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Shinobu Takizawa Tue Minh-Nhat Nguyen André Grossmann Michitaka Suzuki Dieter Enders Hiroaki Sasai 《Tetrahedron》2013,69(3):1202-1209
The acid–base organocatalyzed intramolecular Rauhut–Currier (RC) reaction of the dienone enolates has been developed. The enantioselective RC process produces the highly functionalized α-methylidene-γ-butyrolactones as a single diastereomer with up to 98% ee. 相似文献
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Gisela Ohms Gisbert Grossmann Eli Breuer 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4)
Abstract As known from 31P solid-state NMR investigations of inorganic phosphates there is a correlation between chemical shift anisotropy parameters and crystal lattice parameters. For phosphonic acids and phosphonates similar correlations are not known. 相似文献
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Hartmut Komber Gisbert Grossmann Axel Kretschmer 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):335-343
Abstract Compounds of the following structure (R1O)2(X)P[sbnd]Y–P(X)(OR2)2 (X = O, Y = Sn (n = 1–4), R1 = R2 = Me, iPr; X = S, Y = Sn (n = 1–4), R1, R2 = Me, Et, iPr, iBu; X = S, Y = S-Se-S, S-Te-S, R1 = R2 = Me were prepared and their NMR spectra were analysed. Depending on the number of sulfur atoms, bonded between the phosphorus atoms, typical ranges of the P-P coupling constants were found for the different sulfanes investigated: 2JPP from-10 to-20 Hz, 3JPP less than 3 Hz, 4JPP from +10 to +13 Hz and 5JPP less than 1 Hz. For the small vicinal coupling constants and the relatively large values of 4JPP different possibilities of their interpretation are given. 相似文献
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Jochen Spiegel Philipp M. Cromm Prof. Dr. Aymelt Itzen Prof. Dr. Roger S. Goody Dr. Tom N. Grossmann Prof. Dr. Herbert Waldmann 《Angewandte Chemie (International ed. in English)》2014,53(9):2498-2503
Small GTPases are molecular switches using GDP/GTP alternation to control numerous vital cellular processes. Although aberrant function and regulation of GTPases are implicated in various human diseases, direct targeting of this class of proteins has proven difficult, as GTPase signaling and regulation is mediated by extensive and shallow protein interfaces. Here we report the development of inhibitors of protein–protein interactions involving Rab proteins, a subfamily of GTPases, which are key regulators of vesicular transport. Hydrocarbon‐stapled peptides were designed based on crystal structures of Rab proteins bound to their interaction partners. These modified peptides exhibit significantly increased affinities and include a stapled peptide (StRIP3) that selectively binds to activated Rab8a and inhibits a Rab8a–effector interaction in vitro. 相似文献