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41.
2,6- and 2,7-Dimethylanthracenes were reduced seriatim with lithium in liquid ammonia and lithium in methylamine to their 1,4,5,8,9,10-hexahydro derivatives. Two-fold epoxidation of these tetraenes provided the cis and trans diepoxides resulting from electrophilic attack at the inner double bonds. Trans diepoxide 1 has the very unusual characteristic of lacking a σ plane of symmetry but possessing an inversion center. As a consequence, the 1H NMR spectrum of C1-symmetric 1 is simplified relative to those of its isomers 5, 9, and 10. 相似文献
42.
Pure adaptive search in global optimization 总被引:10,自引:0,他引:10
Pure adaptive seach iteratively constructs a sequence of interior points uniformly distributed within the corresponding sequence of nested improving regions of the feasible space. That is, at any iteration, the next point in the sequence is uniformly distributed over the region of feasible space containing all points that are strictly superior in value to the previous points in the sequence. The complexity of this algorithm is measured by the expected number of iterations required to achieve a given accuracy of solution. We show that for global mathematical programs satisfying the Lipschitz condition, its complexity increases at mostlinearly in the dimension of the problem.This work was supported in part by NATO grant 0119/89. 相似文献
43.
MacLatchy C.S. Smith H.C.L. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1991,19(6):1254-1258
The electron current to a Langmuir probe in a moving high-pressure plasma has been measured and analyzed. The plasma is an atmospheric-pressure propane flame, and the probe's speed relative to the plasma was varied from 10 ms-1 to 30 ms-1. The current is linearly dependent on the speed and appears to be comprised of two components-one driven by diffusion and the other by convection. A model is devised which can be used to measure the electron density. By comparing the density computed from this model to that measured from the ion current, it has been possible to measure the electron mobility in the flame gases. The value obtained by the authors is in good agreement with theoretical calculations found in the literature 相似文献
44.
45.
The flow induced by a finite disc rotating near horizontal ground is considered, including the effects of an underbody. This paper concentrates on determining the shape of the free layer beyond the rim of the disc which is horizontal in the absence of the underbody and ground but forced to deform to ensure that conditions across the layer are satisfied when the underbody or ground is added. The far-field behaviour, the inviscid flow produced by a nominally infinite disc near the ground and the global solution for small ground clearances are considered analytically, and the full problem is posed as an integral problem. This is then solved numerically and analytically. Results are presented for various heights of the disc above the ground and for discs with an axisymmetric underbody present. A universal form is found for the farfield shape (which is controlled by entrainment into the free layer) but both the underbody and the ground effects are found to increase very significantly for reduced clearances. 相似文献
46.
O. Lutz R. Swinne J. C. Brünnich und F. Smith 《Fresenius' Journal of Analytical Chemistry》1913,52(3-4):226-227
Ohne Zusammenfassung 相似文献
47.
Elastic rod models provide a means to interpret single molecule DNA experiments as well as predict DNA behavior under physiological conditions. Here we use an elastic rod model to predict the stability boundary (critical torque vs. applied tension) for single molecule DNA experiments in which the molecule is subjected to applied tension and twist. We discuss the shortcomings of the usual isotropic rod model. We then derive a consistent non-linear material law from the general representation for a hemitropic (chiral) rod. Finally, we present results of a standard bifurcation analysis predicting the stability boundary. We find results from the non-linear hemitropic rod to match the data closely. 相似文献
48.
Let G be a compact Hausdorff group and n a positive integer. It is proved that all subnormal subgroups of G of index dividing n are open if and only if there are only finitely many such subgroups, and that all subgroups of finite index in G are open if and only if there are only countably many such subgroups. 相似文献
49.
Mark P. WattersonAlison A. Edwards John A. LeachMartin D. Smith Osamu IchiharaGeorge W.J. Fleet 《Tetrahedron letters》2003,44(31):5853-5857
Efficient syntheses of all diastereomers of methyl 2,5-anhydro-3-deoxy-hexonate from mannono- or gulono-lactones provide precursors for C-nucleosides of 2-deoxyribose and for THF-templated γ- and δ-amino acids. 相似文献
50.
Role of the microstructure on the transport properties of Y-doped zirconia and Gd-doped ceria 总被引:1,自引:1,他引:0
Transmission electron microscopy characterizations and XPS analyses have allowed us to show the influence of the microstructure
and nanochemistry on the transport properties of Y2O3-(9 mol%)-stabilized zirconia (YSZ) and Gd2O3 (10 mol%)-doped ceria (GDC). The grain boundary electrical conductivity (σgb) and oxygen diffusion coefficient (Do) of conventional YSZ ceramics increase with the grain size, while an opposite behavior was found for GDC samples. This difference
was attributed to glassy precipitates present at YSZ grain boundaries. Furthermore, it was shown that kinetic demixing processes
take place during cooling, at the end of sintering. This causes important changes in the cationic species distribution at
interfaces and plays an important role on the transport properties of these two materials.
Paper presented at the 9th EuroConference on Ionics, Ixia, Rhodes, Greece, Sept. 15 – 21, 2002. 相似文献