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21.
Hiroyasu Sato 《应用有机金属化学》1991,5(4):207-219
This is meant to be a brief overview of the developments of research activities in Japan on organometallic compounds related to their use in electronic and optoelectronic devices. The importance of organometallic compounds in the deposition of metal and semiconductor films for the fabrication of many electronic and opto-electronic devices cannot be exaggerated. Their scope has now extended to thin-film electronic ceramics and high-temperature oxide superconductors. A variety of organometallic compounds have been used as source materials in many types of processing procedures, such as metal–organic chemical vapor deposition (MOCVD), metalorganic vapor-phase epitaxy (MOVPE), metal–organic molecular-beam epitaxy (MOMBE), etc. Deposited materials include silicon, Group III–V and II–VI compound semiconductors, metals, superconducting oxides and other inorganic materials. Organometallic compounds are utilized as such in many electronic and optoelectronic devices; examples are conducting and semiconducting materials, photovoltaic, photochromic, electrochromic and nonlinear optical materials. This review consists of two parts: (I) research related to the fabrication of semiconductor, metal and inorganic materials; and (II) research related to the direct use of organometallic materials and basic fundamental research. 相似文献
22.
23.
M. Sato 《Journal of mathematical chemistry》1991,7(1):341-352
In the first part, a topological characterization of various zeolite frameworks is performed on the basis of the Hamiltonian graph. It affords a simple representation of the framework connectivity, and presents some possibility of the classification as well as the prediction of unknown frameworks. In the second part, a simple and direct method based on the connectivity matrix is presented, by which all the possible Al distributions in a given framework are derived exhaustively under the restriction of Loewenstein's rule. An example of Al preference site determination is applied for zeolite ZSM-5 and compared with the result by the SCF-MO method. 相似文献
24.
Hoon Kim Toshihiko Koseki Tomohiro Ohta Hiroshi Sato Yukihiro Shimogaki 《Applied Surface Science》2006,252(11):3938-3942
The adhesion of Cu on Ru substrates with different crystal orientations was evaluated. The crystal orientation of sputter deposited Ru could be changed from (1 0 0) to (0 0 1) by annealing at 650 °C for 20 min. The adhesion of Cu was evaluated by the degree of Cu agglomeration on Ru. Cu films on annealed Ru films with the (0 0 1) crystal orientation showed 28% lower RMS values and 50% lower Ru surface coverage than Cu as-deposited on Ru having the (1 0 0) crystal orientation after annealing at 550 °C for 30 min, which suggest that Cu wettability on the Ru(0 0 1) was better than that on the Ru(1 0 0) plane. The low lattice misfit of 4% between Cu(1 1 1) and Ru(0 0 1) may be the reason for this good adhesion property. 相似文献
25.
N Murakami T Tanase S Nagai Y Sato T Ueda J Sakakibara H Ando Y Hotta K Takeya 《Chemical & pharmaceutical bulletin》1991,39(8):1962-1966
The Diels-Alder reactions of a cardiac glycoside, proscillaridin (1), with some dienophiles were investigated. The reaction of 1 with alkenes such as methyl vinyl ketone and methyl acrylate afforded 3-oxo-2-oxabicyclo[2.2.2]oct-7-enes (2-5) and para-substituted benzene derivatives (6 and 7), while 1 reacted with alkynes (3-butyn-2-one, methyl propiolate) to yield para- or meta-substituted benzene derivatives (6-9). The biological activities of the resulting derivatives were evaluated by the use of isolated guinea-pig papillary muscle preparations and Na+,K(+)-adenosine triphosphatase (ATPase) preparation from dog kidney. Among the proscillaridin derivatives, compounds 4 and 7 moderately inhibited Na+,K(+)-ATPase activity. Furthermore, the concentration range of 7 over which its positive inotropic effect on guinea-pig papillary muscle preparations, increased from 5% to 95% of maximum was broader than that of 1, i.e., concentration dependency was maintained over a greater range of concentration. 相似文献
26.
Y. Masuda K. Asahi J. Kura Y. Mori H. Sato H. M. Shimizu 《Hyperfine Interactions》1992,74(1-4):149-157
An experimental scheme of the spin detailed balance in polarized neutron transmission through a polarized nuclear target is
discussed for the T-violation test. The value of the spin detailed balance is estimated by using the data of the scattering
amplitudes. The nuclear polarizations of proton,3He and139La are discussed for the T-violation experiment. 相似文献
27.
H. Sato A. Tani A. J. Fielding S. S. Eaton G. R. Eaton N. E. Whitehead M. Ikeya 《Applied magnetic resonance》2004,26(4):601-616
Nitrate radical NO32− in calcitic evaporate was discovered in Antarctica. The distribution and formation of nitrate radical NO32− in the calcite have been studied by pulse and continuous-wave electron spin resonance. In samples that had been annealed
to destroy the NO32−, regeneration of the radical by γ-rays or UV light indicated that the radical was formed by UV light (with wavelengths less
than 340 nm) from solar rays, not by environmental radiation. The nonuniform spatial distribution of the nitrate radical,
which was deduced from high ratios of local spin density to total spin density, suggests that the nitrate impurity was introduced
into the calcium carbonate after carbonate grain formation. Formation of the carbonate-containing nitrate requires the presence
of high amounts of nitrate and a dry climate. Formation of the nitrate radical requires sample exposure to UV light. These
conditions are satisfied in the environment of Antarctica. 相似文献
28.
The motion of a moored floating body under the action of wave forces, which is influenced by fluid forces, shape of the floating body and mooring forces, should be analysed as a complex coupled motion system. Especially under severe storm conditions or resonant motion of the floating body it is necessary to consider finite amplitude motions of the waves, the floating body and the mooring lines as well as non-linear interactions of these finite amplitude motions. The problem of a floating body has been studied on the basis of linear wave theory by many researchers. However, the finite amplitude motion under a correlated motion system has rarely been taken into account. This paper presents a numerical method for calculating the finite amplitude motion when a floating body is moored by non-linear mooring lines such as chains and cables under severe storm conditions. 相似文献
29.
M. Sato 《等离子体物理论文集》1991,31(3):331-335
The Saha equation for a plasma in thermodynamic equilibrium (TE) is approximately solved to give the temperature as an explicit function of population densities. It is shown that the derived expressions for the Saha temperature are valid approximations to the exact solution. An application of the approximate temperature to the calculation of TE plasma parameters is also described. 相似文献
30.
Takuji Sato 《Proceedings of the American Mathematical Society》2003,131(9):2903-2909
We obtain a non-Kähler almost Hermitian manifold of constant holomorphic sectional curvature by changing the almost complex structure in a Kähler manifold of constant holomorphic sectional curvature.