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排序方式: 共有307条查询结果,搜索用时 78 毫秒
31.
Verónica R. Elías Mónica E. Crivello Eduardo R. Herrero Sandra G. Casuscelli Griselda A. Eimer 《Journal of Non》2009,355(22-23):1269-1273
Two methods for the preparation of highly ordered MCM-41 silica are discussed. The quality of the structure was optimized by adequate stirring of the reaction mixture containing low concentration of surfactant, followed by heating at 70 °C for 3 h under stirring. Besides this energetically favorable procedure allowed to obtain structures very stable upon calcination. The role of the ethanol and the hydroxide source in the synthesis process is also analyzed. 相似文献
32.
Pablo H. Pacheco Roberto Olsina Griselda Polla Luis D. Martinez Patricia Smichowski 《Microchemical Journal》2009,91(2):159-164
The adsorption behaviour of Cd onto the relative non-polar L-methionine was studied. To this end, L-met was immobilized on controlled pore glass (CPG), incorporated in a microcolumn and inserted in a flow injection system for Cd preconcentration from aqueous solutions. Binding constant of the system was calculated and it turned to be of 1.99, with sites capacity of n = 3.12. The ratio of Cd moles bound to L-met moles was calculated and it was 0.03:1 at pH 9.0. On-line breakthrough curves were used to study the effect of pH, analyte concentration and influent flow rate on Cd retention. A complementary pH study was added with a titration curve. Transient peak areas revealed that Cd stripping from the column occurred instantaneously. The system achieves an enrichment factor of 130, reaching a detection limit of 0.63 ng L− 1 when 10 mL of the solution were passed through the column. The method was successfully applied to Cd determination in the standard reference material (SRM), QC METAL LL2 metals in natural water, as a validation study. 相似文献
33.
Effectiveness of Photodynamic Therapy in Elimination of HPV‐16 and HPV‐18 Associated with CIN I in Mexican Women 下载免费PDF全文
Elizabeth Maldonado Alvarado Martha Olivia Osorio Peralta Alejandra Moreno Vázquez Lydia Alejandra Martínez Guzmán Maria Eugenia Melo Petrone Zulma Iveth Enriquez Mar Dora Estela Jovel Galdamez Bárbara Carrión Solana Guadalupe Balderas Martínez Eduarda Parra Rossana Inés Castellanos Oliveros Rosa Linda Bello Leiva Araceli Espinosa Montesinos Citlalli Barrera Mendoza Selma Eugenia Medina García Eva Ramón Gallegos 《Photochemistry and photobiology》2017,93(5):1269-1275
This study aimed to determine the effectiveness of photodynamic therapy (PDT), using δ‐aminolevulinic acid (5‐ALA), in the elimination of premalignant cervical lesions in Mexican patients with human papillomavirus (HPV) infection and/or cervical intraepithelial neoplasia (CIN). Thirty women diagnosed with CIN I and/or positive for HPV participated in the study. Topical 6% 5‐ALA in gel form was applied to the uterine cervix; after 4 h, the lesion area was irradiated with a light dose of 200 J cm?2 at 635 nm. This procedure was performed three times at 48‐h intervals. Clinical follow‐up was performed at 3, 6, and 12 months after the initial PDT administration, by colposcopy, cervical cytology, histopathological analysis, polymerase chain reaction, and hybrid capture. Of HPV‐infected patients without evidence of CIN I, 80% cleared the infection, while HPV associated with CIN I was eliminated in 83% of patients (P < 0.05). At 12 months, CIN I had regressed in 57% of patients, although this response was not statistically significant. PDT using 6% 5‐ALA is concluded to be effective in eliminating HPV infection associated or not with CIN I. 相似文献
34.
John Fredy Barrera Edgar Rueda Myrian Tebaldi Roberto Torroba 《Optics Communications》2011,284(19):4350-4355
We develop an experimental protocol to visualize decrypted images that otherwise would have been barely recognizable, while keeping the standard security levels. This image deterioration is partly due to the natural speckle noise as well as the practical limitations arising from the optical elements composing the setup. This protocol is based on an optical image synthesis with digital holography using enlarged sub-samples of an entire image together with a multiplexing technique. We implement the process using a Mach-Zehnder interferometer with a joint transform correlator encrypting architecture. As a result, we get smaller speckle patterns on the final assembled image and a spatial frequency enhancement with respect to the decoded image obtained with the conventional procedures. 相似文献
35.
Y. Borensztein L. Delannoy R. G. Barrera C. Louis 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2011,63(2):235-240
The changes in the optical properties of Au/TiO2 powder catalyst, prepared by
the deposition-precipitation method, are measured in the visible range by use of a
home-made diffuse differential reflectance spectrometer, when the ambient atmosphere is
switched between H2 and O2. Two main features are observed: (i) a
short wavelength one, located between 400 and 600 nm, is shown to be related to the
modifications of the plasmon resonance of the 3-dimensional metallic gold particles with
mean size around 4 nm, induced by the exposure to oxygen or by its removal; (ii) a second
feature, observed at long wavelengths between 600 and 1100 nm, is extremely sensitive to
the exposure to oxygen. This optical feature could be due to the presence in the catalyst,
either of Au0 clusters of several tens atoms, which are expected to display
molecular-like transitions in this optical range, or to specific sites of the Au particles
(edge atoms or peripheral atoms at the interface with the TiO2 support), which
could be highly reactive to oxygen. 相似文献
36.
为准确分析含多孔材料有源声学结构的声学性能,利用一种结合(u,p)方程和有限元技术的计算方法对有源声学结构建模,分析声波在多孔材料中传播规律,并进行了实验验证.基于固相位移和流相声压的(u,p)方程对多孔材料固、流两相间强烈耦合进行分析,建立了多孔材料的有限元模型,并对含有多孔材料双层板有源声学结构的声学性能进行了测量... 相似文献
37.
38.
Full dynamic free energy minimisation is used to study the stability of different polymorphs of MgCl2, with a new set of interionic potentials derived from ab initio calculations using density functional theory. The calculated difference in free energies between the - and β-phases is extremely small: the vibrational contribution reverses the relative ordering of these two structures obtained in the static limit. We predict the thermal expansion of both forms is highly anisotropic and that, unusually, above ≈60 K the expansion is larger parallel than perpendicular to the layers. 相似文献
39.
P. Bermejo Barrera J. F. Vazquez Gonzalez F. Bermejo Martinez 《Mikrochimica acta》1986,88(3-4):259-264
A new method for the direct determination of molybdenum by ETA-AAS in mineral waters without prior separation or concentration is proposed. With careful control of the graphite furnace conditions selective volatilization of the salt matrix is successfully attained. The possible spectroscopic interference due to common metals as well as the reproducibility, precision and repeatability of the method has been studied and the molybdenum content of 21 mineral waters measured. 相似文献
40.
Jana Beinhauer Liangqiao Bian Hui Fan Marek Šebela Maciej Kukula Jose A. Barrera Kevin A. Schug 《Analytica chimica acta》2015
Estrone (E1), estradiols (α/β-E2), and estriol (E3) are four major metabolically active estrogens exerting strong biological activities at very low circulating concentrations. This paper reports a sensitive and efficient method with automated, on-line clean-up and detection to determine trace estrogens in a small volume of serum samples using liquid chromatography–electrospray ionization–tandem mass spectrometry directly, without off-line liquid–liquid or solid-phase extraction pretreatments. Serum aliquots (charcoal stripped fetal bovine serum, 100 μL) were spiked with four estrogen standards and their corresponding isotope-labeled internal standards, then bulk derivatized with 2-fluoro-1-methyl-pyridium p-toluenesulfonate (2-FMP) to establish the calibration curves and perform method validation. Calibration was established in the concentration ranges of 5–1000 pg mL−1, and demonstrated good linearity of R2 from 0.9944 to 0.9997 for the four derivatized estrogens. The lower detection limits obtained were 3–7 pg mL−1. Good accuracy and precision in the range of 86–112% and 2.3–11.9%, respectively, were observed for the quality control (QC) samples at low, medium, and high concentration levels. The stability tests showed that the derivatized serum samples were stable 8 h after derivatization at room temperature and at least to 48 h if stored at −20 °C. The method was applied to measure trace estrogens in real human and bovine serum samples, and three of four estrogen compounds studied were observed and quantified. 相似文献