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101.
Z. J. Yu L. J. Liu R. X. Zhuo 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):13-21
The ring‐opening polymerization of ε‐caprolactone (ε‐CL), initiated by carboxylic acids such as benzoic acid and chlorinated acetic acids under microwave irradiation, was investigated; with this method, no metal catalyst was necessary. The product was characterized as poly(ε‐caprolactone) (PCL) by 1H NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet spectroscopy, and gel permeation chromatography. The polymerization was significantly improved under microwave irradiation. The weight‐average molecular weight (Mw) of PCL reached 44,800 g/mol, with a polydispersity index [weight‐average molecular weight/number‐average molecular weight (Mw/Mn)] of 1.6, when a mixture of ε‐CL and benzoic acid (25/1 molar ratio) was irradiated at 680 W for 240 min, whereas PCL with Mw = 12,100 and Mw/Mn = 4.2 was obtained from the same mixture by a conventional heating method at 210 °C for 240 min. A degradation of the resultant PCL was observed during microwave polymerization with chlorinated acetic acids as initiators, and this induced a decrease in Mw of PCL. However, the degradation was hindered by benzoic acid at low concentrations. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 13–21, 2003 相似文献
102.
The influence of hydrogen bonds on the physical and chemical properties of hydrogen bonding fluid system of A a D d type is investigated from two viewpoints by the principle of statistical mechanics. In detail, we proposed two new ways that can be used to obtain the equilibrium size distribution of the hydrogen bonding clusters, and derived the analytical expression of a relationship between the hydrogen bonding free energy and hydrogen bonding degree. For the nonlinear hydrogen bonding systems, it is shown that the sol-gel phase transition can take place under proper conditions, which is further proven to be a kind of geometrical phase transition rather than a thermodynamic one. Moreover, several problems associated with the geometrical phase transition and liquid-solid phase transition in nonlinear hydrogen bonding systems are discussed. 相似文献
103.
Summary Vezetéknév 相似文献
104.
X.X. Guo 《Surface science》2004,549(3):211-216
We studied parallel conductivities of pure BaF2 films with thicknesses ranging from 35 to 300 nm, epitaxially grown on Al2O3(0 1 2) substrates by molecular beam epitaxy technique. The overall conductivities of the films are found to increase with decreasing thickness. The detailed investigation of the overall conductance as a function of the thickness permits the deconvolution of bulk and boundary effects, the latter being attributed to distinct space charge effects in the interface between BaF2 film and Al2O3 substrate. The (extrinsic) Debye length (λ) is estimated to be about 8 nm at T=593 K, which corresponds to an impurity content of 1018/cm3 (singly ionized dopant assumed). This is consistent with the fact that we observed a constant boundary contribution for all investigated films (film thickness >4λ). It is also consistent with the Debye length observed in a previous report on CaF2/BaF2 heterolayers fabricated by the same technique, in which the low temperature enhancement was also attributed to space charges in BaF2 [Nature 408 (2000) 946]. Only at low temperatures (below 370 °C), the conductance seems to be influenced by strain effect. 相似文献
105.
The use of liquid fuels such as kerosene is of interest for the pulse detonation engine (PDE). Within this context, the aim
of this work, which is a preliminary study, was to show the feasibility to initiate a detonation in air with liquid-fuel pyrolysis
products, using energies and dimensions of test facility similars to those of PDEs. Therefore, two liquids fuels have been
compared, JP10, which is a synthesis fuel generally used in the field of missile applications, and decane, which is one of
the major components of standard kerosenes (F-34, Jet A1, ...). The thermal degradation of these fuels was studied with two
pyrolysis processes, a batch reactor and a flow reactor. The temperatures varied from 600°C to 1,000°C and residence times
for the batch reactor and the flow reactor were, respectively, between 10–30 s and 0.1–2 s. Subsequently, the detonability
of synthetic gaseous mixtures, which was a schematisation of the decomposition state after the pyrolysis process, has been
studied. The detonability study, regarding nitrogen dilution and equivalence ratio, was investigated in a 50 mm-diameter,
2.5 m-long detonation tube. These dimensions are compatible with applications in the aircraft industry and, more particularly,
in PDEs. Therefore, JP10 and decane were compared to choose the best candidate for liquid-fuel PDE studies.
This paper was based on work that was presented at the 20th International Colloquium on the Dynamics of Explosions and Reactive
Systems, Montreal, Canada, July 31 – August 5, 2005. 相似文献
106.
L. V. Giurgiu M. N. Grecu X. Filip O. Raita Al. Darabont D. Gavre J. Blasco 《Applied magnetic resonance》2003,24(3-4):351-360
We report an electron paramagnetic resonance (EPR) investigation of the spin dynamics in the paramagnetic regime of the colossal magnetoresistive manganites La2/3Ca1/3Mn1?x Me x O3 (Me=Al, In;x≤0.05). The temperature dependences of the EPR linewidth and integral intensity have been analyzed in terms of the bottleneck spin relaxation and small-polaron hopping models. The exchange coupling integral between Mn3+ and Mn4+ ions and the polaron activation energy decrease with increasing doping level. A discussion is given concerning the factors which could explain the observed changes. 相似文献
107.
A combined programming and iteration algorithm for finite element analysis of three-dimensional contact problems 总被引:3,自引:0,他引:3
Comparing with two-dimensional contact problems, three-dimensional frictional contact problems are more difficult to deal
with, because of the unknown slip direction of the tangential force and enormous computing time. In order to overcome these
difficulties, a combined PQP (Parametric Quadratic Programming) and iteration method is derived in this paper. The iteration
algorithm, which alleviates the difficulty of unknown slip direction, is used along with the PQP method to cut down computing
costs. Numerical example is given to demonstrate the validity of the present algorithm.
The project supported by the Machinary and Electronics Ministry of China 相似文献
108.
109.
110.
放射源的辐射指纹能起到标识和鉴别放射性物体的作用.在涉及核弹头不可逆销毁过程的深度核裁军核查中,核弹头的辐射指纹对标识和鉴别裁减下来的核弹头将起到关键作用.预先研究辐射指纹的有关技术,如识别机理的研究,将有助于深度核裁军的核弹头核查技术发展.以实验室放射源为研究对象,探索了类型γ射线能谱指纹的同一性识别机理.类型γ射线指纹识别机理的研究,就是要找出一种合适的方法,以较高的置信度,描述两个正在进行比较的γ射线指纹是否为同一放射源的指纹.采用了谱形比较法,并用谱相似度概念来描述两个指纹的相似程度.在谱形比较思想的指导下,编制了放射源类型指纹识别软件,并通过放射源同一性的识别实验验证了软件的有效性,同时研究了谱相似度随统计涨落和测量条件,如时间、源强和本底等因素的变化情况.研究结果表明:1)用相似度概念来描述两个指纹的相似程度,回答两个待比较的γ射线能谱是否代表同一类型放射源,是切实可行的;2)该识别机理只具备识别放射源类型的能力,而对同一类型、差异甚微的放射源个体还不能识别
关键词:
γ射线能谱指纹
辐射指纹
识别机理
核查技术 相似文献