Least squares method for analyzing broadened x-ray line shapes

A method for obtaining values of the widths and other parameters describing the Gaussian and Lorentzian components of peaks, which have the shape of the convolution of those functions, is described. Results of the method are given for X-ray data containing several peaks with different ratios of the composite widths in separate spectra.     

Global properties of tensor rank

The dependence of tensor rank on the underlying ring of scalars is considered. It is shown that the integers are, in a certain sense, the worst scalars. A ring of scalars can be improved by adjoining algebraic elements but not by adjoining indeterminates. The real closed fields are the best scalars among ordered rings, and the algebraically closed fields are best among all rings. Let B(R^m×n×p) be the maximum tensor rank of any m×n×p array of elements from the ring R. A generalization of Gaussian elimination shows that B(R^n×n×n)?$\text{3}\text{4}$n² for most useful rings R. For every R, B(R^m×n×p)?mnp/(m+n+p), and slightly stronger lower bounds are proven for R a field.     

Transverse asymmetry AT' from the quasielastic 3He(e,e') process and the neutron magnetic form factor

We have measured the transverse asymmetry A(T') in 3He(e,e(')) quasielastic scattering in Hall A at Jefferson Laboratory with high precision for Q2 values from 0.1 to 0.6 (GeV/c)(2). The neutron magnetic form factor G(n)(M) was extracted based on Faddeev calculations for Q2 = 0.1 and 0.2 (GeV/c)(2) with an experimental uncertainty of less than 2%.     

Die Trennung des Zinns von anderen Metallen, insbesondere die Bestimmung desselben durch F?llung Mit Cupferron

Ohne Zusammenfassung     

Overtone spectroscopy of some benzaldehyde derivatives

Overtone spectrum of o, m and p-nitrobenzaldehydes and p-chlorobenzaldehyde has been studied in 2000–12000 cm⁻¹ region. Vibrational frequencies and anharmonicity constants for aryl as well as alkyl CH stretch vibrations have been determined. We have also determined the internuclear distances for the aryl CH bond in the different molecules. The small variation observed in these distances is an indication of the substitution effect. It is observed that in the case of p-disubstituted benzens, the shift in aryl CH bond is proportional to sum of the Hammet σ of the substituents. However in the case of o-disubstituted benzenes it is only 80% of the para-substituted shift.     

Calculation and Measurement of Terahertz Active Normal Modes in Crystalline PETN

The terahertz frequency spectrum of pentaerythritol tetranitrate (PETN) is calculated using Discover 1 with the COMPASS 2 force field, CASTEP^[3] and PWscf. 4 The calculations are compared to each other and to terahertz spectra (0.3–3 THz) of crystalline PETN recorded at 4 K. A number of analysis methods are used to characterise the calculated normal modes.     

First observation of the point spread function of optical transition radiation

We represent the first experimental observation of the point spread function (PSF) of optical transition radiation (OTR) performed at KEK-Accelerator Test Facility extraction line. We have demonstrated that the PSF vertical polarization component has a central minimum with a two lobe distribution. However, the distribution width varied significantly with wavelength. We assume that we observed a severe effect from spherical or chromatic aberrations which are not taken into account in any existing theoretical model. We believe that the result of this work will encourage theoreticians to continue developing the theory as it is important for various transition radiation applications. Nonuniform distribution of the OTR PSF creates an opportunity for developing a submicrometer transverse beam size monitor.     

Thermal decomposition of 1,1,2,2-tetraaryl-1,2-ethanediols

The thermal degradation of a series of 1,1,2,2-tetraaryl-1,2-ethanediols has been examined using thermogravimetry (TG) and gas chromatography/mass spectrometry (GC/MS). These compounds are smoothly converted to the corresponding diaryl ketone and diaryl carbinol, i.e., the compounds undergo disproportionation arising from homolytic cleavage of the central carbon–carbon bond. Presumably, cleavage of the carbon–carbon bond generates a radical pair which disproportionates to provide the observed products.     

Poly(2-imidazolin-5-ones)—A new class of heterocyclic polymers

The reaction of bisazlactones (2-oxazolin-5-ones) with primary diamines containing additional secondary or tertiary amine functionality (e.g., diethylenetriamine, triethylenetetramine, or N-methyliminobispropylamine) readily produces polyamides which serve as precursors to a new class of heterocyclic polymers. Thermal cyclodehydration takes place under relatively mild conditions (180–200°C) to produce water-soluble polymers containing the 2-imidazolin-5-one heterocycle. Model reactions have been studied to verify this mode of cyclization and confirm the proposed polymer structure.