排序方式: 共有18条查询结果,搜索用时 203 毫秒
11.
D. F. Saifina V. R. Ganieva V. A. Mamedov 《Russian Journal of Organic Chemistry》2009,45(8):1244-1247
A two-stage method was developed for the synthesis of 3-(α-chloroalkyl- and α-chlorophenylalkyl)-quinoxalin-2(1H)-ones proceeding from methyl chloroalkyl- and chlorophenylalkylpyruvates obtained by Darzens reaction from methyl dichloroacetate
and appropriate aldehydes in the presence of t-BuOK. 相似文献
12.
Mamedov V. A. Saifina D. F. Gubaidullin A. T. Saifina A. F. Rizvanov I. Kh. Ganieva V. R. 《Russian Chemical Bulletin》2009,58(9):1986-1990
A reaction of 3-(α-chlorobenzyl)quinoxalin-2(1 H)-one with α-picoline gives 2-(3-phenyl-indolizin-2-yl)benzimidazole as a result of a ring-contracting rearrangement involving
the fragment C(2)—C(3)—C(Cl)Ph of the quinoxaline system and the fragment N=CH—Me of the α-picoline system. Possible pathways
of this reaction are discussed. 相似文献
13.
G. Yu. Ishmuratov M. P. Yakovleva V. A. Ganieva R. R. Muslukhov G. A. Tolstikov 《Chemistry of Natural Compounds》2005,41(1):41-44
A synthesis of the promising optically pure synthon isopropyl-4R-methyl-6-iodohexanoate based on ozonolytic transformation of the product of regiospecific dehydratation of L-(-)-menthol, (R)-p-menth-3-ene, into 2,6R-dimethyl-8-hydroxyoctan-3-one was proposed.__________Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 33–36, January–February, 2005. 相似文献
14.
Effect of calcium and scandium additives on corrosion-electrochemical properties and electrical conductivity of lightly alloyed
electrical alloys was studied in order to optimize their composition. 相似文献
15.
Sal'nikov Yu. I. Boos G. A. Ryzhkina I. S. Ganieva E. R. Lukashenko S. S. 《Russian Journal of Coordination Chemistry》2004,30(6):430-434
The acid-basic and complexing properties of N,N-dimethyl-N-(2-hydroxybenzyl)ethylenediamine (HL) in aqueous propan-2-ol were characterized by spectrophotometry, pH-metry, and mathematical simulation of equilibria in solutions (T = 25 ± 0.1°C, = 0.1 M KNO3). Dimer H2L2 was found to predominate in solution at c
HL = 0.01 mol/l. Three protonated dimeric (H3L2
+, H4L2
2+, and H5L2
3+), diprotonated monomeric (H3L2+), and triprotonated tetrameric forms (H7L4
3+) were detected in the system, depending on pH. At lower ligand concentrations (c
HL = 0.0015 mol/l), the solution contains both dimers and monomers of this compound. The higher dentate number of HL compared to 2-alkylaminomethylphenols allows it to form more number of both mono- and binuclear complexes ([Cu(HL)]2+, [Cu(HL)2]2+, [CuL2], [CuL2OH]–, [Cu2(HL)2]4+, and [Cu2(HL)2L2]2+), making them more stable. 相似文献
16.
G. Yu. Ishmuratov M. P. Yakovleva V. A. Ganieva R. Ya. Kharisov R. R. Gazetdinov A. M. Abulkaramova G. A. Tolstikov 《Chemistry of Natural Compounds》2006,42(1):92-95
Three new approaches to the synthesis of 1-bromo-3S-methylundecane, a key synthon in the synthesis of (S,S,S)-diprionylacetate, a sex pheromone of pine sawflies of the genera Diprion and Neodiprion, were proposed based on chemo-and stereoselective transformations of L-(-)-menthol derivatives.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 73–76, January–February, 2006. 相似文献
17.
E. S. Ganieva I. M. Ganiev S. A. Grabovskiy N. N. Kabalnova 《Russian Chemical Bulletin》2008,57(11):2332-2334
The product of the reaction of valeraldehyde with chlorine dioxide was determined, and the solvent effect on the reaction
kinetics was studied. The major oxidation product is valeric acid. The reaction rate is described by the second-order equation
w = k[RCHO]·[ClO2]. The rate constants were measured in the 297–328 K interval, and the activation parameters of the reaction were determined. 相似文献
18.
L. S. Khasanova F. A. Gimalova Z. R. Valiullina N. K. Selezneva R. M. Ganieva L. V. Spirikhin M. S. Miftakhov 《Russian Journal of Organic Chemistry》2012,48(9):1238-1244
A new disaccharide block for OSW-1 natural steroidal antitumor agent was described. Regioisomeric 2- and 3-O-p-methoxybenzoyl derivatives of phenyl 1-thio-??-d-xylopyranoside and phenyl 2-O-acetyl-1-thio-??-l-arabinopyranoside derivatives blocked at positions 3 and 4 by R3Si groups were synthesized with a view to use them in the preparation of OSW-1 analogs modified at the disaccharide fragment. 相似文献