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采用电喷雾飞行时间质谱(ESI-TOF-MS)技术,对β-环糊精与3种青蒿素类药物所形成的复合物进行研究,在正离子检测方式下,将β-环糊精与青蒿素类药物等体积比混合后直接进样,然后利用源内碰撞诱导解离(CID)技术对其复合物进行分析.实验表明,在气相中,该非共价复合物可以稳定存在,其化学计量比分别为1∶ 1和2∶ 1.运用该法测定了1∶ 1包络物的结合常数,考察了质谱条件及溶液条件对形成包络物的影响,通过比较结合常数的大小,探讨了β-环糊精与青蒿素类药物在气相状态下的作用方式. 相似文献
13.
Li HY Wang SM Liu HM Li J Han D Bu SS Zhang MZ 《Rapid communications in mass spectrometry : RCM》2008,22(20):3161-3171
As modified nucleosides reflect altered tRNA turnover which seems to be impaired in the body of cancer patients, they have been evaluated as potential tumor markers. High-performance liquid chromatography/electrosprary ionization quadrupole time-of-flight mass spectrometry (HPLC/ESI-Q-TOFMS) was used to identify nucleosides purified from urine in positive ionization mode. Potential nucleosides were assessed by their evident UV absorbance in HPLC and then further examined by mass spectrometric techniques. In this manner, 21 nucleosides were detected in the urine of a patient with lymphoid cancer including three modified nucleosides 5'-dehydro-2-deoxyinosine, N1,N2,N7-trimethylguanosine and N1-methyl-N2-ethylguanosine, which had never been reported previously. 相似文献
14.
N,N'-Diaryl hydrazides tethered with a polyether group at the meta positions undergo [5,5]-sigmatropic (benzidine) rearrangement reactions to furnish 4,4'-diamino-biphenyls (benzidines) strapped with a polyether unit at the 2,2'-positions. 相似文献
15.
We used Monte Carlo method to generate the configurations of disassembly of hot nucleus Au* based on the Atomic Mass Table and the conservation of mass and charge number.The resulted charge distribution of fragments was then used to calculate the conditional moments.The logarithm correlation between second and third moments of experimental charge distribution is very well reproduced by theory.It seems that no connection to the critical phenomenon of concerned system exists. 相似文献
16.
The relation between the Camassa-Holm equation and the Olver-Rosenau-Qiao equation is obtained, and we connect a new Camassa-Holm type equation proposed by Qiao etc. with the first negative flow of the KdV hierarchy by a reciprocal transformation. 相似文献
17.
In the Color Glass Condensate formalism, charged hadron p T spectra in p+p and p+Pb collisions are studied by considering an energy-dependent broadening of nucleon density distribution. Then, in the glasma flux tube picture, the n-particle multiplicity distributions at different pseudo-rapidity ranges are investigated. Both the theoretical results show good agreement with the recent experimental data from ALICE and CMS at LHC energies.The predictive results for p T or multiplicity distributions in p+p and p+Pb collisions at the Large Hadron Collider are also given in this paper. 相似文献
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Based on the nuclear effects considered in the Glauber-Gribov approach, charmed meson production in high energy deep inelastic e+A scattering is investigated in the color dipole formalism. Using the Peterson fragmentation function and the KLR-AdS/CFT color dipole model, which reasonably well describes the HERA data for the inclusive structure functions at small Bjorken-x, we present the predictive results for the D-meson transverse spectra at EIC and LHeC energies. The theoretical results indicate that the $x$-independence phenomena at very small-x predicted by the KLR-AdS/CFT model are not seen in our calculation. 相似文献
20.
In the framework of the Color Glass Condensate, the pseudo-rapidity distributions of charged hadrons in pp and pA collisions at the LHC are studied with the UGD function from the GBW model. With a χ2 analysis of the CMS data in pp collisions at √s=0.9, 2.36, 7 TeV, the normalization factor is obtained and the theoretical results are in good agreement with the experimental data. Then, considering the influence of nucleon hard partons transverse distribution on the number of participants in pA collisions by using a Glauber Monte Carlo method, we also give the predictive results for the multiplicity distributions in pPb collisions at √s=4.4 TeV. 相似文献