Synthesis and characterization of a microsphere‐based coating for textiles with potential as an in situ bioactive delivery system

Proteinaceous microspheres have a wide range of biomedical applications, including their use as drug delivery systems. On the other hand, bioactive and antimicrobial textiles are promising substrates for medical care, in particular, as wound‐dressings. This work relates the development of a new process for the functionalization of textiles through the simultaneous formation and linkage of protein‐based microspheres onto textile fibers by sonochemical techniques. The microspheres developed by this process possess antimicrobial properties by themselves, but other may be incorporated by the encapsulation of various pharmaceutical formulations. This new type of microspheres and particularly their fixation onto textile materials encourage the development of textiles that can be used as delivery systems in a simple, fast, and non‐toxic process. Here it is reported the production of microspheres with a combination of bovine serum albumin (BSA), L ‐Cysteine (L ‐Cys), and n‐dodecane, using the ultrasound technology. The size distribution and morphology of the microspheres was determined as a function of several parameters such as irradiation time and BSA and L ‐Cys concentrations. The produced microspheres were analyzed using a laser light scattering size analyzer, an optical microscope and a scanning electron microscope. The new coating of BSA + L ‐Cys microspheres revealed a high stability and excellent antibacterial properties being a promising alternative to design textile‐based bioactive delivery systems with potential application in the development of textile‐based wound‐dressings. Copyright © 2011 John Wiley & Sons, Ltd.     

A new semidefinite programming hierarchy for cycles in binary matroids and cuts in graphs

The theta bodies of a polynomial ideal are a series of semidefinite programming relaxations of the convex hull of the real variety of the ideal. In this paper we construct the theta bodies of the vanishing ideal of cycles in a binary matroid. Applied to cuts in graphs, this yields a new hierarchy of semidefinite programming relaxations of the cut polytope of the graph. If the binary matroid avoids certain minors we can characterize when the first theta body in the hierarchy equals the cycle polytope of the matroid. Specialized to cuts in graphs, this result solves a problem posed by Lovász.     

Transferral of entailment in duality theory: Dualisability

A number of new results that say how to transfer the entailment relation between two different finite generators of a quasi-variety of algebras is presented. As their consequence, a well-known result saying that dualisability of a quasi-variety is independent of the generating algebra is derived. The transferral of endodualisability is also considered and the results are illustrated by examples.     

Thermal and quality evaluation of vegetable oils used in ruminant feed

Dairies add fat supplements to the diets of small ruminants to increase energy production and consequently the production and quality nutritional and sensorial of the milk. This study investigated the thermal and oxidative stability of babassu, castor, faveleira, and sesame oils by TG/DTA and PDSC. The profile of the fatty oils studied was determined by GC–MS as well as physicochemical characteristics. The thermogravimetric profile of the oils indicated that mass loss was caused by the decomposition or volatility of the triacylglycerides. Faveleira and sesame oils showed a high percentage of polyunsaturated fatty acids, especially C18:2. From a nutritional standpoint, unsaturated oils are more suitable supplements for animals because they promote biochemical changes beneficial to human health.     

Restricted dynamic programming based neighborhoods for the hop-constrained minimum spanning tree problem

In this paper we develop, study and test new neighborhood structures for the Hop-constrained Minimum Spanning Tree Problem (HMSTP). These neighborhoods are defined by restricted versions of a new dynamic programming formulation for the problem and provide a systematic way of searching neighborhood structures based on node-level exchanges. We have also developed several local search methods that are based on the new neighborhoods. Computational experiments for a set of benchmark instances with up to 80 nodes show that the more elaborate methods produce in a quite fast way, heuristic solutions that are, for all cases, within 2% of the optimum.     

Preliminary analysis to BIIR recovery using the microwave process

This paper shows the results of preliminary assessment to devulcanize and recover the bromobutyl rubber (BIIR) using the microwave process. In this work, a heat generating system with high microwave frequency (2.45 GHz) was used. Samples of BIIR (about 0.250 kg) such as rubber caps production leftovers and materials that had not been approved in the quality tests were irradiated, at powers of 1000 W, 2000 W and 3000 W. Various heating times were used: 540 s (9  min) up to 1500 s (25 min). The standard test specimens of non-irradiated and irradiated samples were characterized by rheometric analysis, Shore A hardness measurement and ash test. The best operation conditions were obtained at 780 s and 2000 W. The results showed that the microwave process caused an expressive effect in the BIIR recovery. Some samples presented the tendency to vulcanize again, hence there is a great expectancy for reusing and recycling the devulcanized BIIR, without using any chemical agent in the microwave process.     

Velocity characteristics of the flow around a square cross section cylinder placed near a channel wall

Laser-Doppler measurements are reported of the flow around a square cross section cylinder placed at various heights (Y ₀) above a plane channel wall for a Reynolds number Re _H = 1.36 × 10⁴.The thickness of the turbulent boundary layer on the channel wall at the obstacle position, but with it removed from the water tunnel, was equal to 0.8 H, being H the square obstacle height and the free stream turbulence intensity was 6%. The periodic character of the flow in the near wake was characterized by measurements of turbulence spectra in the range 0 Y ₀/H 3.3 and the results revealed that regular vortex shedding was suppressed for a gap height less than 0.35 H. Detailed results of time averaged mean flow properties, turbulence intensities and Reynolds stresses revealed the structural differences of the near wakes with and without vortex shedding for Y _O = 0.5 and Y _O = 0.25 respectively.List of symbols R _e Reynolds number Re = U ₀ H/v - H Square obstacle height - Y Normal coordinate - Y ₀ Gap distance between the plane wall and obstacle face - C _f Skin friction coefficient - k Turbulent kinetic energy - u Friction velocity - Turbulent boundary layer thickness - y ⁺ Non-dimensional log law coordinate - X _r Separated flow length behind the obstacle - U Mean axial velocity - V Mean radial velocity - u² Axial turbulent stress - ² Normal turbulent stress - u Turbulent shear stress - U ₀ Mean bulk velocity - E Power spectrum energy - f Predominant frequency - h Distance between inner shear layers behind the obstacle - s Distance from the wall to the shear layer behind the obstacle - C _D Drag coefficient     

Controlled Production of Exopolysaccharides from Enterobacter A47 as a Function of Carbon Source with Demonstration of Their Film and Emulsifying Abilities

The bacterium Enterobacter A47 has demonstrated the ability to synthesise distinct exopolysaccharides (EPS) as a function of the substrate used. The culture's performance was evaluated in experiments using either glucose or xylose, as single carbon sources, and compared with the substrate (glycerol) used in previous studies. The highest EPS production (13.23 g L^?1) was obtained in the glucose fed assay, with a volumetric productivity of 3.38 g L^?1 day^?1. The use of xylose resulted in lower productivity (1.39 g L^?1 day^?1). The synthesised polymers have the same main sugar monomers (fucose, glucose, galactose and glucuronic acid), but their relative proportion varied with the substrate used. The acyl groups' content and composition were also affected by the substrate used. The polymers produced from glycerol (EPS-s) and glucose (EPS-g) had identical shear-thinning behaviour and good emulsion-stabilising capacity and their films had similar mechanical and water vapour properties. However, the emulsions stabilised with EPS-g were less stable and destabilised within short periods of time or when subjected to heat and freezing/thawing procedures. On the other hand, the polymer produced from xylose had little emulsion-stabilising capacity and lower apparent viscosity than EPS-s and EPS-g, but its films were considerably more elastic.