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111.
Kai Wu Kang Li Sha Chen Ya‐Jun Hou Yu‐Lin Lu Jing‐Si Wang Mei‐Juan Wei Mei Pan Cheng‐Yong Su 《Angewandte Chemie (International ed. in English)》2020,59(7):2639-2643
A nanocage coupling effect from a redox RuII‐PdII metal–organic cage (MOC‐16) is demonstrated for efficient photochemical H2 production by virtue of redox–guest modulation of the photo‐induced electron transfer (PET) process. Through coupling with photoredox cycle of MOC‐16, tetrathiafulvalene (TTF) guests act as electron relay mediator to improve the overall electron transfer efficiency in the host–guest system in a long‐time scale, leading to significant promotion of visible‐light driven H2 evolution. By contrast, the presence of larger TTF‐derivatives in bulk solution without host–guest interactions results in interference with PET process of MOC‐16, leading to inefficient H2 evolution. Such interaction provides an example to understand the interplay between the redox‐active nanocage and guest for optimization of redox events and photocatalytic activities in a confined chemical nanoenvironment. 相似文献
112.
Shijie Ding Lingyu Kong Yanjuan Jin Jinbao Lin Chao Chang Huaying Li Erqiang Liu Haitao Liu 《先进技术聚合物》2020,31(4):873-884
Fused deposition molding (FDM) is one of the most widely used three‐dimensional (3D) printing technologies. This paper explores the influence of the forming angle on the tensile properties of FDM specimens. Orthogonal layering details were studied through experiments, theory, and finite element simulations. The stiffness and strength of the specimens were analyzed using the classical laminated plate theory and the Tsai–Wu failure criterion. The experimental process was simulated using finite element simulations. Results show that it is feasible to predict the stiffness and strength of FDM specimens using classical laminated plate theory and the Tsai–Wu failure criterion. A molding angle of 45° leads to specimens with maximized tensile properties. Numerical simulations show that changing the molding angle changes the internal stress and deformation fields inside samples, leading to FDM samples with different mechanical properties due to the orthogonal layers at different molding angles. 相似文献
113.
Chen Sun Ya‐Hui Guo Sha‐Sha Han Jing‐Zhao Li Kuan Jiang Lin‐Feng Dong Qi‐Long Liu Cheng‐Yang Yue Xiao‐Wu Lei 《Angewandte Chemie (International ed. in English)》2020,59(38):16465-16469
Considering the instability and low photoluminescence quantum yield (PLQY) of blue‐emitting perovskites, it is still challenging and attractive to construct single crystalline hybrid lead halides with highly stable and efficient blue light emission. Herein, by rationally introducing d10 transition metal into single lead halide as new structural building unit and optical emitting center, we prepared a bimetallic halide of [(NH4)2]CuPbBr5 with new type of three‐dimensional (3D) anionic framework. [(NH4)2]CuPbBr5 exhibits strong band‐edge blue emission (441 nm) with a high PLQY of 32 % upon excitation with UV light. Detailed photophysical studies indicate [(NH4)2]CuPbBr5 also displays broadband red light emissions derived from self‐trapped states. Furthermore, the 3D framework features high structural and optical stabilities at extreme environments during at least three years. To our best knowledge, this work represents the first 3D non‐perovskite bimetallic halide with highly efficient and stable blue light emission. 相似文献
114.
Mingguang Wu Jiaqin Liao Lingxiao Yu Ruitao Lv Peng Li Wenping Sun Rou Tan Xiaochuan Duan Lei Zhang Fang Li Jiyoung Kim Kang Ho Shin Ho Seok Park Wenchao Zhang Zaiping Guo Haitao Wang Yongbing Tang George Gorgolis Costas Galiotis Jianmin Ma 《化学:亚洲杂志》2020,15(7):995-1013
Carbon is a simple, stable and popular element with many allotropes. The carbon family members include carbon dots, carbon nanotubes, carbon fibers, graphene, graphite, graphdiyne and hard carbon, etc. They can be divided into different dimensions, and their structures can be open and porous. Moreover, it is very interesting to dope them with other elements (metal or non‐metal) or hybridize them with other materials to form composites. The elemental and structural characteristics offer us to explore their applications in energy, environment, bioscience, medicine, electronics and others. Among them, energy storage and conversion are extremely attractive, as advances in this area may improve our life quality and environment. Some energy devices will be included herein, such as lithium‐ion batteries, lithium sulfur batteries, sodium‐ion batteries, potassium‐ion batteries, dual ion batteries, electrochemical capacitors, and others. Additionally, carbon‐based electrocatalysts are also studied in hydrogen evolution reaction and carbon dioxide reduction reaction. However, there are still many challenges in the design and preparation of electrode and electrocatalytic materials. The research related to carbon materials for energy storage and conversion is extremely active, and this has motivated us to contribute with a roadmap on ‘Carbon Materials in Energy Storage and Conversion’. 相似文献
115.
Wen-Jie Shi Dan Liu Xin Li Dr. Sha Bai Prof. Yao-Yu Wang Prof. Dr. Ying-Feng Han 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(29):7853-7861
The incorporation of functional groups into the cavity of discrete supramolecular coordination cages (SCCs) will bring unique functions and applications. Here, three dicarboxylate ligands (H2 L1 Cl, H2 L2 Cl and H2 L3 Cl) containing N-heterocyclic carbene (NHC) precursors as linkers were introduced to construct SCCs by combining with two C3-symmertic (CpZr)3(μ3-O)(μ2-OH)3 clusters as three-connect vertices, resulted in a series of rugby-like V2E3 (V=vertex, E=edge) type homoleptic cages ( SCC-1 , SCC-2 and SCC-3 ). However, V4E6-type tetrahedral cages ( SCC-4 and SCC-5 ), incorporating six Au-NHC moieties, were obtained when the corresponding NHC-gold(I) functionalized ligands (H2 L1 Au, H2 L2 Au) were applied. For the first time, we present a trackable CpZr-involved cage to cage conversion to generate a heteroleptic V2E3 cage ( SCC-6 ) from two homoleptic cages ( SCC-2 and SCC-5 ) with different geometries of V2E3 and V4E6. The heteroleptic assembly SCC-6 can also be formed upon a subcomponent displacement strategy. The structural transformation and reassembly processes were detected and monitored by 1H NMR spectroscopy and electrospray-ionization mass spectrometry. The formation of heteroleptic assembly was further supported by single crystal X-ray diffraction analysis. Moreover, homoleptic cage SCC-2 possesses a trigonal bipyramidal cationic cavity allowing the encapsulation of a series of sulfonate anionic guests. 相似文献
116.
A local gradient estimate for positive solutions of porous medium equations on complete noncompact Riemannian manifolds under the Ricci flow is derived. Moreover, a global gradient estimate for such equations on compact Riemannian manifolds is also obtained. 相似文献
117.
Xi Liu Yi Qin Junlong Zhu Xiaoli Zhao Tanyu Cheng Yanrong Jiang Haitao Sun Lin Xu 《中国化学快报》2021,32(4):1537-1540
A series of triphenylamine (TPA) derivatives with various substituent groups were prepared and showed different absorption and fluorescence characteristics due to the substituent effect. On account of the existence of pyridine units, these TPA derivatives exhibited acid-induced tunable multicolor fluorescence emission including white light emission. In addition, acid-induced fluorescence regulation of these compounds has been also realized in the solid state, which enable them to be successfully constructed the stimuli-responsive fluorescent films and fluorescent inks for inkjet printing. 相似文献
118.
Theoretical Analysis of Interference Nanolithography of Surface Plasmon Polaritons without a Match Layer 下载免费PDF全文
Interference nanolithography techniques based on long-range surface plasmon polaritons (LR-SPP) are hardly ever achieved by experiments at present. One key reason is that suitable liquid materials are difflcult to find as the match layer connects the metal film and the resist. We redesign a Kretschmann-Raether structure for interference lithography. A polymer layer is coated under the metal film, and an air layer is placed between the polymer layer and the resist layer. This design not only avoids the above-mentioned question of the match layer, but also can form a soft contact between the polymer layer and the resist layer and can protect the exposure pattern. Simulation results confirm that a device with an appropriately thick polymer layer can form high intensity and contrast interference fringes with a critical dimension of about λ/7 in the resist. In addition, the fabrication of the device is very easy. 相似文献
119.
Total syntheses of nine novel phospholipids were accomplished to facilitate the identification and biological testing of compounds that are generated upon oxidative cleavage of arachidonate and linoleate esters of 2-lysophosphatidylcholine, the two most abundant polyunsaturated phospholipids in low-density lipoprotein. An efficient general synthesis exploiting 2-lithiofuran as a 4-oxo-2-butenoyl carbanion equivalent provided phospholipids containing gamma-keto-alpha,beta-unsaturated carbonyl functional arrays. By exploiting facile cis-trans isomerizations, two commercially available cis alkenes, (2Z)-2-butene-1,4-diol and 2,5-dihydrofuran, could be employed as starting materials for preparing the Horner-Wadsworth-Emmons reagent 4-(diethoxyphosphoryl)-2E-butenal, a valuable building block for the synthesis of 2,4-dienals. The reagent was exploited in a total synthesis of 13-oxotridec-9E,11E-dienoic acid, confirming the identity of this product that is generated upon autoxidation of linoleic acid and by decomposition of 13-hydroperoxy-9,11-octadecadienoate (13-HPODE), especially in the presence of redox active transition metal ions, cytochrome p-450, or hydroperoxide lyase. 相似文献
120.
可能性理论的推广方法及合理性研究 总被引:1,自引:0,他引:1
本文通过引入二维可能性分布函数的概念,将可能性测度推广到二维的情形。并给出了二维可能性测度的一些重要性质。文中还重点证明了该推广方法的合理性。 相似文献