Methane conversion in a multielectrode slipping surface discharge in the two-phase water-gas medium

The multielectrode slipping surface discharge in a two-phase water-gas (methane) medium is studied experimentally as a plasma-chemical converter of methane into various hydrocarbons, carbon, and hydrogen. The energy value of methane decomposition is on the order of 5 eV/molecule, which is close to record-high values attained in high-pressure discharges. The degree of conversion of methane is determined and the possibility of its substantial increase is considered.     

Numerical study of the effects occurring near a circular cylinder in stratified fluid flows with short buoyancy periods

Flow around a two-dimensional circular cylinder of a stratified fluid with periods buoyancy T_b = 25.2 and 6.28 sec is studied numerically over a wide range of Reynolds and Froude numbers. It is found that in the presence of a perturbation ahead of a cylinder which moves downstream with increasing Reynolds number, the salinity isolines have the shape of a semi-circular comb with sharp teeth. The shape change of the attached waves and the occurrence of fluid layers of different densities in the cylinder wake are studied. In flows with a buoyancy period T_b = 6.28 sec at Reynolds numbers Re < 60, stagnant zones are found in the cylinder wake, and at Re > 60, these zones are absent.     

Synthesis and crystal structure of α,α′-dihydroxydi(perfluorocyclohexyl)peroxide

Conclusions Reaction of stoichiometric quantities of perfluorocyclohexanone and 98% H₂O₂ in neutral media quantitatively forms ,-dihydroxydi(perfluorohexyl)peroxide, for which the main crystal and molecular structural parameters were determined by x-ray analysis.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 918–923, April, 1989.     

Compression of whistler waves in a plasma with a nonstationary magnetic field

We present the results of our experiments in which the propagation of whistler waves in a plasma with a nonstationary magnetic-field perturbation (B=B₀+δB(t), δB/B₀ ≤ 5%) was investigated. The parametric and dispersive phenomena in a variable magnetic field were studied on the unique Krot plasma bench (the plasma column was 4 m in length and 1.5 m in diameter). A periodic field perturbation is shown to lead to an amplitude-frequency modulation of the whistler wave and to fragmentation of the signal into separate frequency-modulated wavepackets followed by their compression. The formation and compression of pulses is attributable to strong whistler group-velocity dispersion near the electron cyclotron frequency (ω ≤ ω_H). The results can be used to interpret the spectral shapes of the signals received from the Earth’s magnetosphere and ionosphere in the electron and ion whistler frequency ranges.     

Potassium as a promoter in the Co-based Fischer-Tropsch catalysis

A doping effect of a Co catalyst with potassium in the Fischer-Tropsch synthesis was found to sharply decrease formation of methane, increase selectivity on the C₅₊ hydrocarbons, and increase the chain growth index.     

Qubits based on spectrally selected groups of Pr<Superscript>3+</Superscript> ions in a LaF<Subscript>3</Subscript> crystal

Spectral selection, i.e., the separation of a group of particles with a spread in resonance frequencies smaller than the hyperfine splitting of working levels has been implemented by the method of burning of long-lived spectral dips in the inhomogeneously broadened absorption line of Pr³⁺ in a LaF₃ crystal. The possibility of implementing qubits (basic elements of quantum computations) on ensembles of spectrally selected particles and the main operations with them, including the manipulation of the populations of hyperfine (qubit) levels and the controlled shift of the absorption line of one spectrally selected group of ions upon excitation of another group (two-qubit operations), has been demonstrated. The decay rates of the population of hyperfine sublevels of the ground state of the spectrally selected group of particles have been measured.     

Special characteristics of the propagation of three-dimensional viscous jets

Numerical investigations were made of the propagation, in a supersonic wake, of uncalculated jets, flowing out of nozzles of square and rectangular cross section, and of lumped jets, made up of from two to nine individual jets; the special characteristics of their flow were investigated in the initial, transitional, and main sections. Specifically, for lumped jets, the possibility of replacing them by a single axisymmetric jet, equivalent in mass-flow rate, is discussed. To calculate a three-dimensional unexpanded supersonic jet, flowing out into a wake, in [1] it was proposed to use a numerical method for solving a simplified system of Navier-Stokes equations for steady-state flow, and numerical investigations were made of the three-dimensional interaction of four jets in a supersonic wake, at small distances from the outlet cross section of the nozzle, i.e., mainly in the initial sections of the jets, where the mixing layers along the boundaries of the jets are still not closed. Here the method of [1] is used to study the special characteristics of three-dimensional viscous jets at large distances from the outlet cross section of the nozzle in the region of the main section, where the mixing layers have come together and a single three-dimensional jet has been formed. The system of equations, the boundary conditions, the numerical method, the system of coordinates, and the nomenclature used are the same as in [1].     

Synthesis and structure of the platinum complexes [Bu4N]+[PtBr5(DMSO)]?, [Ph4P]+[PtBr5(DMSO)]?, and [Ph3(n-Am)P]+[PtBr5(DMSO)]?

The complexes [Bu₄N]₂⁺[PtBr₆]²⁻ (I), [Ph₄P]₂⁺[PtBr₆]²⁻ (II), and [Ph₃(n-Am)P]₂⁺ (III) are synthesized by the reactions of tetrabutylammonium bromide, tetraphenylphosphonium bromide, and triphenyl(n-amyl)-tetraphenylphosphonium bromide, respectively, with potassium hexabromoplatinate (mole ratio 2: 1). After recrystallization from dimethyl sulfoxide, complexes I, II, and III transform into [Bu₄N]⁺[PtBr₅(DMSO)]⁻ (IV), [Ph₄P]⁺[PtBr₅(DMSO)]⁻ (V), and [Ph₃(n-Am)P]⁺[PtBr₅(DMSO)]⁻ (VI). According to the X-ray diffraction data, the cations of complexes IV–VI have a slightly distorted tetrahedral structure. The N-C and P-C bond lengths are 1.492(7)–1.533(6) and 1.782(10)–1.805(10) ?, respectively. The platinum atoms in the mononuclear anions are hexacoordinated. The dimethyl sulfoxide ligands are coordinated with the Pt atom through the sulfur atom (Pt-S 2.3280(18)–2.3389(11) ?). The Pt-Br bond lengths are 2.4330(6)–2.4724(6) ?.     

Photon echo in an atomic frequency comb in a Pr-doped LaF3 crystal

The possibility of storage of an optical pulse in a memory based on an atomic frequency comb in a Pr³⁺:LaF₃ crystal is demonstrated experimentally. A new method of storage-time control using an external electric field is proposed and experimentally implemented.