One-pot synthesis of 2-trifluoromethylchromones

We report a simple and suitable method for the preparation of useful 2-trifluoromethylchromones in one step, in high yields and avoiding the use of solvents. We were able to detect the intermediate of this reaction. Furthermore a mechanism for the formation of the 7-methoxy-3-trifluoroacetyl-2-trifluoromethylchromone through the unexpected double trifluoroacetylation of 4-methoxy-2-hydroxyacetophenone followed by dehydration is also proposed. All compounds are fully identified and characterized by spectroscopic techniques.     

X-ray diffraction, Raman spectrum and magnetic susceptibility of the magnetic semiconductor Cu2FeSnS4

In an attempt to resolve the crystal structure and the corresponding space group of the magnetic semiconductor Cu₂FeSnS₄, samples of this compound were studied by X-ray diffraction, differential thermal analysis, Raman scattering and magnetic susceptibility. It was found that at room temperature this compound prepared by a careful crystal growth process, including annealing to equilibrium at a suitable temperature followed by slow cooling of the samples to 300 K, crystallizes in a tetragonal structure with space group .     

Code retrieval via undercover multiplexing

The purpose of this research is to develop an undercover multiplexing technique to give additional protection for optical information encryption. We employ the double random phase mask as our basic optical encryption system. The holographic storage medium of choice is a photorefractive crystal. To achieve the multiplexing we use the aperture size of the pupil in the optical system, as it governs the speckle size. We introduce such variation in order to produce a decorrelation between two consecutively stored speckle patterns. Each stored speckle pattern is associated to an input encrypted image, thus producing a multiplexing of the encrypted information. We implement this operation without altering the setup architecture and the random phase masks. This multiplexing is our undercover operation to encipher a true code behind a fake code. Under this approach, the user can only recover the bulk information stored in the volume hologram. However, he cannot recover the true code without the additional information on the pupil size key, even if accessed in position of the original decoding mask.     

Fluorescence Measurements of Steady State Peroxynitrite Production Upon SIN-1 Decomposition: NADH Versus Dihydrodichlorofluorescein and Dihydrorhodamine 123

The production of peroxynitrite during 3-morpholinosydnonimine (SIN-1) decomposition can be continuously monitored, with a sensitivity 0.1 M, from the kinetics of NADH fluorescence quenching in phosphate buffers, as well as in buffers commonly used with cell cultures, like Locke's buffer or Dulbecco's modified Eagle's medium (DMEM-F12). The half-time for peroxynitrite production during SIN-1 decomposition ranged from 14–18 min in DMEM-F12 (plus and minus phenol red) to 21.5 min in Locke's buffer and 26 min in DMEM-F12 supplemented with apotransferrin (0.1 mg/mL). The concentration of peroxynitrite reached a peak that was linearly dependent upon SIN-1 concentration, and that for 100 M SIN-1 amounted to 1.4 ± 0.2 M in Locke's buffer, 3.2–3.6 M in DMEM-F12 (plus and minus phenol red) and 1.8 M in DMEM-F12 supplemented with apotransferrin. Thus, the maximum concentration of peroxynitrite ranged from 1.2 to 3.6% of added SIN-1. NADH was found to be less sensitive than dihydrorhodamine 123 and 2,7-dichlorodihydrofluorescein diacetate to oxidation by H₂O₂, which is produced during SIN-1 decomposition in common buffers. It is shown that peroxynitrite concentration can be controlled (±5%) during predetermined times by using sequential SIN-1 pulses, to simulate chronic exposure of cells or subcellular components to peroxynitrite.     

In situ transient FTIR and XANES studies of the evolution of surface species in CO oxidation on Au/TiO2

The adsorption of CO and its reaction with oxygen were investigated using a combination of in situ Fourier transform infrared spectroscopy, step response measurements in a microreactor, (18)O isotopic labeling, and X-ray absorption near edge structure spectroscopy. An as-prepared sample in which Au is present as a surface oxyhydroxy complex does not adsorb CO. On an activated sample in which only metallic Au is detected, 0.18 +/- 0.03 mol CO/(mol Au) are adsorbed on Au at -60 degrees C, which shows an IR band at 2090 cm(-1). When oxygen is present in the gas phase, this species reacts with a turnover rate of 1.4 +/- 0.2 mol CO(mol Au min)(-1), which is close to the steady-state turnover rate. In contrast, there is a very small quantity of adsorbed oxygen on Au. A small IR peak at 1242 cm(-1) appears when an activated sample is exposed to CO. It reacts rapidly with oxygen and is shifted to 1236 cm(-1) if (18)O is used. It is assigned to the possible intermediate hydroxycarbonyl.     

The impact of multi-skilling on personnel scheduling in the service sector: a retail industry case

Using personnel scheduling to reduce overstaffing and understaffing in a service industry across multiple periods is often undermined by lack of flexibility due to the exclusive use of specialized personnel. This study analyses the impacts of assigning multi-skilled personnel to different activities and its potential for improving schedule efficiency. A proposed mixed integer linear programming model determines which employees are trained to work in which activities and their assignments over a one-week planning horizon. The model results show that the lowest total-cost multi-skilled configurations are obtained in scenarios where personnel supply and demand are in equilibrium. Half of employees would continue to be specialized for just one activity while the half slated for multi-skilling would be trained in most cases for just one additional activity, even though training cost is assumed to be minimal. It is also shown that multi-skilling is best applied to employees whose contracts are highly flexible.     

Prevailing effects of interference or diffraction by multiple apertures

The effects of interference and diffraction produced by a bidimensional structure composed of multiple and identical apertures are studied. Such effects are competitive during the propagation, that is, in some planes the interference effects are more visible, while in others prevail the diffraction ones. Using the number of Fresnel zones, the spatial domains where the interference or diffraction effects prevail are defined and parameterized. Simulation and experimental results are further introduced to verify the proposed method.     

Information encryption through dyadic permutations

Dyadic displacements of an image can be interpreted as a special type of permutations of its pixel addresses. Owing to this property, they can be used to encrypt the information contained in the pictures without information loss or damage. The information recovery can be performed successfully by using dyadic correlations.