Synthesis of core-shell structured Au@Bi2S3 nanorod and its application as DNA immobilization matrix for electrochemical biosensor construction

The core-shell structured Au@Bi2S3 nanorods have been prepared through direct in-situ growth of Bi2S3 at the surface of pre-synthesized gold nanorods.The product was characterized by X-ray diffraction,transmission electron microscopy and energy-dispersive X-ray spectroscopy.Then the obtained Au@Bi2S3 nanorods were coated onto glassy carbon electrode to act as a scaffold for fabrication of electrochemical DNA biosensor on the basis of the coordination of-NH2 modified on 5’-end of probe DNA and Au@Bi2S3.Electrochemical characterization assays demonstrate that the Au@Bi2S3 nanorods behave as an excellent electronic transport channel to promote the electron transfer kinetics and increase the effective surface area by their nanosize effect.The hybridization experiments reveal that the Au@Bi2S3 matrix-based DNA biosensor is capable of recognizing complementary DNA over a wide concentration ranging from 10 fmol/L to 1 nmol/L.The limit of detection was estimated to be 2 fmol/L(S/N=3).The biosensor also presents remarkable selectivity to distinguish fully complementa ry sequences from basemismatched and non-complementary ones,showing great promising in practical application.     

Enzymatic silicone oligomerization catalyzed by a lipid-coated lipase

A lipid (1)-coated lipase can catalyze the oligomerization of diethoxydimethylsilane (DEDMS) in isooctane containing 2wt% water, where the polymerization occurs at the OH group of the coating lipid (1) in the enzyme cavity.     

Magnetic field generation from cosmological perturbations

In this Letter, we discuss the generation of magnetic field from cosmological perturbations. We consider the evolution of three component plasma (electron, proton, and photon) evaluating the collision term between electrons and photons up to the second order. The collision term is shown to induce electric current, which then generates magnetic field. There are three contributions, two of which can be evaluated from the first-order quantities, while the other one is fluid vorticity, which is purely second order. We estimate the magnitudes of the former contributions and show that the amplitude of the produced magnetic field is about approximately 10(-19) G at 10 Mpc comoving scale at the decoupling. Compared to astrophysical and inflationary mechanisms for seed-field generation, our study suffers from much less ambiguities concerning unknown physics and/or processes.     

p-adic multiple zeta values I.

Our main aim in this paper is to give a foundation of the theory of p-adic multiple zeta values. We introduce (one variable) p-adic multiple polylogarithms by Colemans p-adic iterated integration theory. We define p-adic multiple zeta values to be special values of p-adic multiple polylogarithms. We consider the (formal) p-adic KZ equation and introduce the p-adic Drinfeld associator by using certain two fundamental solutions of the p-adic KZ equation. We show that our p-adic multiple polylogarithms appear as coefficients of a certain fundamental solution of the p-adic KZ equation and our p-adic multiple zeta values appear as coefficients of the p-adic Drinfeld associator. We show various properties of p-adic multiple zeta values, which are sometimes analogous to the complex case and are sometimes peculiar to the p-adic case, via the p-adic KZ equation.     

Efficient synthesis of optically active α-substituted glutamate analogs possessing α-hydroxymethyl and α-alkoxymethyl groups

Highly enantioselective synthesis of (2R)-α-(hydroxymethyl)glutamate (1), a selective agonist of mGluR2 and 3, was achieved in short steps using an asymmetric version of the Strecker synthesis. This was converted into its α-methoxymethyl- and α-benzyloxymethyl derivatives 2 and 3, possible ligands as tools to investigate glutamate receptors, via protection of the sterically hindered amino group by means of phase transfer catalyst.     

Can a pomeron be really “supersoft”?

The low energy J/gf photoproduction cross-section has been studied on the basis of the Pomeron model. To incorporate the discrepancy between experimental data and predictions by conventional models, i.e. the sum of the soft Pomeron with intercept 1.08 and the hard Pomeron with intercept 1.418, a Regge trajectory associated with a scalar meson (f,a) exchange which we call “supersoft” Pomeron, is introduced additionally. To distinguish between the conventional model and this new additional Pomeron, observations related to other polarization observables in upcoming polarized experiments are discussed.     

Study of Si(0 0 1)4 × 2-Ga structure by scanning tunneling microscopy and ab initio calculation

We have studied Si(0 0 1)-Ga surface structures formed at Ga coverages of slightly above 0.50 monolayer (ML) at 250 °C by scanning tunneling microscopy (STM). 4 × 2-, 5 × 2-, and 6 × 2-Ga structures were observed in a local area on the surface. The 4 × 2-Ga structure consists of three protrusions, as observed in filled- and empty-state STM images. The characters of these structures are clearly different from those of other Si(0 0 1)-Ga structures. We also performed an ab initio calculation of the energetics for several possible models for the 4 × 2-Ga structure, and clarified that the three-orthogonal-Ga-dimer model is the most stable. Also, the results of comparing the simulated STM images and observation images at various bias voltages indicate that this structural model is the most favorable.     

Production of ultraheavy leptonium and/or quarkonium ate + e − colliders in TeV regions

The production cross section of the ultraheavy leptonium and quarkonium with the mass around 1 TeV which have the contribution of the Higgs-boson exchange is calculated in TeV regions ate ⁺ e ^? colliders. In some kinematical regions, we find that the Drell ratio for a bound state production shows a prominent resonance structure.