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51.
Gianfranco Denti Scolastica Serroni Giovanni Sindona Nicola Uccella 《Journal of the American Society for Mass Spectrometry》1993,4(4):306-311
Fast-atom bombardment (FAB) mass spectrometry in the negative ionization mode enables the sputtering into the gas phase of the ruthenium complexes [Ru(2,2′-bipyridine[bpy])2(2,5-bis) (pyrydil)pyrazine[dpp])](PF6)2; [Ru(bpy)2,(2,3dpp)](PF6)2;[Ru(bpy)2,(2,3-dpp-Me)]( PF6)3; and [Ru(bpy)2(?-2,3-dpp)]2 RuCl2(PF6)4 as intact radical anions. These data, combined with those avaiiable from the positive FAB spectra allow a full characterization of the analytes. 相似文献
52.
Antonia Sacchi Paolo De Caprariis Luciano Mayol Giovanni De Martino 《Journal of heterocyclic chemistry》1995,32(3):1067-1069
4-Hydroxy-3-phenylprolines were synthesized via 1-acetyl-2,2-diethoxycarbonyl-2,3-dihydro-3-phenyl-1H-pyrrole. Reversed phase hplc resulted in the isolation of the products which were characterized by 1H and 13C nmr spectroscopy. 相似文献
53.
Giovanni Monegato 《Numerical Algorithms》1996,11(1):271-283
We consider the numerical solution of second kind integral equations of the form $$u(y) - \int\limits_0^1 {k(y/x)\frac{{u(x)}}{x}dx = f(y), 0 \le y \le 1,} $$ for some given kernelk(t). These equations, usually indicated as of Mellin type, arise in a variety of applications. In particular, we examine a Nyström interpolant based on the following product quadrature rule: $$\int\limits_0^1 {k(y/x)\frac{{u(x)}}{x}dx \approx \sum\limits_{i = 0}^n {w_{ni} (y)u(x_{mi} ).} } $$ This rule is obtained by interpolatingu(x) by the Lagrange polynomial associated with the set of Gauss-Radau nodes {x ni}. Under certain assumptions on the kernelk(t), we are able to prove the stability of our interpolant and derive convergence estimates. 相似文献
54.
A (k,k)-current T on an open subset of CN is plurisubharmonic if is positive. Positive plurisubharmonic currents admit Lelong numbers; we prove here that they are independent on the coordinates system. Moreover, if Y is an analytic subset of pure dimension, then the Lelong numbers of T on Y are given by a non negative weakly plurisubharmonic function. 相似文献
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58.
Giovanni Gaiffi 《manuscripta mathematica》1996,91(1):83-94
Let
be the complexified Coxeter arrangement of hyperplanes of typeA
n−1. In this paper we construct anS
n+1 extension of the naturalS
n action on the complex cohomology ring of the complement ofA
n−1. Recurrence formulas connecting characters with respect to theS
n and theS
n+1 action are given. 相似文献
59.
Di-2-pyridylketone semicarbazone as ligand in metal complexes: synthesis and X-ray crystal structure
Luigi P. Battaglia Pier Giovanni Berzolla Anna Bonamartini Corradi Corrado Pelizzi 《Journal of chemical crystallography》1993,23(12):973-979
A series of complexes of di-2-pyridylketone semicarbazone (Hdips) and Mn(II), Co(II), Co(III), Ni(II) and Cu(II) nitrates were synthesized and characterized by means of IR spectroscopy and for cobalt and nickel by X-ray crystal structures. The results are in agreement with the formulae: Mn(Hdips)2(NO3)2·2H2O, [Co(Hdips)2](NO3)2·H2O (I), [Ni(Hdips)2](NO3)2·H2O (II), Cu(Hdips)(NO3)2·2H2O, [Co(dips)2](NO3)·2H2O (III). The structure of I and II are monoclinic, space groupP21/c, with, I,a=15.980(4),b=11.531(2),c=16.170(2)Å;=104.20(2)°,Z=4,R=0.032; II,a=16.109(5),b=11.480(3),c=16.135(6)Å;=104.15(2)°,Z=4,R=0.069. Compound III is also monoclinic, space groupP21/c witha=12.173(5),b=15.619(5),c=15.338(8)Å;=111.40(4)°,Z=4,R=0.059. In these complexes the ligand is tridentate via carbonylic oxygen, semicarbazone and pyridine nitrogens forming each two five membered chelate rings with the metal in a distorted octahedral geometry. 相似文献
60.
Armentano D De Munno G Mastropietro TF Julve M Lloret F 《Journal of the American Chemical Society》2005,127(31):10778-10779
Intermolecular proton transfer in solid phase from the hydroxo bridge to a water molecule occurs in a new mu-hydroxo iron(III) compound of formula {EtNH3[Fe2(ox)2Cl2(mu-OH)].2H2O}n leading to a still crystalline compound in which the mu-oxo bridge replaces the mu-hydroxo one. Both three-dimensional compounds exhibit magnetic ordering at Tc ca. 70 K due to a spin canting. 相似文献