全文获取类型
收费全文 | 529篇 |
免费 | 5篇 |
国内免费 | 6篇 |
专业分类
化学 | 286篇 |
晶体学 | 11篇 |
力学 | 5篇 |
数学 | 48篇 |
物理学 | 190篇 |
出版年
2021年 | 3篇 |
2019年 | 3篇 |
2018年 | 9篇 |
2017年 | 3篇 |
2015年 | 4篇 |
2014年 | 10篇 |
2013年 | 15篇 |
2012年 | 14篇 |
2011年 | 27篇 |
2010年 | 17篇 |
2009年 | 35篇 |
2008年 | 18篇 |
2007年 | 25篇 |
2006年 | 20篇 |
2005年 | 23篇 |
2004年 | 14篇 |
2003年 | 8篇 |
2002年 | 11篇 |
2001年 | 14篇 |
2000年 | 10篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1993年 | 14篇 |
1992年 | 10篇 |
1991年 | 14篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1988年 | 7篇 |
1987年 | 12篇 |
1986年 | 3篇 |
1985年 | 10篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 10篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 10篇 |
1977年 | 3篇 |
1976年 | 8篇 |
1975年 | 7篇 |
1973年 | 6篇 |
1969年 | 3篇 |
1917年 | 2篇 |
1895年 | 2篇 |
1880年 | 4篇 |
排序方式: 共有540条查询结果,搜索用时 0 毫秒
61.
62.
63.
In this work we present a deperturbation study of the d?(3)Π(g), v=6 state of C(2) by double-resonant four-wave mixing spectroscopy. Accurate line positions of perturbed transitions are unambiguously assigned by intermediate level labeling. In addition, extra lines are accessible by taking advantage of the sensitivity and high dynamic range of the technique. These weak spectral features originate from nearby-lying dark states that gain transition strength through the perturbation process. The deperturbation analysis of the complex spectral region in the (6,5) and (6,4) bands of the Swan system (d(3)Π(g)-a?(3)Π(u)) unveils the presence of the energetically lowest high-spin state of C(2) in the vicinity of the d?(3)Π(g), v=6 state. The term energy curves of the three spin components of the d state cross the five terms of the 1?(5)Π(g) state at rotational quantum numbers N ≤ 11. The spectral complexity for transitions to the v = 6 level of d?(3)Π(g) state is further enhanced by an additional perturbation at N = 19 and 21 owing to the b?(3)Σ(g)(-), v=19 state. The spectroscopic characterization of both dark states is accessible by the measurement of 122 "window" levels. A global fit of the positions to a conventional Hamiltonian for a linear diatomic molecule yields accurate molecular constants for the quintet and triplet perturber states for the first time. In addition, parameters for the spin-orbit and L-uncoupling interaction between the electronic levels are determined. The detailed deperturbation study unravels major issues of the so-called high-pressure bands of C(2). The anomalous nonthermal emission initially observed by Fowler in 1910 [Mon. Not. R. Astron. Soc. 70, 484 (1910)] and later observed in numerous experimental environments are rationalized by taking into account "gateway" states, i.e., rotational levels of the d?(3)Π(g), v=6 state that exhibit significant (5)Π(g) character through which all population flows from one electronic state to the other. 相似文献
64.
Shmilovits-Ofir M Miller Y Gerber RB 《Physical chemistry chemical physics : PCCP》2011,13(19):8715-8722
Vibrational energy flow and conformational transitions following excitation of the OH stretching mode of the most stable conformer of glycine are studied by classical trajectories. "On the fly" simulations with the PM3 semiempirical electronic structure method for the potential surface are used. Initial conditions are selected to correspond to the ν=1 excitation of the OH stretch. The main findings are: (1) An an equilibrium-like ratio is established between the populations of the 3 lowest-lying conformers after about 10 picoseconds. (2) There is a high probability throughout the 150 ps of the simulations for finding the molecule in geometries far from the equilibrium structures of the lowest-energy conformers. (3) Energy from the initial excited OH (ν=1) stretch flows preferentially to 5 other vibrational modes, including the bending motion of the H atom. (4) RRK theory yields conformational transition rates that deviate substantially from the classical trajectory results. Possible implication of these results for vibrational energy flow and conformational transitions in small biological molecules are discussed. 相似文献
65.
G. E. Milkereit S. S. H. Gerber Karin Jankowski A. Terjung R. R. Schmidt V. Vill 《Journal of Thermal Analysis and Calorimetry》2005,82(2):471-475
Summary A set of Y-shaped and Siamese-twin shaped carbohydrate based glycolipids was investigated using polarising microscopy. The
structure was changed from the normal type (1 head, two chains) to complex inverted structures (2 heads outside 1 to 3 chains
in the middle part). The carbohydrate headgroup was changed from mono- to disaccharide; also the alkyl chain length was varied
systematically. The compounds displayed different thermotropic mesophases (Smectic A phases, columnar phases and cubic phases)
depending on the type of carbohydrate headgroup and the alkyl chain length. 相似文献
66.
M. Knopp K. -H. Speidel F. Hagelberg H. -J. Simonis P. N. Tandon J. Gerber 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1987,4(4):329-334
Attenuated γ-angular correlations and atomic spin precessions were measured for single-electron fluorine ions recoiling through vacuum in weak transverse magnetic fields The Coulomb excited long-lived19F(5/2+) state at 197 keV was used as probe. The angular correlations observed in the focal coordinate system of the Coulomb excitation process as well as the spin precessions in weak external fields are well explained with simple electron configurations associated with the highly stripped ions. 相似文献
67.
A unique method of coupling computational fluid dynamics (CFD) to model predictive control (MPC) for controlling melt temperature in plastic injection molding is presented. The methodology is based on using CFD to generate, via open-loop testing, a temperature and input dependent system model for multi-variable control of a three-heater barrel on an injection molding machine. Results clearly show the benefit of temperature and input dependent system models for MPC control, and that CFD can be used to dramatically reduce the time associated with open-loop testing through physical experiments. 相似文献
68.
W. Pfeiffer F. Sattler S. Vogler G. Gerber J.-Y. Grand R. Möller 《Applied physics. B, Lasers and optics》1997,64(2):265-268
Direct illumination of the tunneling gap in an ultrahigh vacuum scanning tunneling microscope with ultrashort pump-probe laser
pulses may offer ultimate spatial and temporal resolution in surface experiments. The electronic bandwidth of the tunneling
gap ( 1 THz) does not limit the time resolution. Our experiments show that multiphoton photoelectron emission from the sample limits
the application of this detection scheme at high laser fluence. However, a substrate specific pump-probe effect in the photoelectron
yield with femtosecond transients is observed on Tantalum and on GaAs(110) surfaces.
Received: 5 November 1996 相似文献
69.
T. Pfeifer D. Walter C. Winterfeldt C. Spielmann G. Gerber 《Applied physics. B, Lasers and optics》2005,80(3):277-280
We demonstrate the generation of arbitrarily shaped spectra of coherent soft X-ray radiation by adaptive control of the driving laser pulse. The selection of both narrow and wide spectral ranges as well as suppression of high-harmonic emission in a selected wavelength region is achieved. Feedback-controlled spectral engineering of coherent soft X-rays paves the way to shaping of soft X-ray pulses and coherent control of electron dynamics in the sub-femtosecond regime. 相似文献
70.
K. -H. Speidel L. Kleinen A. Gohla R. Ernst H. Busch G. Jakob U. Grabowy V. Roth J. Gerber 《Zeitschrift für Physik A Hadrons and Nuclei》1997,358(4):389-393
Measurements of transient magnetic fields (TF) were performed for the first time in the amorphous compounds of Fe80B20 and Fe85B15 for 24Mg(2+), 28Si(2+), 48Ti(2+) and 56Fe(2+) probe ions employing light and heavy ion beams. The motivation for these experiments was to investigate whether ion beam induced attenuations of TF are substantially weaker in these materials than in crystalline Fe. This expectation was indeed satisfied. The attenuations observed were found to be smaller at least by a factor of 2. 相似文献