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排序方式: 共有139条查询结果,搜索用时 156 毫秒
61.
David Cousin 《Tetrahedron》2008,64(16):3534-3540
We describe new methodology for the synthesis of both enantiomers of 7,7-dichlorobicyclo[3.2.0]hep-2-en-6-one and conversion of these compounds into stereochemically defined bicyclo[3.3.0]oct-2-en-7-ones and thence trisubstituted cyclopentanes. These are key intermediates for the synthesis of prostanoids, brefeldin and other cyclopentane-containing natural products. 相似文献
62.
Haouache Somia Jimenez-Saelices Clara Cousin Fabrice Falourd Xavier Pontoire Bruno Cahier Karine Jrome Franois Capron Isabelle 《Cellulose (London, England)》2022,29(3):1567-1581
Cellulose - Nanocelluloses occur under various crystalline forms that are currently being selectively used for a wide variety of high performance materials. In the present study, two cellulose... 相似文献
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64.
Mikhail K. Gratchev Galina I. Kurochkina Eric Monflier Sebastien Tilloy Herve Bricout Edward E. Nifantiev 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6-7):1489-1492
Principal peculiarities of the use of phosphocontaining cyclodextrins as a new class of supramolecular structures are discussed. For the first time cyclodextrin perphosphite has been obtained and isolated in an individual state by the treatment of g -cyclodextrin with triazolide neopentylenephosphorous acid. Cyclodextrin perphosphite exhibited an unusual transphosphorylation under reaction with some chlorophosphites. The inclusion of adamantane into the cyclodextrin cavity results in slowing this reaction down. Some water-soluble cyclodextrin derivatives displayed high activity as phase transfer catalysts in biphase catalysis. 相似文献
65.
Sabine Gei? Max Schneider Gerhild Donnevert Jürgen W. Einax Nicole Lettmann Aurélien Rey Herbert Lepper Birgit K?rner Theodor Prey Bettina Hilger Moana Engelke Marie-Pierre Strub Herve Adrien George Sawal Dirk L?ffler Tom Schillings Ines Hussy Philipp Steinbichl Sigrid Scharf Alexander Ruderisch Jorge E. Olmos F. Javier Santos Arantxa Bartolome Josep Caixach 《Accreditation and quality assurance》2012,17(1):15-25
A validation interlaboratory trial was carried out to prepare ISO 12010: Water quality??Determination of short-chain polychlorinated alkanes (SCCP) in water??Method using gas chromatography/mass spectrometry (GC-MS) and electron capture negative ionisation (ECNI). The task was to determine the sum of short-chain polychlorinated n-alkanes with carbon chain lengths of C10?CC13 and a chlorine content between 49% (g/100?g) and 67% (g/100?g) in water by GC-ECNI-MS. The quantification had to be performed by multiple linear regression as described in ISO/DIS 12010, the compulsory method. Samples distributed were real river samples, and waste water spiked with a target concentration of 0.4 and 0.6???g/L for the sum of SCCPs, i.e. a concentration around the environmental quality target level according to the European Water Framework Directive. The different types of water samples tested were surface water with <150?mg/L suspended matter, surface water with 0.5?g/L suspended matter, and filtered waste waster. The interlaboratory trial included the extraction of the water samples, a column chromatographic clean up, a concentration step, and integration of chromatographic unresolved complex mixtures as well as the calibration and quantification by multiple linear regression. The reproducibility standard deviation of the standard concentration was 11.9%. Reproducibility standard deviations of concentrations in the three different water samples between 27.8 and 34.2% were achieved by 10?C12 participating laboratories from six countries. 相似文献
66.
We demonstrate a simplified arrangement for spatiotemporal ultrashort pulse characterization called Hartmann-Shack assisted, multidimensional, shaper-based technique for electric-field reconstruction. It employs an acousto-optic pulse shaper in combination with a second-order nonlinear crystal and a Hartmann-Shack wavefront sensor. The shaper is used as a tunable bandpass filter, and the wavefronts and intensities of quasimonochromatic spectral slices of the pulse are obtained using the Hartmann-Shack wavefront sensor. The wavefronts and intensities of the spectral slices are related to one another using shaper-assisted frequency-resolved optical gating measurements, performed at particular points in the beam. This enables a three-dimensional reconstruction of the amplitude and phase of the pulse. We present some example pulse measurements and discuss the operating parameters of the device. 相似文献
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68.
We review, based on structural information, the mechanisms involved when putting in contact two nano-objects of opposite electrical charge, in the case of one negatively charged polyion, and a compact charged one. The central case is mixtures of PSS, a strong flexible polyanion (the salt of a strong acid, and with high linear charge density), and Lysozyme, a globular protein with a global positive charge. A wide accurate and consistent set of information in different situations is available on the structure at local scales (5-1000?), due to the possibility of matching, the reproducibility of the system, its well-defined electrostatics features, and the well-defined structures obtained. We have related these structures to the observations at macroscopic scale of the phase behavior, and to the expected mechanisms of coacervation. On the one hand, PSS/Lysozyme mixtures show accurately many of what is expected in PEL/protein complexation, and phase separation, as reviewed by de Kruif: under certain conditions some well-defined complexes are formed before any phase separation, they are close to neutral; even in excess of one species, complexes are only modestly charged (surface charges in PEL excess). Neutral cores are attracting each other, to form larger objects responsible for large turbidity. They should lead the system to phase separation; this is observed in the more dilute samples, while in more concentrated ones the lack of separation in turbid samples is explained by locking effects between fractal aggregates. On the other hand, although some of the features just listed are the same required for coacervation, this phase transition is not really obtained. The phase separation has all the macroscopic aspects of a fluid (undifferentiated liquid/gas phase) - solid transition, not of a fluid-fluid (liquid-liquid) one, which would correspond to real coacervation). The origin of this can be found in the interaction potential between primary complexes formed (globules), which agrees qualitatively with a potential shape of the type repulsive long range attractive very short range. Finally we have considered two other systems with accurate structural information, to see whether other situations can be found. For Pectin, the same situation as PSS can be found, as well as other states, without solid precipitation, but possibly with incomplete coacervation, corresponding to differences in the globular structure. It is understandable that these systems show smoother interaction potential between the complexes (globules) likely to produce liquid-liquid transition. Finally, we briefly recall new results on Hyaluronan/Lysozyme, which present clear signs of coacervation in two liquid phases, and at the same time the existence of non-globular complexes, of specific geometry (thin rods) before any phase separation. These mixtures fulfill many of the requirements for complex coacervation, while other theories should also be checked like the one of Shklovskii et al. 相似文献
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70.
An acousto-optic pulse shaper has been used to characterize few-cycle pulses generated in a hollow-core fiber. A grism pair precompensates for the dispersion of the acousto-optic crystal, allowing the full pulse-shaping window to be used for replica generation rather than self-compensation. A 9.4 fs pulse was measured, the shortest ever measured with an acousto-optic pulse shaper, to our knowledge. 相似文献