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991.
The variance of a chromatographic band is derived in the case of RPLC gradient elution when the organic modifier is significantly retained onto the stationary phase. This derivation is based on the extension of a model due to Poppe et al. [H. Poppe, J. Paanakker, M. Bronckhorst, J. Chromatogr., 204 (1981) 77] which assumes that the gradient front remains unchanged and propagates along the column at the same speed as the mobile phase, following piston flow. Theoretical and experimental results are compared in the case of caffeine on a C(1)-silica stationary phase eluted with an acetonitrile gradient. The actual retention behaviors of caffeine and acetonitrile were implemented in the theoretical calculations. The model predicts compression factors between 0.71 and 0.34 for relatively smooth gradient steepness, betat(0), between 0.009 and 0.054 while the corresponding experimental band compression factors vary between 1.01 and 0.43 for the very same gradient steepness. The model underestimation of these factors arises likely from the strong deviation of the actual retention behavior from the prediction of the Linear Solvent Strength Model (LSSM). 相似文献
992.
The influence of microwave irradiation on the mass transfer kinetics of an insulin variant in reversed-phase liquid chromatography (RPLC) was investigated. The elution band profiles of insulin were obtained by the pulse-response method, under linear conditions. The RPLC column was placed in a microwave oven and the incremental change in the temperature of the column effluent stream at various microwave energies and mobile phase flow rates were measured. The microwave energy dissipated in the column was set at 15 and 30 W and the mobile phase flow rate was varied from 1.0 to 2.5 mL/min at a mobile phase composition of acetonitrile, water, and trifloroacetic acid (31:69:0.1, v/v/v). The experimental data were analyzed using the conventional method of moment analysis and the lumped pore diffusion model. Regardless of mobile flow rates, the effluent temperatures measured at 15 and 30 W microwave power input were 25+/-1 and 30+/-1 degrees C, respectively. The effect of microwave irradiation on the mass transfer of the variant insulin was determined by comparing the band profiles obtained under the same experimental conditions, at the same column temperature, with and without irradiation. The calculated intraparticle diffusion coefficient, D(e), at 30 W (30+/-1 degrees C) microwave irradiation was ca. 20% higher than without irradiation at 30+/-1 degrees C. These preliminary results suggest that microwave irradiation may have a significant influence on the intraparticle diffusion of insulin in RPLC. 相似文献
993.
The temperatures of the metal wall along a chromatographic column (longitudinal temperature gradients) and of the liquid phase across the outlet section of the column (radial temperature gradients) were measured at different flow rates with the same chromatographic column (250 mm x 4.6 mm). The column was packed with 5 microm C18-bonded silica particles. The measurements were carried out with surface and immersion thermocouples (all junction Type T, +/-0.1 K) that measure the local temperature. The column was either left in a still-air bath (ambient temperature, T(ext) = 295-296 K) or insulated in a packing foam to avoid air convection around its surface. The temperature profiles were measured at several values of the inlet pressure (approximately = 100, 200, 300 and 350 bar) and with two mobile phases, pure methanol and a 2.5:97.5 (v/v, %) methanol:water solution. The experimental results show that the longitudinal temperature gradients never exceeded 8 K for a pressure drop of 350 bars. In the presence of the insulating foam, the longitudinal temperature gradients become quasi-linear and the column temperature increases by +1 and +3 K with a water-rich (heat conductivity approximately = 0.6 W/m/K) and pure methanol (heat conductivity approximately = 0.2 W/m/K), respectively. The radial temperature gradients are maximum with methanol (+1.5 K at 290 bar inlet pressure) and minimum with water (+0.8 K at 290 bar), as predicted by the solution of the heat transfer balance in a chromatographic column. The profile remains parabolic all along the column. Combining the results of these measurements (determination of the boundary conditions on the wall, at column inlet and at column outlet) with calculations using a realistic model of heat dispersion in a porous medium, the temperature inside the column could be assessed for any radial and axial position. 相似文献
994.
Autofluorescence (AF) imaging is a powerful tool for the detection of (pre-)neoplastic lesions in the bronchi. Several endoscopic imaging systems exploit the spectral and intensity contrast of AF between healthy and (pre-)neoplastic bronchial tissues, yet, the mechanisms underlying these contrasts are poorly understood. In this report, the effect of formalin fixation on the human bronchi AF, hence on the contrast, was studied by spectrofluorometric point measurements and DAFE (Diagnostic AutoFluorescence Endoscopy) broad field imaging. Generally, formalin-fixed samples have higher AF intensity than in vivo, whereas the emission spectral shape is similar. Additionally, the spectrofluorometric data showed a moderate decrease of the AF intensity on (pre-)neoplastic lesions relative to the healthy bronchial samples. However, this decrease was lower than that reported from in vivo measurements. Neither spectral measurements nor imaging revealed spectral contrast between healthy bronchial tissue and (pre-)neoplastic lesions in formalin. These results indicate that epithelial thickening and blood supply in the adjacent lamina propria are likely to play a key role in the generation of the AF contrast in bronchial tissues. Our results show that the AF contrast in bronchial tissues was significantly affected by standard, 10% buffered, formalin fixation. Therefore, these samples are not suited to AF contrast studies. 相似文献
995.
The influence of suction on the spirals pattern that appear on the periphery of an aspirated opened rotor–stator cavity is studied by means of tomography. A radial gap, located between the rotating disk and the fixed cylindrical wall allow the suction of an outer flux made up of a jet of fresh air and a high contrasted smoke thin sheet produced in the outside cavity Ekman layer. Sequences of tomographies allow the characterization of the apparition and disappearance thresholds according to Reynolds number, suction and wave number. To cite this article: D. Rémy et al., C. R. Mecanique 332 (2004). 相似文献
996.
In this paper, we present the design, modelling and experimental validation of a novel experimental cam-follower rig for the
analysis of bifurcations and chaos in piecewise-smooth dynamical systems with impacts. Experimental results are presented
for a cam-follower system characterized by a radial cam and a flat-faced follower. Under variation of the cam rotational speed,
the follower is observed to detach from the cam and then show the emergence of periodic impacting behaviour characterized
by many impacts and chattering. Further variations of the cam speed cause the sudden transition to seemingly aperiodic behaviour.
These results are compared with the numerical simulation of a mathematical model of the system which shows the same qualitative
behaviour. Excellent quantitative agreement is found between the numerical and experimental results. 相似文献
997.
This article concerns heat transfer due to thermocapillary convection induced by an air bubble introduced under a heated wall into a silicone oil layer. An experimental study is carried out under normal gravity conditions with direct measurements by means of a heat fluxmeter. Effects of the bubble size and the temperature gradient are systematically investigated for two values of viscosity. The nature of the thermocapillary convection state (stationary or oscillatory) is determined by shadowgraphy. Two regimes of heat transfer are made evident. They depend on the Prandtl number but are independent of the state of the flow. To cite this article: C. Reynard et al., C. R. Mecanique 331 (2003). 相似文献
998.
999.
An Alternative Anionic Polyelectrolyte for Aqueous PEDOT Dispersions: Toward Printable Transparent Electrodes 下载免费PDF全文
Anna I. Hofmann Wiljan T. T. Smaal Dr. Muhammad Mumtaz Dr. Dimitrios Katsigiannopoulos Dr. Cyril Brochon Falk Schütze Dr. Olaf R. Hild Dr. Eric Cloutet Prof.Dr. Georges Hadziioannou 《Angewandte Chemie (International ed. in English)》2015,54(29):8506-8510
Organic conducting polymers are promising electrode materials for printable organic electronics. One of the most studied conducting polymers is PEDOT:PSS, which is sufficiently conductive and transparent, but which shows some drawbacks, such as hygroscopicity and acidity. A new approach to stabilize PEDOT in aqueous dispersions involves the replacement of PSS with a basic polyanion based on a polystyrene backbone with (trifluoromethylsulfonyl)imide (TSFI) side groups. The PEDOT:PSTFSIK dispersions were obtained by oxidative polymerization of EDOT in an aqueous PSTFSIK solution and were characterized with regard to their composition, morphology, doping, rheological behavior, and optoelectronic performance. The PEDOT:PSTFSIK dispersions showed excellent printability and good optoelectronic performance (238 Ohm sq?1 at 91 % transmittance, σ>260 S cm?1) and were successfully integrated as flexible electrodes in OLED and OPV devices. 相似文献
1000.