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51.
52.
Marsiske H Antreasyan D Bartels HW Besset D Bieler C Bienlein JK Bizzeti A Bloom ED Brock I Brockmüller K Cabenda R Cartacci A Cavalli-Sforza M Clare R Compagnucci A Conforto G Cooper S Cowan R Coyne D Engler A Fairfield K Folger G Fridman A Gaiser D Gelphman D Glaser G Godfrey G Graaf K Heimlich FH Heinsius FH Hofstadter R Irion J Jakubowski Z Janssen H Karch K Keh S Kiel T Kilian H Kirkbride I Kloiber T Kobel M Koch W König AC Königsmann K Kraemer RW Krüger S Landi G Lee R Leffler S 《Physical review D: Particles and fields》1990,41(11):3324-3335
53.
54.
ÜMMÜHAN OCAK HALIT KANTEKIN YAŞAR GÖK H. BASIR ŞENTÜRK 《Journal of inclusion phenomena and macrocyclic chemistry》2006,55(1-2):87-91
The selective liquid–liquid extraction of various transition metal cations from the aqueous phase to the organic phase was carried out using a 14-membered N2O2S2-macrobicycle. Metal picrates such as Pb2+, Co2+, Zn2+, Ni2+,Cu2+ and Cd2+ were used in this extraction studies. It was found that the ligand showed moderate selectivity towards Pb2+ only among the other metals. The extraction constant (log K
ex) was determined to be 13.8 for Pb2+ complex. 相似文献
55.
Hynes J Doubleday WW Dyckman AJ Godfrey JD Grosso JA Kiau S Leftheris K 《The Journal of organic chemistry》2004,69(4):1368-1371
A survey of several electrophilic ammonia reagents for the N-amination of indole- and pyrrole-containing heterocycles revealed that monochloramine (NH(2)Cl) is an excellent reagent for this transformation. Pyrroles and indoles containing a variety of substitution were aminated on nitrogen with isolated yields ranging from 45% to 97%. 相似文献
56.
Nicholas A. Barnes Stephen M. Godfrey Ruth T.A. Halton Imrana Mushtaq Simon Parsons Robin G. Pritchard Mark Sadler 《Polyhedron》2007
Structural and spectroscopic data on the series of compounds “PhSeX”, where X = Cl, CN or SCN, are reported and compared with previously reported data on “PhSeX” systems (X = Br and I). The chloro-compound displays a “square” motif, Ph4Se4Cl4, in the solid state, linked by long Se–Se bonds [2.993(3)–3.035(3) Å], and forms a loosely held network of Se4 and Cl4 squares in its extended structure. In contrast, the pseudohalogen derivatives, PhSeCN and PhSeSCN, consist of essentially monomeric units, which form chains held together by weak Se?N interactions in the solid state. These Se?N interactions are much shorter in PhSeCN, 3.023(3)–3.065(4) Å, than in PhSeSCN, 3.348(4) Å. Weaker Se?N contacts are also present between the chains. The structure of PhSeSCN described here is the first reported crystallographic study of a selenium thiocyanate compound. Spectroscopic studies suggest that all three compounds exist as monomers in solution. The results reported herein illustrate the subtle differences in the solid-state structures of PhSeX compounds. 相似文献
57.
58.
Graphene nanoribbons (GNR) in mutually perpendicular electric and magnetic fields are shown to exhibit dramatic changes in their band structure and electron transport properties. A strong electric field across the ribbon induces multiple chiral Dirac points, closing the semiconducting gap in armchair GNRs. A perpendicular magnetic field induces partially formed Landau levels as well as dispersive surface-bound states. Each of the applied fields on its own preserves the even symmetry Ek=E−k of the subband dispersion. When applied together, they reverse the dispersion parity to be odd and gives Ee,k=−Eh,−k and mix the electron and hole subbands within the energy range corresponding to the change in potential across the ribbon. This leads to oscillations of the ballistic conductance within this energy range. 相似文献
59.
Jürgen Brüning Edith Alig Martin U. Schmidt 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(7):o341-o344
Ezetimibe {systematic name: (3R,4S)‐1‐(4‐fluorophenyl)‐3‐[(3S)‐3‐(4‐fluorophenyl)‐3‐hydroxypropyl]‐4‐(4‐hydroxyphenyl)azetidin‐2‐one}, C24H21F2NO3, is used to lower cholesterol levels by inhibiting cholesterol resorption in the human intestine. The crystal structure of ezetimibe anhydrate was solved from laboratory powder diffraction data by means of real‐space methods using the program DASH [David et al. (2006). J. Appl. Cryst. 39 , 910–915]. Subsequent Rietveld refinement with TOPAS Academic [Coelho (2007). TOPAS Academic User Manual. Version 4.1. Coelho Software, Brisbane, Australia] led to a final Rwp value of 8.19% at 1.75 Å resolution. The compound crystallizes in the space group P212121 with one molecule in the asymmetric unit. The molecules are closely packed and two intermolecular hydrogen bonds form an extended hydrogen‐bond architecture. 相似文献
60.
Georgekutty Joseph A. Santhosh Kumar R. Rajesh Godfrey Louis 《Indian Journal of Physics》2010,84(9):1223-1228
DC electrical conductivity studies were carried out along the three crystallographic axes for tripotassium sodium dichromate
(K3Na(CrO4)2 or KNCr). Earlier studies of phase transition in this crystal show successive phase transitions at 239 K and 853 K. In this
paper we report the dc electrical conductivity measurements in the temperature region 303–430 K along the crystallographic
axes. An anomaly in conductivity was obtained around 326 K along both the axes. This may be attributed as due to a newly observed
phase transition in the crystal. DSC taken for the sample also shows exothermic peak supporting the occurrence of newly observed
phase transition. 相似文献