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991.
Albertin G Antoniutti S Castro J García-Fontán S Noé M 《Dalton transactions (Cambridge, England : 2003)》2007,(46):5441-5452
Trichlorostannyl complexes [M(SnCl3)(bpy)2P]BPh4 [M = Ru, P = P(OEt)(3), 1a PPh(OEt)2 1b; M = Os, P = P(OEt)3 2; bpy = 2,2'-bipyridine] were prepared by allowing chloro complexes [MCl(bpy)2P]BPh4 to react with SnCl2 in 1,2-dichloroethane. Bis(trichlorostannyl) compounds Ru(SnCl3)2(N-N)P2 [N-N = bpy, P = P(OEt)3 3a, PPh(OEt)2 3b; N-N = 1,10-phenanthroline (phen), P = P(OEt)3 4] were also prepared by reacting [RuCl(N-N)P3]BPh4 precursors with SnCl2.2H2O in ethanol. Treatment of both mono- 1a, 2 and bis 3a trichlorostannyl complexes with NaBH4 afforded mono- and bis(trihydridestannyl) derivatives [M(SnH3)(bpy)2P]BPh4 5, 6 and Ru(SnH3)2(bpy)P2 7[P = P(OEt)3], respectively. Treatment of 1a, 2 with MgBrMe gave the trimethylstannyl complexes [M(SnMe3)(bpy)2P]BPh4 8, 9 and treatment of 3a afforded the bis(stannyl) Ru(SnClMe2)2(bpy)P2 10 derivative. Alkynylstannyl complexes [M{Sn(C triple bond CR)3}(bpy)2P]BPh4 11-13 and Ru[Sn(C triple bond CR)3]2(N-N)P2 14-17(R = p-tolyl, Bu t; N-N = bpy, phen) were also prepared by allowing trichlorostannyl compounds 1-4 to react with Li+[RC triple bond C]* in thf. The complexes were characterised spectroscopically and by the X-ray crystal structure determination of [Ru(SnMe3)(bpy)2{P(OEt)3}]BPh4 derivative. 相似文献
992.
Rosini G Borzatta V Boschi F Candido G Marotta E Righi P 《Chemical communications (Cambridge, England)》2007,(26):2717-2719
The occurrence of p(1),n(1) salt when accompanied by substrate self-association can have profound effects on enantiomer separation processes of non-racemic mixtures, impeding the complete recovery of the major enantiomer through formation of an inescapable racemate cage. 相似文献
993.
In this issue of Chemistry & Biology, Duquesne and colleagues [1] describe the biosynthetic machinery of microcin J25, an antibacterial peptide that adopts an exceptional three-dimensional structure resembling a knot. The dedicated enzymes, McjB and McjC, were identified and employed to produce this modification in vitro. 相似文献
994.
The use of SIMS and SEM for the characterization of individual particles with a matrix originating from a nuclear weapon. 总被引:1,自引:0,他引:1
Ylva Ranebo Mats Eriksson Gabriele Tamborini Nedialka Niagolova Olivier Bildstein Maria Betti 《Microscopy and microanalysis》2007,13(3):179-190
The application of scanning electron microscopy (SEM) and secondary ion mass spectrometry (SIMS) for characterization of mixed plutonium and uranium particles from nuclear weapons material is presented. The particles originated from the so-called Thule accident in Greenland in 1968. Morphological properties have been studied by SEM and two groups were identified: a "popcorn" structure and a spongy structure. The same technique, coupled with an energy-dispersive X-ray (EDX) spectrometer, showed a heterogeneous composition of Pu and U in the surface layers of the particles. The SIMS depth profiles revealed a varying isotopic composition indicating a heterogeneous mixture of Pu and U in the original nuclear weapons material itself. The depth distributions agree with synchrotron-radiation-based mu-XRF (X-ray fluorescence microprobe) measurements on the particle (Eriksson, M., Wegryzynek, D., Simon, R., & Chinea-Cano, E., in prep.) when a SIMS relative sensitivity factor for Pu to U of 6 is assumed. Different SIMS identified isotopic ratio groups are presented, and the influence of interferences in the Pu and U mass range are estimated. The study found that the materials are a mixture of highly enriched 235U (235U:238U ratio from 0.96 to 1.4) and so-called weapons grade Pu (240Pu:239Pu ratio from 0.028 to 0.059) and confirms earlier work reported in the literature. 相似文献
995.
Zecchina A Rivallan M Berlier G Lamberti C Ricchiardi G 《Physical chemistry chemical physics : PCCP》2007,9(27):3483-3499
Fe-ZSM-5 and Fe-silicalite zeolites efficiently catalyse several oxidation reactions which find close analogues in the oxidation reactions catalyzed by homogeneous and enzymatic compounds. The iron centres are highly dispersed in the crystalline matrix and on highly diluted samples, mononuclear and dinuclear structures are expected to become predominant. The crystalline and robust character of the MFI framework has allowed to hypothesize that the catalytic sites are located in well defined crystallographic positions. For this reason these catalysts have been considered as the closest and best defined heterogeneous counterparts of heme and non heme iron complexes and of Fenton type Fe(2+) homogeneous counterparts. On this basis, an analogy with the methane monooxygenase has been advanced several times. In this review we have examined the abundant literature on the subject and summarized the most widely accepted views on the structure, nuclearity and catalytic activity of the iron species. By comparing the results obtained with the various characterization techniques, we conclude that Fe-ZSM-5 and Fe-silicalite are not the ideal samples conceived before and that many types of species are present, some active and some other silent from adsorptive and catalytic point of view. The relative concentration of these species changes with thermal treatments, preparation procedures and loading. Only at lowest loadings the catalytically active species become the dominant fraction of the iron species. On the basis of the spectroscopic titration of the active sites by using NO as a probe, we conclude that the active species on very diluted samples are isolated and highly coordinatively unsaturated Fe(2+) grafted to the crystalline matrix. Indication of the constant presence of a smaller fraction of Fe(2+) presumably located on small clusters is also obtained. The nitrosyl species formed upon dosing NO from the gas phase on activated Fe-ZSM-5 and Fe-silicalite, have been analyzed in detail and the similarities and differences with the cationic, heme and non heme homogeneous counterparts have been evidenced. The same has been done for the oxygen species formed by N(2)O decomposition on isolated sites, whose properties are more similar to those of the (FeO)(2+) in cationic complexes (included the [(H(2)O)(5)FeO](2+)"brown ring" complex active in Fenton reaction) than to those of ferryl groups in heme and non heme counterparts. 相似文献
996.
Cioffi C Campidelli S Sooambar C Marcaccio M Marcolongo G Meneghetti M Paolucci D Paolucci F Ehli C Rahman GM Sgobba V Guldi DM Prato M 《Journal of the American Chemical Society》2007,129(13):3938-3945
Single-wall carbon nanohorns (SWNHs) are a new class of material that is closely related to single-wall carbon nanotubes. Here, we describe the synthesis and characterization of a series of SWNHs functionalized with ethylene glycol chains and porphyrins. Functionalization of carbon nanohorns has been achieved using two different synthetic protocols: (1) direct attack of a free amino group on the nanohorn sidewalls (nucleophilic addition) and (2) amidation reaction of the carboxylic functions in oxidized nanohorns. The nanohorn derivatives have been characterized by a combination of several techniques, and the electronic properties of the porphyrin/nanohorn assemblies (SWNH/H2P) have been investigated by electrochemistry, spectroelectrochemistry, and a series of steady-state and time-resolved spectroscopy. The cyclic voltammetry curve of nanohorn/porphyrin conjugate 6 showed a continuum of faradic and pseudocapacitive behavior, which is associated with multiple-electron transfers to and from the SWNHs. Superimposed on such a pseudocapacitive current, the curve also displays three discrete reduction peaks at -2.26, -2.57, and -2.84 V and an oxidation peak at 1.12 V (all attributed to the porphyrin moiety). Steady-state and time-resolved fluorescence demonstrated a quenching of the fluorescence of the porphyrin in SWNH/H2P conjugates 5 and 6 compared to the reference free base porphyrin. Transient absorption spectra permitted the electron-transfer process between the porphyrins and the carbon nanostructures to be highlighted. 相似文献
997.
998.
Krafft C Kirsch M Beleites C Schackert G Salzer R 《Analytical and bioanalytical chemistry》2007,389(4):1133-1142
The objectives of this study were to optimize the preparation of pristine brain tissue to obtain reference information, to optimize the conditions for introducing a fiber-optic probe to acquire Raman maps, and to transfer previous results obtained from human brain tumors to an animal model. Brain metastases of malignant melanomas were induced by injecting tumor cells into the carotid artery of mice. The procedure mimicked hematogenous tumor spread in one brain hemisphere while the other hemisphere remained tumor free. Three series of sections were prepared consecutively from whole mouse brains: dried, thin sections for FTIR imaging, hematoxylin and eosin-stained thin sections for histopathological assessment, and pristine, 2-mm thick sections for Raman mapping. FTIR images were recorded using a spectrometer with a multi-channel detector. Raman maps were collected serially using a spectrometer coupled to a fiber-optic probe. The FTIR images and the Raman maps were segmented by cluster analysis. The color-coded cluster memberships coincided well with the morphology of mouse brains in stained tissue sections. More details in less time were resolved in FTIR images with a nominal resolution of 25 microm than in Raman maps collected with a laser focus 60 microm in diameter. The spectral contributions of melanin in tumor cells were resonance enhanced in Raman spectra on excitation at 785 nm which enabled their sensitive detection in Raman maps. Possible reasons why metastatic cells of malignant melanomas were not identified in FTIR images are discussed. 相似文献
999.
Balasubramaniyam Arul Prakasam Kuppukkannu Ramalingam Gabriele Bocelli Andrea Cantoni 《Polyhedron》2007
The current paper describes the synthesis and characterization of the following adducts: [Zn(4-mpzdtc)2(1,10-phen)] · H2O (1), [Zn(4-mpzdtc)2(2,2′-bipy)] (2), [Cd(4-mpzdtc)2(1,10-phen)] (3), [Cd(4-mpzdtc)2(2,2′-bipy)] (4), [Zn(padtc)2(1,10-phen)] (5) and [Cd(padtc)2(1,10-phen)] (6) (where, 4-mpzdtc = 4-methylpiperazinecarbodithioate anion, padtc = N,N′-(iminodiethylene)bisphthalimide dithiocarbamate anion, 1,10-phen = 1,10-phenanthroline and 2,2′-bipy = 2,2′-bipyridine). All the synthesized complexes were characterized by UV–Vis, IR, NMR, (1H and 13C) and fluorescence spectra. A single crystal X-ray structural analysis was carried out for complex 1. IR spectra of the complexes show the contribution of the thioureide form to the structures. The observed deshielding of the α-protons for 1–6 in the 1H NMR spectra is attributed to the drift of electrons from the nitrogen of the NR2 groups, forcing a high electron density towards sulfur via the thioureide π-system. In the 13C NMR spectra, the most important thioureide (N13CS2) carbon signals are observed in the region 206–208 ppm. Fluorescence spectra of complexes 5 and 6 show intense fluorescence due to the presence of rigid conjugated systems such as phthalimide and 1,10-phenanthroline. The observed fluorescence maxima for complexes with a MS4N2 chromophore in the visible region are assigned to the metal-to-ligand charge transfer (MLCT) processes. Single crystal X-ray structural analysis of 1 showed that the zinc atom is in a distorted octahedral environment with a MS4N2 chromophore. VBS equivalent to 1.81 supports the correctness of the determined structure. The piperazine ring in the dithiocarbamate fragment is in the normal chair conformation. 相似文献
1000.
Gabriele B Mancuso R Salerno G Ruffolo G Plastina P 《The Journal of organic chemistry》2007,72(18):6873-6877
A general and convenient synthesis of substituted quinolines by regioselective copper- or palladium-catalyzed 6-endo-dig cyclization-dehydration of 1-(2-aminoaryl)-2-yn-1-ols is reported. The crude substrates were easily obtained by the Grignard reaction between the appropriate alkynylmagnesium bromide and 2-aminoaryl ketones and could be used without further purification for the subsequent cyclization step. Heteroannulation reactions were carried out in MeOH or DME as the solvent at 60 or 100 degrees C in the presence of CuCl(2) or PdX(2) (in conjunction with 10 equiv of KX, X = Cl, I) as the catalyst to afford the quinoline derivatives in good to excellent isolated yields based on starting 1-(2-aminoaryl)-2-yn-1-ols (66-90%). 相似文献