On the nontrivial non-travelling wave profiles of nonlinear evolution and wave equations

The overall aim of the present paper is to find and analyze the new non-travelling wave solutions of the nonlinear evolution and wave equations. With the aid of symbolic computation and based on the generalized extended tanh-function method, we propose the newly extended tanh-function expansion algorithm and get many new non-travelling wave solutions of the (2 + 1)-dimensional Broer–Kaup–Kupershmidt equations. The solutions which we obtain are more abundant than the solutions which the generalized extended tanh-function method gets. At the same time, the solutions contain arbitrary functions which may be helpful to explain some complex phenomena. We also give some figures to describe the property of these solutions. In additions, the method can also be successfully applied to other nonlinear evolution and wave equations.     

ML／Y分子筛复合材料的制备,表征及其催化性能研究

采用沸石合成法制备了ＭＬ／Ｙ（Ｍ＝ Ｆｅ，Ｃｏ，Ｃｒ；Ｌ＝ ８－ ｑｕｉｎｏｌｉｎｏｌａｎｄ ｓａｌｉｃｙｌｉｃ ａｃｉｄ （ｄｅｎｏｔｅｄ ａｓＱｘ ａｎｄ ＳＡｒｅｓｐｅｃｔｉｖｅｌｙ）） 复合材料，并通过ＸＲＤ、ＦＴＩＲ、ＩＣＰ、ＵＶ－ ｖｉｓ 及催化反应等手段对其进行了表征。ＦＴＩＲ和ＵＶ－ ｖｉｓ 测试结果表明： 合成体系中含有的金属配合物经过水热晶化后封装或固定在分子筛的空腔中。通过Ｘ射线衍射原位跟踪Ｙ型分子筛的晶化过程，发现合成体系中含有金属配合物的性质及其量的多少不仅对Ｙ型分子筛的晶化有很大影响，而且使其封装或固定在分子筛中的量也有所差异。另外，以环己烷氧化为探针反应考察了ＭＬ／Ｙ的催化性能，结果表明ＭＬ／Ｙ的氧化能力来自于所封装或固定的金属配合物，其氧化能力主要取决于配合物中心离子的性质     

Novel gel polymer electrolyte based on matrix of PMMA modified with polyhedral oligomeric silsesquioxane

Journal of Solid State Electrochemistry - One novel cage kind of polyhedral ligomeric silsesquioxane (POSS), for modification application of gel polymer electrolyte (GPE) in lithium ion batteries...     

General admissibility for linear estimators in a general multivariate linear model under balanced loss function

A generalization of Zellner’s balanced loss function is proposed. General admissibility in a general multivariate linear model is investigated under the generalized balanced loss function. And the sufficient and necessary conditions for linear estimators to be generally admissible in classes of homogeneous and nonhomogeneous linear estimators are given, respectively.     

An investigation of the deprotonation of hydrazone-based receptors on interaction with anion: develop a colorimetric system distinguishing cyanide from anions

Hydrazone-based receptors, containing fluorene-skeleton substituents, in a THF solution, in the presence of fluoride or cyanide, do not only form H-bond complexes, but mainly undergo deprotonation of the N–H fragments, an event, which is signaled by the color change, the ability of the deprotonation is associated with the fluorene skeleton. The deprotonation process is also reversible by the addition of metal ions, while cyanide from fluoride could be distinguished by the addition of copper (II).     

Zn-Co bimetallic supported ZSM-5 catalyst for phosgene-free synthesis of hexamethylene–1,6–diisocyanate by thermal decomposition of hexamethylene–1,6–dicarbamate

A set of mono-and bimetallic(Zn-Co) supported ZSM-5 catalysts was first prepared by PEG-additive method. The physicochemical properties of the catalysts were investigated by FTIR, XPS, XRD, N_2adsorption-desorption measurements, SEM, EDS and NH3-TPD techniques. The physicochemical properties showed that the Zn Co_2O_4 spinel oxide was formed on the ZSM-5 support and provided effectual synergetic effect between Zn and Co species for the bimetallic catalyst. Furthermore, bimetallic supported ZSM-5 catalyst exhibited weak, moderate and strong acidic sites, while the monometallic supported ZSM-5 catalyst showed only weak and moderate or strong acidic sites. Their catalytic performances for thermal decomposition of hexamethylene–1,6–dicarbamate(HDC) to hexamethylene–1,6–diisocyanate(HDI) were then studied. It was found that the bimetallic supported ZSM-5 catalysts,especially Zn-2Co/ZSM-5 catalyst showed excellent catalytic performance due to the good synergetic effect between Co and Zn species, which provided a suitable contribution of acidic sites. HDC conversion of 100% with HDI selectivity of 91.2% and by-products selectivity of 1.3% could be achieved within short reaction time of 2.5 h over Zn-2Co/ZSM-5 catalyst.     

Two New Daphniphyllum Alkaloids from Daphniphyllum calycinum

Two new daphniphyllum alkaloids named 2‐hydroxyyunnandaphnine D ( 1 ) and methyl 7‐hydroxyhomodaphniphyllate ( 2 ), together with eight known alkaloids, daphnioldhanin D, calyciphylline F, calyciphylline B, deoxycalyciphylline B, daphnicyclidin H, macropodumine C, 9,10‐epoxycalycine A, and yunnandaphnine A, were isolated from the stems and leaves of Daphniphyllum calycinum. Their structures and relative configurations were established on the basis of spectral evidence (including 2D‐NMR) and subsequently confirmed by a single‐crystal X‐ray crystallographic diffraction analysis.