Orange photoluminescent N-doped graphene quantum dots as an effective co-sensitizer for dye-sensitized solar cells

Journal of Solid State Electrochemistry - In this research, nanocoral (NC) film of TiO2 was decorated with nitrogen-doped graphene quantum dots (NGQDs, average size of ∼ 9 nm)...     

Molecular dynamics simulation of potassium along the liquid-vapor coexistence curve

The applicability of pair potential functions to liquid alkali metals is questionable. On the one hand, some recent reports in the literature suggest the validity of two-parameter pair-wise additive Lennard-Jones (LJ) potentials for liquid alkali metals. On the other hand, there are some reports suggesting the inaccuracy of pair potential functions for liquid metals. In this work, we have performed extensive molecular dynamics simulations of vapor-liquid phase equilibria in potassium to check the validity of the proposed LJ potentials and to improve their accuracy by changing the LJ exponents and taking into account the temperaturedependencies of the potential parameters. We have calculated the orthobaric liquid and vapor densities of potassium using LJ (12–6), LJ (8.5–4) and LJ (5–4), effective pair potential energy functions. The results show that using an LJ (8.5–4) potential energy function with temperature-independent parameters, ε and σ, is inadequate to account for the vapor-liquid coexistence properties of potassium. Taking into account the temperature-dependencies of the LJ parameters, ε(T) and σ(T), we obtained the densities of coexisting liquid and vapor potassium in a much better agreement with experimental data. Changing the magnitude of repulsive and attractive contributions to the potential energy function shows that a two-parameter LJ (5–4) potential can well reproduce the densities of liquid and vapor potassium. The results show that LJ (5–4) potential with temperature-dependent parameters produces the densities of liquid and vapor potassium more accurately, compared to the results obtained using LJ (12–6) and LJ (8.5–4) potential energy functions.     

The effect of cation distribution on magnetization of ZnFe2O4 nanoparticles

In this work zinc ferrite (ZnFe₂O₄) nanoparticles have been prepared by sol-gel method in two different media, one acidic and another one basic and then annealed at different temperatures from 350 to 800 °C. XRD investigations show that both samples have a single phase spinel structure. Mean crystallite sizes of the samples were calculated, using Scherrer’s formula, which are 13 and 16 nm for the samples prepared in acidic and basic media, respectively. The variation of cation distribution in the samples was estimated by the ratio of (2 2 0) and (2 2 2) intensity diffraction peaks and the results show that as-prepared nanoparticles have different ionic distributions in comparison with that of bulk zinc ferrite. Also the results show that by increasing annealing temperature the ionic distribution of the zinc ferrite nanoparticles tends to that of bulk sample. The magnetic properties of the samples were studied by VSM and the results show that zinc ferrite nanoparticles have a ferrimagnetic behavior. Also the morphology of the powders was examined by TEM.     

Cyclic peptide conjugate of curcumin and doxorubicin as an anticancer agent

The hydrophobicity of curcumin creates hurdle towards its use in the anticancer therapy. Herein, we synthesized a curcumin-doxorubicin conjugated cyclic peptide scaffold to improve the solubility of curcumin and create a conjugate containing two anticancer agents. A solid-phase Fmoc/tBu solid phase methodology was used to synthesize a cell-penetrating nuclear targeting peptide with free thiol and amine groups, which was coupled with the activated doxorubicin (Dox) and curcumin, affording Dox-peptide-curcumin conjugate (DPCC) (10). The antiproliferative activity of the conjugate was evaluated in human leukemia carcinoma cell (CCRF-CEM), human ovarian carcinoma cell (SKOV-3), and normal kidney cell line (LLCPK). Cyclic peptide-doxorubicin conjugate (7) and DPCC (10) did not inhibit the proliferation of normal kidney LLCPK cells after 72?h incubation, but were cytotoxic in CCRF-CEM (73% and 41%, respectively) and SKOV-3 (55% and 30%, respectively) cells while Dox was cytotoxic (60–79%) in all three cell lines under similar conditions, suggesting selectivity of these compounds towards cancer cells.     

Fabrication of ultra-fast humidity ZITO nanoporous sensor by sol–gel technique for dynamic situation and human breath

Measuring humidity in dynamic situation needs very high sensitive and fast response sensors. For this purpose, a new high sensitive humidity sensor based on ZnO/ITO (ZITO) composite nanostructure were designed on alumina substrate by sol–gel technique. Step by step monitoring of fabricated substrate after annealing at 400?°C was performed using scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and UV–Vis techniques. An oscilloscope and digital ohmmeter were applied to determine time-varying voltage and resistance signal of the fabricated sensors, respectively, while exposed to various humidity level. Sensitivity, response, recovery time, deposited layers thicknesses, composition ratio of ZnO:ITO and annealing temperature parameters were considered to achieve optimum conditions. The optimum conditions for maximum sensitivity were obtained as 1:1(ITO:ZnO) ratio, 400?°C annealing temperature, and three times layer by layer coating. Fabricated sensor has excellent response and recovery time (1.0 and 9?s) and long life time at room temperature (25?±?1?°C) for monitoring human breath and dynamic situation.

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Competitive immunoassay for Ochratoxin a based on FRET from quantum dot-labeled antibody to rhodamine-coated magnetic silica nanoparticles

We report on a highly sensitive competitive immunoassay for the mycotoxin Ochratoxin (OTA) using magnetic silica nanoparticles (NPs) fluorescently labeled with rhodamine 123 (Rho123) as signal intensifier. The method is based on the measurement of fluorescence resonance energy transfer (FRET) that occurs from CdTe quantum dots covered with anti-OTA antibody to the dye Rho123 on the surface of the NPs. The immunoreaction between anti-OTA antibody and OTA brings the fluorophore (acting as the acceptor) in close proximity of the QDs (acting as the donor), and this causes FRET to occur upon photo-excitation of the QDs. The size and polydispersity of the silica coated magnetic NPs was studied via TEM. The method has a detection limit of 0.8 pg of OTA per mL. It was applied to the determination of OTA in spiked human serum. A linear relationship is found between the increase in the fluorescence intensity of Rho 123 at 580 nm and the concentration of OTA in spiked samples over the 8 to 48 pg?mL^?1 concentration range. This highly sensitive homogeneous competitive detection scheme is simple, rapid and efficient. It does not require multiple separation steps and excessive washing.

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Graphical abstract Following photoexcitation of immobilized quantum dots (QDs), FRET occurs between the QDs and Rhodamine 123. The close proximity of Rho 123 and the magnetic silica core/shell particles leads to strongly intensified emission to result in an assay for Ochratoxin A that has a detection limit as low as 0.8 pg?mL^-1

     

Solid‐phase microextraction of ultra‐trace amounts of tramadol from human urine by using a carbon nanotube/flower‐shaped zinc oxide hollow fiber

A new method is successfully developed for the separation and determination of a very low amount of tramadol in urine using functionalized multiwalled carbon nanotubes/flower‐shaped zinc oxide before solid‐phase microextraction combined with gas chromatography. Under ultrasonic agitation, a sol of multiwalled carbon nanotubes and flower‐shaped zinc oxide were forced into and trapped within the pore structure of the polypropylene and the sol solution immobilized into the hollow fiber. Flower‐shaped zinc oxide was synthesized and characterized by Fourier transform infrared spectroscopy. The morphology of the fabricated solid‐phase microextraction surface was investigated by scanning electron microscopy and X‐ray diffraction. The parameters affecting the extraction efficiencies were investigated and optimized. Under the optimized conditions, the method shows linearity in a wide range of 0.12–7680 ng/mL, and a low detection limit (S/N = 3) of 0.03 ng/mL. The precision of the method was determined and a relative standard deviation of 3.87% was obtained. This method was successfully applied for the separation and determination of tramadol in urine samples. The relative recovery percentage obtained for the spiked urine sample at 1000 ng/mL was 94.2%.     

Centralized resource allocation for enhanced Russell models

This paper proposes a centralized resource allocation (CRA) model for the enhanced Russell model. All the DMUs can be easily projected onto the efficient frontier by solving only one model. This projection can be made by transforming the proposed model to a linear programming problem. In this paper, instead of non-radially increasing or decreasing the inputs or outputs individually, we increase or decrease non-radially all of the inputs and outputs at the same time. By solving a single model, we can provide targets for all DMUs. By the proposed approximation, different targets can be found for all DMUs, as compared to those obtained by the previous approximations. The proposed model can be developed to CRA models. Finally, an applied example emphasizes the importance of the proposed model.     

Analytical treatment on magnetohydrodynamic (MHD) flow and heat transfer due to a stretching hollow cylinder

This paper studied on magnetohydrodynamics flow and heat transfer outside a stretching cylinder. Momentum and energy equations are reduced using similarity transformation and converted into a system of ordinary differential equations which are solved analytically by the homotopy analysis method. The effects of the parameters involved, namely the magnetic parameter (M), Prandtl number (Pr) and Reynolds number (Re) on the velocity and temperature fields are investigated. The obtained results are valid for the whole solutions' domain with high accuracy. These methods can be easily extended to other linear and nonlinear equations and so can be found widely applicable in engineering and sciences. Copyright © 2009 John Wiley & Sons, Ltd.     

Finding DEA-efficient hyperplanes using MOLP efficient faces

This paper suggests a method for finding efficient hyperplanes with variable returns to scale the technology in data envelopment analysis (DEA) by using the multiple objective linear programming (MOLP) structure. By presenting an MOLP problem for finding the gradient of efficient hyperplanes, We characterize the efficient faces. Thus, without finding the extreme efficient points of the MOLP problem and only by identifying the efficient faces of the MOLP problem, we characterize the efficient hyperplanes which make up the DEA efficient frontier. Finally, we provide an algorithm for finding the efficient supporting hyperplanes and efficient defining hyperplanes, which uses only one linear programming problem.