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521.
522.
Georgios A. Heropoulos Giancarlo Cravotto Barry R. Steele 《Tetrahedron letters》2007,48(18):3247-3250
Ultrasound and microwave assisted bromination reactions of various alkylaryls with N-bromosuccinimide, either neat or in water, shows diverse chemoselectivity. Thus, ring substitution occurs in water with ultrasound, whereas with microwaves both side-chain α-bromination and ring substitution occur. With neat reactants, side-chain α-bromination predominates for microwave assisted reactions. In the presence of water the chemoselectivity with microwave-promoted bromination is similar to that observed using classical methods. 相似文献
523.
The cosmological equations suggested by the non-relativistic renormalizable gravitational theory proposed by Hořava are considered. It is pointed out that the early universe cosmology has features that may give an alternative to inflation and the theory may be able to escape singularities. 相似文献
524.
Panagiotis Haskis Nikolaos Mantzos Dimitra Hela Georgios Patakioutas 《International journal of environmental analytical chemistry》2019,99(4):310-327
Biochars obtained by biomass pyrolysis have been proposed as a soil amendment to improve soil properties and fertility as well as to retain pesticides and other environmental contaminants. The present study investigates the degradation of metribuzin herbicide and its metabolites deamino- (DA), deaminodiketo- (DADK) and diketo- (DK) metribuzin under simulated solar light and dark conditions as well as their mobility using TLC plates coated with soil and soil?biochar mixtures at 1% and 5% w/w ratio. Biochar was characterised by X-Ray diffraction, porosimetry, scanning electron microscopy and Fourier transform infrared spectroscopy. Degradation under light conditions followed biphasic kinetics, with bi-exponential model fitted better for the soil substrate, while the Gustafson–Holden model was found more appropriate to describe degradation kinetics in 1% soil/biochar mixture. In soil, DA presented the lowest degradation rate (DT50:440.9 h), followed by metribuzin (DT50:208.0 h), DADK (DT50:110.8 h) and DK (DT50:106.5 h). The addition of biochar reduced drastically the degradation or even inhibited the photolytic process for the studied reaction period. The mobility retention factor (Rf) in soil ranged from 0.49 for metribuzin to 0.63 for DADK. The addition of biochar practically immobilises the compounds in the surface layer as Rf ranged from 0.14 to 0.10 for metribuzin and from 0.23 to 0.16 for DADK in soil/biochar mixtures 1% and 5%, respectively. In conclusion, the addition of biochar reduced dramatically the photodegradation rates as well as the mobility of metribuzin and its metabolites due to increased adsorption. 相似文献
525.
The combined effects of weak compressibility and viscoelasticity in steady, isothermal, laminar axisymmetric Poiseuille flow are investigated. Viscoelasticity is taken into account by employing the Oldroyd-B constitutive model. The fluid is assumed to be weakly compressible with a density that varies linearly with pressure. The flow problem is solved using a regular perturbation scheme in terms of the dimensionless isothermal compressibility parameter. The sequence of partial differential equations resulting from the perturbation procedure is solved analytically up to second order. The two-dimensional solution reveals the effects of compressibility and the other dimensionless numbers and parameters in the flow. Expressions for the average pressure drop, the volumetric flow rate, the total axial stress, as well as for the skin friction factor are also derived and discussed. The validity of other techniques used to obtain approximate solutions of weakly compressible flows is also discussed in conjunction with the present results. 相似文献
526.
In the simulation of shell problems in which plastic stresses in thickness direction are developed, the necessity of a more accurate integration through thickness using more integration points e.g. Gauss points becomes obvious, often increasing respectively the computational time and effort. A new algorithm is proposed for the automatic adaptation of the integration formula in thickness direction during the computation. Simple engineering criteria are found to define the time-point and the regions to increase the number of integration points. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
527.
We study the behavior of the Yang-Mills flow for unitary connections on compact and non-compact oriented surfaces with varying
metrics. The flow can be used to define a one dimensional foliation on the space of representations of a once punctured surface. This foliation universalizes over Teichmüller space and is equivariant with
respect to the action of the mapping class group. It is shown how to extend the foliation as a singular foliation over the
augmented boundary of Teichmüller space obtained by adding nodal Riemann surfaces. Continuity of this extension is the main
result of the paper.
Received May 18, 1998 / Revised August 30, 1999 / Published online July 20, 2000 相似文献
528.
Andreas Kaidatzis Vassilis Psycharis Georgios Giannopoulos José Miguel García‐Martín Dimitrios Niarchos 《固体物理学:研究快报》2017,11(2)
Ultrathin FePt films (thickness between 1 nm and 5 nm) were studied for non‐volatile memories applications. The films were magnetron sputtered on monocrystalline MgO?001? substrates at 500 °C. The films are polycrystalline, except the 1 nm thick film which is not continuous. It is shown that films with thickness higher than 2.7 nm have L10 structure and perpendicular magnetic anisotropy, while a transition to in‐plane anisotropy occurs for thinner films. The out‐of‐plane coercivity drops from 16 kOe at the thicker film to 0.5 kOe at the thinner one.
529.
Vassilikogiannakis G Margaros I Montagnon T Stratakis M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(20):5899-5907
Biomimetic syntheses of the litseaverticillols A-G, I and J are reported herein. The syntheses rely heavily on the application of two different modes of reaction for photochemically generated singlet oxygen, namely, the [4+2] cycloaddition of singlet oxygen (1O2) with furans and the ene reaction of 1O2 with double bonds. The highlight of these syntheses is a one-pot cascade sequence, involving five synthetic operations initiated by a [4+2] reaction, to form the fully functionalised litseaverticillol core. A series of regioselective ene reactions are then used to appositely functionalise the side chains. The synthesis of litseaverticillol E (both its originally proposed and its actual structures) allows a structural reassignment of this natural product. 相似文献
530.
The present work reports a new, simple and rapid reversed flow-injection (r-FI) method for the accurate and precise spectrophotometric determination of captopril (CPL) in pharmaceutical formulations. The method is based on the inhibitory effect of CPL on the complex formation of Co(II) with 2,2'-dipyridyl-2-pyridylhydrazone (DPPH). The chemical and FI variables were studied and optimized. The calibration graph was linear in the range 0-250 mg l(-1) CPL, at a sampling rate of 60 injections per hour. The method was found to be very precise [s(r)=0.8% at 100.0 mg l(-1) CPL (n=12)] and the 3sigma detection limit (c(L)=2.5 mg l(-1)) was quite satisfactory. Its application to commercially available pharmaceuticals produced excellent results, with a mean relative error of e(r)<1.0%. 相似文献