hard problems useful for cryptography. However, we believe that each one of our individual results is a significant step towards a polynomial time algorithm for factoring in ${SL(2,\,\mathbb{F}_{2^n})}$ .     

Investigation of the microporosity of high performance concrete by proton nuclear relaxation.

The difference in microporosity features between high and ultra high performance concrete was highlighted by measuring their respective proton spin-lattice relaxation times. A surface fractal dimension was attributed to each formulation and exhibits a correlation with the amount of calcium silicate hydrates.     

Buffeting in transonic flow prediction using time‐dependent turbulence model

In transonic flow conditions, the shock wave/turbulent boundary layer interaction and flow separations on wing upper surface induce flow instabilities, ‘buffet’, and then the buffeting (structure vibrations). This phenomenon can greatly influence the aerodynamic performance. These flow excitations are self‐sustained and lead to a surface effort due to pressure fluctuations. They can produce enough energy to excite the structure. The objective of the present work is to predict this unsteady phenomenon correctly by using unsteady Navier–Stokes‐averaged equations with a time‐dependent turbulence model based on the suitable (k–ε) turbulent eddy viscosity model. The model used is based on the turbulent viscosity concept where the turbulent viscosity coefficient (Cμ) is related to local deformation and rotation rates. To validate this model, flow over a flat plate at Mach number of 0.6 is first computed, then the flow around a NACA0012 airfoil. The comparison with the analytical and experimental results shows a good agreement. The ONERA OAT15A transonic airfoil was chosen to describe buffeting phenomena. Numerical simulations are done by using a Navier–Stokes SUPG (streamline upwind Petrov–Galerkin) finite‐element solver. Computational results show the ability of the present model to predict physical phenomena of the flow oscillations. The unsteady shock wave/boundary layer interaction is described. Copyright © 2005 John Wiley & Sons, Ltd.     

Interference of transverse rings in multifilamentation of powerful femtosecond laser pulses in air

We observe multiple filaments and interference of their ring structures in the propagation of 14 mJ, 45 fs infrared laser pulse in air. We suggest a simple physical model describing the formation and the interference of rings as the result of superposition of the background field of the whole beam and the fields that diverge from the filaments due to the defocusing in the laser-produced plasma. The size and the number of maxima in the interference pattern depend on the position of the filament formation along the direction of propagation. The simulated picture of the ring structure interference is in qualitative agreement with the one obtained from the experiment.     

Continuous-wave and femtosecond laser operation of Yb:CaGdAlO4 under high-power diode pumping

We demonstrate the generation of 68 fs secant hyperbolic pulses at a 105 MHz repetition rate with an average power of 520 mW from a diode-pumped Yb(3+):CaGdAlO(4) mode-locked laser. A semiconductor saturable absorber allows passive mode locking, and a 15 W diode laser is used to pump directly the crystal. To our knowledge this represents the highest average power ever obtained for a sub-100 fs diode-pumped Yb-bulk laser.     

A Highly Effective Ruthenium System for the Catalyzed Dehydrogenative Cyclization of Amine–Boranes to Cyclic Boranes under Mild Conditions

We recently disclosed a new ruthenium‐catalyzed dehydrogenative cyclization process (CDC) of diamine–monoboranes leading to cyclic diaminoboranes. In the present study, the CDC reaction has been successfully extended to a larger number of diamine–monoboranes ( 4 – 7 ) and to one amine–borane alcohol precursor ( 8 ). The corresponding NB(H)N‐ and NB(H)O‐containing cyclic diaminoboranes ( 12 – 15 ) and oxazaborolidine ( 16 ) were obtained in good to high yields. Multiple substitution patterns on the starting amine–borane substrates were evaluated and the reaction was also performed with chiral substrates. Efforts have been spent to understand the mechanism of the ruthenium CDC process. In addition to a computational approach, a strategy enabling the kinetic discrimination on successive events of the catalytic process leading to the formation of the NB(H)N linkage was performed on the six‐carbon chain diamine–monoborane 21 and completed with a ¹⁵N NMR study. The long‐life bis‐σ‐borane ruthenium intermediate 23 possessing a reactive NHMe ending was characterized in situ and proved to catalyze the dehydrogenative cyclization of 1 , ascertaining that bis σ‐borane ruthenium complexes are key intermediates in the CDC process.     

The total synthesis of the crinine alkaloid hamayne via a Pd[0]-catalyzed intramolecular alder-ene reaction

The racemic form of the title alkaloid, 1, has been prepared in 13 steps from the ring-fused gem-dibromocyclopropane 7. Key transformations include the thermally induced electrocyclic ring-opening of compound 7, the Pd[0]-catalyzed intramolecular Alder-ene (IMAE) reaction of the derived sulfonamide (±)-12, and the conversion of the ensuing C-3a-arylhexahydroindole (±)-16 into (±)-hamayne via a Pictet-Spengler reaction.     

Effect of sterilization on non-woven polyethylene terephthalate fiber structures for vascular grafts

Non-woven polyethylene terephthalate (PET) fibers produced via melt blowing and compounded into a 6 mm diameter 3D tubular scaffold were developed with artery matching mechanical properties. This work compares the effects of ethylene oxide (EtO) and low temperature plasma (LTP) sterilization on PET surface chemistry and biocompatibility. As seen through X-ray photoelectron spectroscopy (XPS) analysis, LTP sterilization led to an increase in overall oxygen content and the creation of new hydroxyl groups. EtO sterilization induced alkylation of the PET polymer. The in vitro cytotoxicity showed similar fibroblastic viability on LTP- and EtO-treated PET fibers. However, TNF-α release levels, indicative of macrophage activation, were significantly higher when macrophages were incubated on EtO-treated PET fibers. Subcutaneous mice implantation revealed an inflammatory response with foreign body reaction to PET grafts independent of the sterilization procedure.     

MALDI imaging mass spectrometry of lipids by adding lithium salts to the matrix solution

Mass spectrometry imaging of lipids using MALDI–TOF/TOF mass spectrometers is of growing interest for chemical mapping of organic compounds at the surface of tissue sections. Many efforts have been devoted to the best matrix choice and deposition technique. Nevertheless, the identification of lipid species desorbed from tissue sections remains problematic. It is now well-known that protonated, sodium- and potassium-cationized lipids are detected from biological samples, thus complicating the data analysis. A new sample preparation method is proposed, involving the use of lithium salts in the matrix solution in order to simplify the mass spectra with only lithium-cationized molecules instead of a mixture of various cationized species. Five different lithium salts were tested. Among them, lithium trifluoroacetate and lithium iodide merged the different lipid adducts into one single lithium-cationized species. An optimized sample preparation protocol demonstrated that the lithium trifluoroacetate salt slightly increased desorption of phosphatidylcholines. Mass spectrometry images acquired on rat brain tissue sections by adding lithium trifluoroacetate showed the best results in terms of image contrast. Moreover, more structurally relevant fragments were generated by tandem mass spectrometry when analyzing lithium-cationized species.